MATERIAL SAFETY DATA SHEET – MSDS Product Name ... - WEG
MATERIAL SAFETY DATA SHEET – MSDS Product Name ... - WEG
MATERIAL SAFETY DATA SHEET – MSDS Product Name ... - WEG
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<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong> <strong>–</strong> <strong>MSDS</strong><br />
<strong>Product</strong> <strong>Name</strong>: DILUENT POLI W 1104 EXP<br />
Last revision date:10/12/08 Page: 1 / 7<br />
<strong>Product</strong> <strong>Name</strong>:<br />
1. PRODUCT AND COMPANY IDENTIFICATION<br />
DILUENT POLI W 1104 EXP<br />
Code:<br />
10990968 (20 L)<br />
10254052 (200 L)<br />
Company <strong>Name</strong> : <strong>WEG</strong> Tintas Ltda<br />
Address:<br />
Rodovia BR 280, Km 50<br />
CEP 89270-000 - Guaramirim <strong>–</strong> SC<br />
Phone Number: (47) 3276-4000<br />
Fax Number: (47) 3276-5500<br />
In case of emergency : (11) 5012-5311 (Intoxication Control Center )<br />
E-mail / site: tintas@weg.net - www.weg.net<br />
Type of <strong>Product</strong> :<br />
2. COMPOSITION AND INFORMATION ON INGREDIENTS<br />
Chemical preparation<br />
Chemical nature : <strong>Product</strong> based in solvent .<br />
Hazardous Ingredient(s):<br />
Chemical <strong>Name</strong><br />
CAS<br />
Registry<br />
Number<br />
Concentration Synonyms Risk Classification<br />
Xylene 1330-20-7 40 - 60%<br />
Dimethyl benzene;<br />
Methyl toluene<br />
T, F + , Xn, Xi<br />
n-metil pirolidona 872-50-4 50- 70% N-metil-2-pirolidona Xi<br />
Classification system :<br />
The ingredients had beem classified in accordance with the directive<br />
67/548/EEC .<br />
3. HAZARDOUS IDENTIFICATION<br />
Principal Hazardous :<br />
Toxic product for contact with the skin and ingest ion. Cause burning.<br />
Inflammable <strong>Product</strong> : Toxicity of vapors.<br />
<strong>Product</strong> effect of human health :<br />
Ingestion:<br />
It can cause irritation on the mouth and troat, gastrointestinal disturbs .<br />
Eyes:<br />
May cause burning.<br />
Inhalation:<br />
It can cause irritation in the thro at and nose, respiratory tract .<br />
Skin:<br />
Cause burning. It can cause burning or irritation and dermatitis in contact .<br />
Specific Hazards :<br />
Inflammab le liquid: when it was warm abo ve your point of loom, this material Will release toxic vapor and flame,<br />
and could be burn in the open ar ea if on show in one source of ignition.<br />
Environment effect<br />
Harmful to the fauna and the flora. It contaminates the water way.<br />
4. FIRST AID MEASURES<br />
First aid measures<br />
Call to the CCI <strong>–</strong> Intoxication Control Center if a ny doubt or necessity of more information. Phone: (55) (0xx 11)<br />
5012 -5311 (Available 24 hours a Day).<br />
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If<br />
Inhalation:<br />
breathing is difficult, give oxygen. Call a doctor. Do not give anything orally. Take<br />
the label of product when possible.<br />
<strong>WEG</strong> TINTAS<br />
Rodovia BR 280, Km 50 - Fone: (47) 3276-4000 - Fax: (47) 3276-5500 - CEP 89270-000 - Guaramirim <strong>–</strong> SC<br />
EMERGÊNCIA: (11) 5012 -5311 - E-mail: tintas@weg.net - www.weg.net
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong> <strong>–</strong> <strong>MSDS</strong><br />
<strong>Product</strong> <strong>Name</strong>: DILUENT POLI W 1104 EXP<br />
Last revision date:10/12/08 Page: 2 / 7<br />
After skin contact :<br />
After eye contact :<br />
Remove exposed or contaminated material. Remove product with vegetal oil<br />
(coking oil). Wash contaminated skin with plenty water. Do not wash<br />
contaminated skin with thinner or solvent. Seek medical attention if any skin<br />
irritation or adverse reaction or other symptoms occurs.<br />
In case of contact, immediately flush eyes with plenty of water for at last 15<br />
minutes. Remove contact lens, if any. Victim must see k immediate medical<br />
attention. Take copy of label and <strong>MSDS</strong> to health professional with victim, if<br />
possible. Call physician.<br />
After ingestion: Do not induce vomit. Call a doctor immediately .<br />
