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BIOSORPTION OF Pb2+, Cd2+, & Ni2+ FROM WATERS BY ...

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1.6.1.2. Entrapment in Polymeric Matrices<br />

The polymers matrices used are calcium alginate (Babu et al. 1993, Costa and<br />

Leite, 1991, Peng and Koon, 1993, Gulay Bayramoglu et al. 2002), polyacrylamide<br />

(Macaskie, et al. 1987), polysulfone (Veglio, et al. 2003, Bai and Abraham 2003).<br />

Gel particles are obtained from immobilization in calcium alginate and<br />

polyacrylamide. The materials obtained from immobilization in polysulfone and<br />

polyethyleneimine are the strongest.<br />

1.6.1.3. Covalent Bonds to Vector Compounds<br />

Silica gel is the most common vector compound (carrier). In this technique,<br />

the form of materials are gel type particles. It is generally utilized for algal<br />

immobilization (Holan, et al. 1993).<br />

1.6.1.4. Cross-Linking<br />

The addition of the cross-linker leads to the formation of stable cellular<br />

aggregates. This technique was found useful for the immobilization of algae (Holan,<br />

et al. 1993, Valdman and Leite 2000). The most common cross linkers are:<br />

formaldehyde, glutaric dialdehyde, divinylsulfone and formaldehyde - urea mixtures.<br />

1.7. Aim of this Study<br />

The aim of this study was primarily based on the biosorption of aqueous Pb 2+ ,<br />

Cd 2+ , and Ni 2+ by the algae (biosorbents) such as Dunaliella salina, Oocytis sp.,<br />

Poprhyridium cruentum, and Scenedesmus protuberans and investigate the<br />

biosorption ability of the biosorbents towards the metal ions.<br />

In this sudy, biosorption experiments were with respect to the pH of the metal<br />

ion solution, sorption time, initial metal ion concentration, and the amount of the<br />

biosorbent used. The desorption of the metals from the biosorbents and the repetitive<br />

usability of the biosorbents were also studied. In addition, competitive performance<br />

of the metals were also studied in the presence of the other metal ions.<br />

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