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Single-Photon Atomic Cooling - Raizen Lab - The University of ...

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constant which is given by<br />

α = e2<br />

c4πǫ0<br />

≈ 1<br />

. (2.2)<br />

137<br />

<strong>The</strong>re are two causes <strong>of</strong> the fine structure splittings. <strong>The</strong> first is due to<br />

the coupling between the magnetic moment <strong>of</strong> the electrons and the effective<br />

magnetic field seen by the electrons due to their motion around the nucleus.<br />

<strong>The</strong> second cause is due to relativistic corrections to the kinetic and potential<br />

energy <strong>of</strong> the electrons. For Rb, the first contribution dominates and so I will<br />

focus solely on it.<br />

<strong>The</strong> Hamiltonian describing the interaction between the outermost elec-<br />

tron’s magnetic moment and orbital angular momentum can be written as<br />

Hfs = A( L · S), (2.3)<br />

where A is a constant parameterizing the strength <strong>of</strong> the interaction, S is the<br />

spin <strong>of</strong> the electron and L is the orbital angular momentum <strong>of</strong> the electron.<br />

To solve this Hamiltonian we introduce the total electron angular mo-<br />

mentum J, given by<br />

J = L + S, (2.4)<br />

where by the triangle inequality the quantum number J must lie in the range<br />

|L − S| ≤ J ≤ L + S. (2.5)<br />

<strong>The</strong> convention that the magnitude <strong>of</strong> J is J(J + 1), and that the eigen-<br />

value <strong>of</strong> Jz is mJ is being used. We next note that squaring both sides <strong>of</strong><br />

27

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