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Ph.D. Thesis - Physics

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1.4.1 Decoherence<br />

Decoherence is the irreversible loss of information from a quantum system to its environ-<br />

ment. It arises from interactions between a quantum system and a “reservoir” of states<br />

too numerous to keep track of. Thus, although the full evolution of the system and reser-<br />

voir together is unitary, the evolution of the system alone exhibits non-unitary dynamics.<br />

Decoherence is present in any quantum-mechanical system, but the question always is the<br />

degree to which the evolution is altered by decoherence. The main questions studied by<br />

researchers are the sources of decoherence and the methods of reducing it. Since nuclear<br />

spins and ion traps are the quantum systems used in this thesis, we discuss here the main<br />

sources of decoherence for each.<br />

The two primary types of decoherence relevant to nuclear spins are amplitude damping<br />

and dephasing. Each affects a different part of the density matrix of the quantum system.<br />

Amplitude damping affects the on-diagonal elements, or “populations,” causing population<br />

transfer from one state to another, typically from an excited state to a lower-energy (or the<br />

ground) state. However, due to the low spin polarization of a room-temperature nuclear spin<br />

system, the thermal state is a nearly equal mixture of the ground and excited spin states.<br />

In NMR, the rate at which this occurs is given by the inverse of the T1 time. Dephasing<br />

affects the off-diagonal elements, or “coherences,” effectively changing the relative phases<br />

between different terms of the quantum state, and thus destroying coherence. The rate of<br />

this process is characterized in NMR as 1/T2. The T2 time arises from a number of both<br />

macroscopic and microscopic sources.<br />

An important macroscopic source of dephasing in NMR is inhomogeneities in the static<br />

and oscillating magnetic fields used to control the nuclei. Such inhomogeneities can be<br />

corrected in one of two ways: first, by measuring and improving the field homogeneity, and<br />

second by using spin-echo techniques to correct for the inhomogeneities that remain. Still,<br />

a number of microscopic and uncontrollable processes contribute to limiting the coherence<br />

time, including the fundamental cause of the T1 time: spin transitions induced by thermal<br />

excitation of spins.<br />

Decoherence of the quantum states of trapped ions, by contrast, includes processes that<br />

affect either the internal (electronic) or external (motional) degrees of freedom. Both the<br />

electronic and motional quantum states are important for the storage and processing of<br />

quantum information. Decoherence of electronic states can be attributed to two primary<br />

sources: scattering events and control errors. For instance, the excited state lifetime in a<br />

qubit separated by optical wavelengths is fundamentally limited by spontaneous emission.<br />

For hyperfine qubits manipulated with a laser Raman transition, however, the spontaneous<br />

scattering rate defines this limit [OLJ + 95]. Some common control errors include fluctuations<br />

in the laser intensity or polarization, as well as fluctuations of ambient magnetic fields, and<br />

in practice these fluctuating controls limit the coherence times [BKRB08]. Motional states,<br />

by contrast, decohere largely due to heating caused by fluctuating potentials on the trap<br />

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