Action to be prevented:<br />
Induce vomit.<br />
Brief description o f the main symptoms and effects :<br />
Headaches, dizziness, fat igue, and in extreme cases, uncon sciousness.<br />
Notes to the doctor :<br />
Make symptomatic treatment . Do not induce vomiting . The gastric-cleaning is indicate when the pacient intromit<br />
a big quantity, m ore than 5 ml of the substance in the pure form . The toxic potencial of quantity intromited must<br />
be valued according to the risk of aspiration of the gastric -cleaning. The ativate coal in solution must be useful.<br />
However, in same cases the coal induce vomi ting.<br />
5. FIRE FIGHTING MEASURES<br />
Fire fighting measures:<br />
Water Spray, Foam, Dry Chemical, CO2.<br />
For safeting reasons unsuitable extinguishing agents :<br />
Water jet, extintor de gás carbônico.<br />
Specific Risks:<br />
The fine particles dispense will take fo rm to the explosive mixtures in the air . In case of fire or dense black<br />
fumes, the harmful decomposition products inhalation can provoke health problems.<br />
Especial Methods :<br />
Refresh closed receptacles arou nd the fire. Evacuate the area and combat the fir e at a safe distance. Use dikes<br />
to contain the water used in the combat and eliminate it according to the local legislation. Use water under fog<br />
form to cool the recipients exposed to the fire. In case of intense fire in stor age area, use rubber hoses hand led<br />
at distance.<br />
Firefighter protection :<br />
Firefighters m ust wear self-contained breathing apparatus and full protective equipment.<br />
6. SPILL / LEAK CONTROL PROCEDURES<br />
Personal protective equipment :<br />
Proper personal prot ective equipment should be use d. Evacuate immediate area. Avoid inhalation of fogs/vapor<br />
and direct contact with product. Do not smoke.<br />
Eliminate all sources of ignition :<br />
Eliminate and/or isolate all sources of ignition. Signal and ventilate area of<br />
spill. Use non-sparking tools.<br />
Dust control: Not applicable, since it is a liquid product.<br />
Prevention of inhalation, skin<br />
absorption, contact with eyes<br />
and mucous membranes :<br />
Proper personal protective equipment should be used, such as: face<br />
mask with OV filter (Organic Vapors) and goggles.<br />
Environment protection :<br />
Prevent material or firef ighting waste wat er from entering into sewer and rive r beds. In case of si gnificant sp ill,<br />
retain spilled liquid with inert material, such as sand or e arth. If suitable, absorb spilled liqui d with absorbent<br />
<strong>WEG</strong> TINTAS<br />
Rodovia BR 280, Km 50 - Fone: (47) 3276-4000 - Fax: (47) 3276-5500 - CEP 89270-000 - Guaramirim <strong>–</strong> SC<br />
EMERGÊNCIA: (11) 5012 -5311 - E-mail: tintas@weg.net - www.weg.net
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong> <strong>–</strong> <strong>MSDS</strong><br />
<strong>Product</strong> <strong>Name</strong>: DILUENT POLI W 1104 EXP<br />
Last revision date:10/12/08 Page: 3 / 7<br />
materials, such as sawdust, cotton waste or other suitable materials<br />
Cleaning Procedures :<br />
Recovery:<br />
Elimination:<br />
HANDLING<br />
Technical Measures<br />
Exposure Control <strong>–</strong><br />
Personal Protection :<br />
Fire and Exp losion<br />
Prevention:<br />
Safe Handling<br />
Precaution:<br />
Safe Handling Information :<br />
Remove contaminated diking mater ial with a vacuum-truck and transfer it to an<br />
emergency tank. Eart h all used equipment. Maintain p roduct in closed emergency<br />
containers prope rly labeled for later recovery or disposal.<br />
Incinerate all contamin ated material in authorized plant. Do not pour the product into<br />
sewers. The final disposal of this material should be followed -up by disposal experts<br />
and made in accordance with the environmental regulations.<br />
7. HANDLING AND STORAGE<br />
The use of face mask with OV filter (Org anic Vapors) is recommended . Use<br />
appropriate eye protect ion in case of eventual chemical splash eye contact exists.<br />
Wear rubber gloves to avoid direct conta ct of the product with the skin.<br />
