Processing kodak motion picture films, module 3 analytical procedures
Processing kodak motion picture films, module 3 analytical procedures Processing kodak motion picture films, module 3 analytical procedures
CALCULATIONS For Sodium Persulfate, g/L g/L Na 2S 2O 8 = Where: (mLs B - mLs A) (N cerate) (eq wt Na 2 S 2 O 8 ) mL Sample mLs B = volume of sulfato cerate in milliliters required to reach the equivalence point without the addition of sample (Blank) mLs A = volume of sulfato cerate in milliliters required to reach the equivalence point with the addition of sample N cerate = normality of the sulfato cerate in milliequivalents per milliliter (meq/mL) eq wt Na 2 S 2 O 8 = equivalent weight of sodium persulfate in milligrams per milliequivalent (119.05 mg/meq) mL Sample = volume of sample pipetted in step 1 of part A of procedure If mL 0.0497 N sulfato cerate = 32.85 mLs g/L Na 2S 2O 8 = g/L Na 2 S 2 O 8 = 20.18 mLs Blank = 49.90 mLs (49.90 - 32.85) (0.0497) (119.05 5.00 4 Processing KODAK Motion Picture Films, Module 3, Analytical Procedures H24.03
Determination of the pH of the Eastman Color Print-2 Stop Bath ECP-2-890 Process ECN-2 ECP-2D VNF-1/LC RVNP Formulas — SB-14 — — INTRODUCTION Exposure of the electrodes to the low pH of the stop bath causes improper electrode response when the same electrodes are used to measure the pH of more alkaline solutions. A separate set of electrodes should be used for measurement of stop bath pH. Sulfuric acid, 0.25 N, (pH 0.95 ± 0.05) is used as a reference solution in measuring stop bath pH. The electrodes and meter are first standardized with potassium acid phthalate buffer (pH 4.010 at 27°C). The pH of the 0.25 N sulfuric acid is then measured. If the pH value for the 0.25 N sulfuric acid is 0.95 ± 0.05, the meter is adjusted to the nominal value of 0.95 and the pH of the stop bath is measured. Stop bath pH is measured at 27 ± 5°C. SPECIAL APPARATUS Corning Model 12 Research pH Meter or equivalent Corning No. 476024 Glass Electrode or Leeds and Northrup No, 117169 Glass Electrode Beckman Fiber Junction Calomel Electrode, No. 39170 (filled with 3.5 N potassium chloride) REAGENTS Use reagents that are ACS Reagent Grade unless specified otherwise. Potassium Acid Phthalate Buffer, 0.05 M Sulfuric Acid, 0.25 N PROCEDURE 1. Follow the Standardization of pH Meter - Low pH Range procedure in Method ULM-191-2, pH Measurement of Photographic Processing Solutions, (or any subsequent pH method) for preparation of the meter. 2. Rinse the electrode assembly with distilled water and immerse the electrodes in potassium acid phthalate buffer. Set a timer for two minutes. At the end of the two minutes standardize the meter at pH 4.010. 3. Rinse the electrode assembly with distilled water and lower the electrodes into 0.25 N sulfuric acid solution in a 150-mL beaker. Set a timer for two minutes. At the end of two minutes the pH should be 0.95 ± 0.05. a. If the pH of the 0.25 N sulfuric acid is 0.95 ± 0.05, adjust the meter to the nominal value of 0.95 and proceed to step 4. b. If the pH is not 0.95, repeat the procedure using another glass electrode. 4. Rinse the electrodes and lower the assembly into the stop bath solution. Set a timer for two minutes. At the end of two minutes record the pH of the stop bath. If another stop bath pH measurement is to be made, repeat the procedure. Processing KODAK Motion Picture Films, Module 3, Analytical Procedures H24.03 1
- Page 129 and 130: Buffering Capacity Determination of
- Page 131 and 132: Buffering Capacity Determination of
- Page 133 and 134: Titrimetric Determination of EASTMA
- Page 135 and 136: VISUAL TITRATION STATISTICS Repeata
- Page 137 and 138: Titration of the Developing Agent w
- Page 139 and 140: Cerimetric Determination of CD-2 Co
- Page 141 and 142: Cerimetric Determination of KODAK C
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- Page 149 and 150: CALCULATIONS For Na3Fe(CN) 6 g/L Na
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- Page 163 and 164: Recovery Recovery is used instead o
- Page 165 and 166: B. Thiosulfate Determination 1. Sam
- Page 167 and 168: Examples: Titration mL 0.1 N Na 2S
- Page 169 and 170: Potentiometric Determination of Pot
- Page 171 and 172: APPARATUS All volumetric glassware
- Page 173 and 174: Potentiometric Determination of Kod
- Page 175 and 176: PROCEDURE A. Preparation of Sample
- Page 177 and 178: Titrimetric Determination of Persul
- Page 179: APPARATUS Conical Flask with stoppe
- Page 183 and 184: Determination of the pH of Processe
- Page 185 and 186: Potentiometric Determination of Sil
- Page 187 and 188: APPARATUS METROHM 536 Titrator or e
- Page 189 and 190: Determination of Sodium Metabisulfi
- Page 191 and 192: II. Visual Endpoint Titrations A. R
- Page 193 and 194: APPARATUS METROHM 536 Titrator or e
- Page 195 and 196: Viscosity Determination of Sound-Tr
- Page 197 and 198: Titrimetric Determination Of Benzyl
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- Page 201 and 202: PROCEDURE B For Seasoned Tank Note:
- Page 203 and 204: Potentiometric Determination of Bro
- Page 205 and 206: CALCULATIONS mL AgNO 3 that would b
- Page 207 and 208: Titrimetric Determination of Buffer
- Page 209 and 210: Potentiometric Determination of Kod
- Page 211 and 212: Spectrophotometric Determination of
- Page 213 and 214: Titrimetric Determination of Citraz
- Page 215 and 216: Potentiometric Determination of Eth
- Page 217 and 218: Titrimetric Determination of Ferric
- Page 219 and 220: Iodometric Determination of Ferricy
- Page 221 and 222: Potentiometric Determination of Fer
- Page 223 and 224: Iodometric Determination of Formali
- Page 225 and 226: Spectrophotometric Determination of
- Page 227 and 228: Titrimetric Determination of Hypo I
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CALCULATIONS<br />
For Sodium Persulfate, g/L<br />
g/L Na 2S 2O 8 =<br />
Where:<br />
(mLs B - mLs A) (N cerate) (eq wt Na 2 S 2 O 8 )<br />
mL Sample<br />
mLs B = volume of sulfato cerate in milliliters required to<br />
reach the equivalence point without the<br />
addition of sample (Blank)<br />
mLs A = volume of sulfato cerate in milliliters required to<br />
reach the equivalence point with the addition of<br />
sample<br />
N cerate = normality of the sulfato cerate in<br />
milliequivalents per milliliter (meq/mL)<br />
eq wt Na 2 S 2 O 8 = equivalent weight of sodium persulfate in<br />
milligrams per milliequivalent<br />
(119.05 mg/meq)<br />
mL Sample = volume of sample pipetted in step 1 of part A of<br />
procedure<br />
If mL 0.0497 N sulfato cerate = 32.85 mLs<br />
g/L Na 2S 2O 8 =<br />
g/L Na 2 S 2 O 8 = 20.18<br />
mLs Blank = 49.90 mLs<br />
(49.90 - 32.85) (0.0497) (119.05<br />
5.00<br />
4 <strong>Processing</strong> KODAK Motion Picture Films, Module 3, Analytical Procedures H24.03