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Single-Photon Atomic Cooling - Raizen Lab - The University of ...

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2.1 Rubidium<br />

Rubidium (Rb) is an alkali metal. Its common use in atomic exper-<br />

iments is due in part to its relatively simple energy level structure and its<br />

possession <strong>of</strong> an accessible effective cycling transition. <strong>The</strong> simplicity <strong>of</strong> the<br />

energy level structure is due to the fact that <strong>of</strong> Rb’s 37 electrons only one is<br />

in the outermost shell. 85 Rb is the most abundant and only stable isotope<br />

<strong>of</strong> rubidium, however the experimental work performed in this dissertation<br />

was done entirely on 87 Rb. <strong>The</strong> reason for this is that 87 Rb has a simpler<br />

hyperfine structure, the topic <strong>of</strong> the next section. 87 Rb has a relative natural<br />

abundance <strong>of</strong> 27.83(2)% and decays to β − + 87 Sr with a total disintegration<br />

energy <strong>of</strong> 0.283 MeV [40]. While unstable, the nuclear lifetime is 4.88×10 10 yr<br />

[40] making this form <strong>of</strong> rubidium effectively stable over the duration <strong>of</strong> our<br />

experiment. <strong>The</strong> mass <strong>of</strong> 87 Rb was accurately determined from a Penning trap<br />

measurement to be m = 1.443 160 648(72) × 10 −25 kg [41]. <strong>The</strong> vapor pressure<br />

<strong>of</strong> solid Rb is an important experimental quantity because it dictates the load-<br />

ing rate into the first stage <strong>of</strong> our experimental procedure. This value can be<br />

taken from a vapor-pressure model for solid Rb given by [42], which is<br />

log10Pv = 2.881 + 4.857 − 4215<br />

, (2.1)<br />

T<br />

where Pv is the vapor pressure in torr and T is in K. This model is specified to<br />

have an accuracy better than ±5% from 298-550K. <strong>The</strong> ambient temperature<br />

surrounding our experimental chamber is approximately 295K resulting in a<br />

vapor pressure <strong>of</strong> 2.9 × 10 −7 torr. More will be said about how this relates<br />

25

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