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Exergy evolution of the mineral capital on earth - circe

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Acknowledgements<br />

The work with this dissertati<strong>on</strong> has been exciting, instructive, and fun, although<br />

moments <str<strong>on</strong>g>of</str<strong>on</strong>g> hardship and frustrati<strong>on</strong> have also existed. Without help, support, and<br />

encouragement from a great number pers<strong>on</strong>s, I would never have been able to<br />

finish this PhD. In this l<strong>on</strong>g ride <str<strong>on</strong>g>of</str<strong>on</strong>g> almost 5 years, I have had <str<strong>on</strong>g>the</str<strong>on</strong>g> opportunity to<br />

meet excepti<strong>on</strong>al people around <str<strong>on</strong>g>the</str<strong>on</strong>g> world.<br />

In <str<strong>on</strong>g>the</str<strong>on</strong>g> scientific field, many researchers have unselfishly supported me. I should<br />

start to acknowledge <str<strong>on</strong>g>the</str<strong>on</strong>g> Russian geochemist N.A. Grigor’ev, that I discovered by<br />

chance investigating <str<strong>on</strong>g>the</str<strong>on</strong>g> literature about <str<strong>on</strong>g>the</str<strong>on</strong>g> geochemistry <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> <strong>earth</strong>. Through<br />

a quite complicated communicati<strong>on</strong> procedure (via ordinary post and in Russian<br />

language), Grigor’ev generously shared with me his not yet published results about<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> <str<strong>on</strong>g>mineral</str<strong>on</strong>g>ogical compositi<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> <strong>earth</strong>’s crust. Thanks to <str<strong>on</strong>g>the</str<strong>on</strong>g> translati<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g><br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> Russian teacher in <str<strong>on</strong>g>the</str<strong>on</strong>g> University <str<strong>on</strong>g>of</str<strong>on</strong>g> Zaragoza Helena Moradell, Grigor’ev’s<br />

excepti<strong>on</strong>al and pi<strong>on</strong>eer work has been <str<strong>on</strong>g>the</str<strong>on</strong>g> base <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> model <str<strong>on</strong>g>of</str<strong>on</strong>g> c<strong>on</strong>tinental crust<br />

developed in this PhD.<br />

A deep debt <str<strong>on</strong>g>of</str<strong>on</strong>g> thanks is also owed to Gavin Mudd from <str<strong>on</strong>g>the</str<strong>on</strong>g> Institute for Sustainable<br />

Water Resources in M<strong>on</strong>ash University (Australia), who kindly made available and<br />

prior to publicati<strong>on</strong>, his excellent and also pi<strong>on</strong>eer study about average <str<strong>on</strong>g>mineral</str<strong>on</strong>g> ore<br />

grades in his country. Thanks to Mudd’s work, a comprehensive case study <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

<str<strong>on</strong>g>mineral</str<strong>on</strong>g> exergy degradati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> a nati<strong>on</strong> was possible.<br />

This <str<strong>on</strong>g>the</str<strong>on</strong>g>sis has required a high level <str<strong>on</strong>g>of</str<strong>on</strong>g> geological and geochemical knowledge.<br />

Therefore, my chemical engineering background had to be reinforced with <strong>earth</strong><br />

science’s fundamentals. Of essential help was <str<strong>on</strong>g>the</str<strong>on</strong>g> c<strong>on</strong>tinued support <str<strong>on</strong>g>of</str<strong>on</strong>g> Javier<br />

Gómez, from <str<strong>on</strong>g>the</str<strong>on</strong>g> department <str<strong>on</strong>g>of</str<strong>on</strong>g> petrology in <str<strong>on</strong>g>the</str<strong>on</strong>g> University <str<strong>on</strong>g>of</str<strong>on</strong>g> Zaragoza. From<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> very beginning, he became my un<str<strong>on</strong>g>of</str<strong>on</strong>g>ficial advisor in <str<strong>on</strong>g>the</str<strong>on</strong>g> geological field and his<br />

point <str<strong>on</strong>g>of</str<strong>on</strong>g> view has been very valued for this work. I should also thank <str<strong>on</strong>g>the</str<strong>on</strong>g> “Instituto<br />

Geológico y Minero de España - IGME”, and in particular Miguel Ángel Zapatero,<br />

for making available IGME’s informati<strong>on</strong> and <str<strong>on</strong>g>mineral</str<strong>on</strong>g> statistics.<br />

Decisive for <str<strong>on</strong>g>the</str<strong>on</strong>g> accomplishment <str<strong>on</strong>g>of</str<strong>on</strong>g> this PhD, was my 3-m<strong>on</strong>th stay at <str<strong>on</strong>g>the</str<strong>on</strong>g> British<br />

Geological Survey (BGS), <strong>on</strong>e <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> most renowned geological instituti<strong>on</strong>s in<br />

Europe. Not <strong>on</strong>ly <str<strong>on</strong>g>the</str<strong>on</strong>g> excepti<strong>on</strong>al library and data bases <str<strong>on</strong>g>of</str<strong>on</strong>g> BGS were crucial for this<br />

work, but also <str<strong>on</strong>g>the</str<strong>on</strong>g> good advice <str<strong>on</strong>g>of</str<strong>on</strong>g> many <str<strong>on</strong>g>of</str<strong>on</strong>g> its premium researchers. I would like to<br />

express my deepest gratitude to <str<strong>on</strong>g>the</str<strong>on</strong>g> BGS’s director, John Ludden, who immediately<br />

accepted me in <str<strong>on</strong>g>the</str<strong>on</strong>g> organizati<strong>on</strong> and gave me access with no excepti<strong>on</strong> to all BGS<br />

available informati<strong>on</strong>. Thanks go also to Andrew Bloodworth, head <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> Mineral’s<br />

UK department and to all his team, for <str<strong>on</strong>g>the</str<strong>on</strong>g>ir warm welcome and for treating me as<br />

<strong>on</strong>e more <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> group. I cannot forget Tim Colman, who was always willing to help<br />

me and from which I learnt so many things. I have met at BGS many good friends<br />

that surely will remain in <str<strong>on</strong>g>the</str<strong>on</strong>g> future.<br />

vii

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