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BIOSORPTION OF Pb2+, Cd2+, & Ni2+ FROM WATERS BY ...

BIOSORPTION OF Pb2+, Cd2+, & Ni2+ FROM WATERS BY ...

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3. The metal removal is influenced by the biomass concentration in solution. The<br />

lower quantities of biomass is enough to sequester the metals from the<br />

solution, if the amount of biomass is increased it influences the solution<br />

chemistry of the metals, the activity of the functional groups in the biomass,<br />

and also the compettion between metallic ions. This phenomenon can be<br />

attributed to the interference between the binding sites. This parameter should<br />

be undertaken once biosorption is considered for the removal of metals.<br />

4. Biosorption is utilized to treat wastewater if more than one type of metal ions<br />

would be present. Hence, the presence of other interfering ions can decline the<br />

uptake of the metal which is interested in. In contrast, the presence of Fe 2+ and<br />

Zn 2+ was found to influence uranium uptake by Rhizopus arrhizus (Tsezos<br />

and Volesky 1982) and cobalt uptake by different microorganisms seemed to<br />

be completely inhibited by the presence of uranium, lead, mercury and copper<br />

(Volesky 2007).<br />

5. Cell size and structure , and morphology and also affects the amounts of<br />

metal biosorbed by different biomasses. The greater the cell surface area to<br />

dry weight ratio, the greater the quantity of metal biosorbed by a cell surface<br />

per unit weight.<br />

1.4.3. Advantages of Biosorption<br />

Biosorption has several superiorities over the traditional metal removal<br />

methods that makes it is to be more preferential:<br />

1. Cheap: The cost of biosorbents is low as they often are made from abundant<br />

or waste materials.<br />

2. Metal selective: The metal-sorbing preformance of different types of biomas<br />

can be more or less on different metals. This depends on various factors such<br />

as type of biomass, mixture in the solution, and the type of biomass<br />

preparation.<br />

3. Regenerative: Biosorbent can be reused after the metal is recycled.<br />

4. No sludge generation: No secondary problems with sludge occurs with<br />

biosorption as in the case with many other metal removal technologies.<br />

12

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