Processing kodak motion picture films, module 3 analytical procedures

Processing kodak motion picture films, module 3 analytical procedures Processing kodak motion picture films, module 3 analytical procedures

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CALCULATIONS For Sodium Persulfate, g/L g/L Na 2S 2O 8 = Where: (mLs B - mLs A) (N cerate) (eq wt Na 2 S 2 O 8 ) mL Sample mLs B = volume of sulfato cerate in milliliters required to reach the equivalence point without the addition of sample (Blank) mLs A = volume of sulfato cerate in milliliters required to reach the equivalence point with the addition of sample N cerate = normality of the sulfato cerate in milliequivalents per milliliter (meq/mL) eq wt Na 2 S 2 O 8 = equivalent weight of sodium persulfate in milligrams per milliequivalent (119.05 mg/meq) mL Sample = volume of sample pipetted in step 1 of part A of procedure If mL 0.0497 N sulfato cerate = 32.85 mLs g/L Na 2S 2O 8 = g/L Na 2 S 2 O 8 = 20.18 mLs Blank = 49.90 mLs (49.90 - 32.85) (0.0497) (119.05 5.00 4 Processing KODAK Motion Picture Films, Module 3, Analytical Procedures H24.03

Determination of the pH of the Eastman Color Print-2 Stop Bath ECP-2-890 Process ECN-2 ECP-2D VNF-1/LC RVNP Formulas — SB-14 — — INTRODUCTION Exposure of the electrodes to the low pH of the stop bath causes improper electrode response when the same electrodes are used to measure the pH of more alkaline solutions. A separate set of electrodes should be used for measurement of stop bath pH. Sulfuric acid, 0.25 N, (pH 0.95 ± 0.05) is used as a reference solution in measuring stop bath pH. The electrodes and meter are first standardized with potassium acid phthalate buffer (pH 4.010 at 27°C). The pH of the 0.25 N sulfuric acid is then measured. If the pH value for the 0.25 N sulfuric acid is 0.95 ± 0.05, the meter is adjusted to the nominal value of 0.95 and the pH of the stop bath is measured. Stop bath pH is measured at 27 ± 5°C. SPECIAL APPARATUS Corning Model 12 Research pH Meter or equivalent Corning No. 476024 Glass Electrode or Leeds and Northrup No, 117169 Glass Electrode Beckman Fiber Junction Calomel Electrode, No. 39170 (filled with 3.5 N potassium chloride) REAGENTS Use reagents that are ACS Reagent Grade unless specified otherwise. Potassium Acid Phthalate Buffer, 0.05 M Sulfuric Acid, 0.25 N PROCEDURE 1. Follow the Standardization of pH Meter - Low pH Range procedure in Method ULM-191-2, pH Measurement of Photographic Processing Solutions, (or any subsequent pH method) for preparation of the meter. 2. Rinse the electrode assembly with distilled water and immerse the electrodes in potassium acid phthalate buffer. Set a timer for two minutes. At the end of the two minutes standardize the meter at pH 4.010. 3. Rinse the electrode assembly with distilled water and lower the electrodes into 0.25 N sulfuric acid solution in a 150-mL beaker. Set a timer for two minutes. At the end of two minutes the pH should be 0.95 ± 0.05. a. If the pH of the 0.25 N sulfuric acid is 0.95 ± 0.05, adjust the meter to the nominal value of 0.95 and proceed to step 4. b. If the pH is not 0.95, repeat the procedure using another glass electrode. 4. Rinse the electrodes and lower the assembly into the stop bath solution. Set a timer for two minutes. At the end of two minutes record the pH of the stop bath. If another stop bath pH measurement is to be made, repeat the procedure. Processing KODAK Motion Picture Films, Module 3, Analytical Procedures H24.03 1

CALCULATIONS<br />

For Sodium Persulfate, g/L<br />

g/L Na 2S 2O 8 =<br />

Where:<br />

(mLs B - mLs A) (N cerate) (eq wt Na 2 S 2 O 8 )<br />

mL Sample<br />

mLs B = volume of sulfato cerate in milliliters required to<br />

reach the equivalence point without the<br />

addition of sample (Blank)<br />

mLs A = volume of sulfato cerate in milliliters required to<br />

reach the equivalence point with the addition of<br />

sample<br />

N cerate = normality of the sulfato cerate in<br />

milliequivalents per milliliter (meq/mL)<br />

eq wt Na 2 S 2 O 8 = equivalent weight of sodium persulfate in<br />

milligrams per milliequivalent<br />

(119.05 mg/meq)<br />

mL Sample = volume of sample pipetted in step 1 of part A of<br />

procedure<br />

If mL 0.0497 N sulfato cerate = 32.85 mLs<br />

g/L Na 2S 2O 8 =<br />

g/L Na 2 S 2 O 8 = 20.18<br />

mLs Blank = 49.90 mLs<br />

(49.90 - 32.85) (0.0497) (119.05<br />

5.00<br />

4 <strong>Processing</strong> KODAK Motion Picture Films, Module 3, Analytical Procedures H24.03

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