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Conservation and Innovation : Helmholtz's Struggle with Energy ...

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potential function 201. It is worth noting that still in 1847 <strong>Helmholtz's</strong> idea of<br />

electric tension was reminiscent of Volta's influential "density of electricity" 202.<br />

Helmholtz <strong>with</strong> great intellectual ingenuity struggled to apply his conceptual<br />

framework of living <strong>and</strong> tension forces to every realm of nature: he did not use<br />

mathematical requirements as heuristic tools <strong>and</strong> thus differed from mathematical<br />

physicists such as Clausius <strong>and</strong> Riemann to a great extent. But he also differed<br />

widely from experimentalists such as Joule: in discussing the heat generated in an<br />

electrical discharge he stressed the interpretation of the heat as the vis viva<br />

produced by a decrease of the quantity of tension forces (i.e. of the potential) <strong>and</strong><br />

of the discharge as an oscillatory process of alternating currents, more than the<br />

search for experimental results. In fact for the mechanical equivalent of heat<br />

(whose numerical value enters in the laws expressed, given the electrostatic<br />

system of units utilised 203) he asserted that "up to now observations are lacking".<br />

Detailed information is instead given on the relation between the heat produced<br />

through the discharge of a specific battery <strong>and</strong> the shape <strong>and</strong> dimension of the<br />

connecting wire 204 (quoting Riess, Vorselman de Heer <strong>and</strong> Knochenauer).<br />

The fact that conceptual explanation played a greater role than empirical<br />

corroboration or mathematical formalism is again exemplified in the discussion of<br />

galvanism. For Helmholtz 205 the contact law of Volta, if correctly interpreted, is<br />

not in disagreement, as often remarked 206, <strong>with</strong> the impossibility of perpetual<br />

motion.<br />

201 Helmholtz, Hermann. "Ueber einige Gesetze der Vertheilung elektrischer Ströme<br />

in körperlichen Leitern mit Anwendung auf die thierisch-elektrischen Versuche." In Pogg Ann<br />

89 (1853): 211-33, 352-77. Repr. in WA 1 p.475, P.224.<br />

202 On Volta's influence in Germany see: Teichmann, Jurgen. "L'influenza di A.Volta<br />

in Germania." Quaderni del Giornale di Fisica 3 (1977): 43-60. In 1849 Kirchhoff unified the<br />

concepts of electric tension, electrostatic <strong>and</strong> electrodynamic potential : Kirchhoff,Gustav. "On<br />

a Deduction of Ohm's Law, in Connection <strong>with</strong> the Theory of Electrostatics" Phil Mag 3<br />

XXXVII (1850): 463-8; translated from Pogg Ann LXXVIII (1849) P.506; see also : my<br />

<strong>Energy</strong> <strong>and</strong> Electr Pp.77 <strong>and</strong> 96-7; Archibald, Thomas. "Tension <strong>and</strong> Potential from Ohm to<br />

Kirchhoff." In Centaurus 31 (1988): 141-63.<br />

criticisms.<br />

203 See Planck Princip P.41.<br />

204 Helmholtz Erhaltung Pp.43-4. This was going to be another object of Clausius'<br />

205 Helmholtz Erhaltung P.45.<br />

206 Kuhn seems still to believe it: Kuhn Sim Disc P.73. See above n.20.

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