Adequate local exhausting ventilation should be provided t o keep vapor<br />
concentration below explosive limits. All conductive parts of the system in contact<br />
with the product shall be grou nded electrically. Do not smoke in the working area.<br />
Handling of the product respecting the rules of security and industrial hygiene .<br />
Emergency shower and eyes washer must be installed in areas of use and<br />
storage.<br />
§ Prevent contact with the skin, mucosa, eyes and vapor inhalation;<br />
§ Do not reuse the packing;<br />
§ Do not smoke, eat or drink in the storage area.<br />
§ Wash the hands after handling.<br />
§ Store in a cool, dry area far from high temperatures, flames and oxidizers .<br />
STORAGE<br />
Technical appropriate measures :<br />
The electrical installation must meet the requirements of the stand ards NEC (National Electrical Code) or IEC<br />
(Internationa l Electrical Commission) and/or ABNT (Brazilian Association of Techni cal Standards). The floor of<br />
the storage area must be waterproof, not combustible and shall be provided with outfall ditches for dr aining the<br />
product to damming tanks. Stora ge tanks must be surrounded by damming tanks and fitted with draining devices<br />
to enable fast drainage in case of leakage .<br />
Storage Conditions :<br />
Suitable:<br />
Avoid:<br />
Non-compatible<br />
<strong>Product</strong>s and Materials :<br />
Store the product in a dry, well -ventilated covered are a with good marking. Keep<br />
this product away from heat and sparking sources, away from foods and strong<br />
oxidizer. Keep conta iners always closed and w ell identified.<br />
Avoid to exposing the product to high temperatures, rain or direct sunlight<br />
Exposure.<br />
Do not store with explosive materials, inflammable and/or toxic gases, oxidants<br />
substances, corrosive and material that can suffer spontaneous combustion .<br />
Safe materials for packaging :<br />
Recommended : Metallic and/or amber type glass containers<br />
Inadequate: Some plastic materials .<br />
<strong>WEG</strong> TINTAS<br />
Rodovia BR 280, Km 50 - Fone: (47) 3276-4000 - Fax: (47) 3276-5500 - CEP 89270-000 - Guaramirim <strong>–</strong> SC<br />
EMERGÊNCIA: (11) 5012 -5311 - E-mail: tintas@weg.net - www.weg.net
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong> <strong>–</strong> <strong>MSDS</strong><br />
<strong>Product</strong> <strong>Name</strong>: DILUENT POLI W 1104 EXP<br />
Last revision date:10/12/08 Page: 4 / 7<br />
8. EXPOSURE CONTROL/PERSONAL PROTECTION<br />
Engineering Controls<br />
Provide suitable ventilation. Maintain product concentration level below recommended tolerances (T.L.).<br />
Otherwise, use suitable breathing mask.<br />
Specific Control Parameters :<br />
Recommended monitoring<br />
procedures:<br />
Occupational Exposure Limit :<br />
In areas where chemical products are handled, you must monit or the<br />
people exposure according to (PPRA), (Environmental Risk Prevention<br />
Program) from NR-9.<br />
<strong>Name</strong> TLV/TWA (ppm) TLV/STEL (ppm) TLV/TETO (ppm)<br />
n-metil pirolidona 10/8horas - -<br />
Xylene 100 150 -<br />
Suitable individual personal protection equip ment:<br />
Use respiratory mask with organic vapour f ilter whenever concentration is infe rior<br />
to the tolerance limit and there is not oxygen deficiency. Whenever concentration<br />
Proteção respiratória:<br />
is superior to the tolerance limit and/or t here is oxygen deficiency use mask with<br />
organic vapour and air supplement.<br />
Hand Protection:<br />
When exposure is prolonged and repeated, wear nitrile rubber gloves. Protection<br />
creams may be used for protecti ng exposed skin areas (never use these creams<br />
after exposure).<br />
Eye Protection: Use hermetic goggles for pro tecting eyes against splash es.<br />
Skin and Body Protection:<br />
Wear antistatic clothes made of natural fibers and/or made of synthetic fibers<br />
resistant to high temperatures. If the product contacts the skin, begin<br />
immediately decontamination area with running water.<br />
Special precaut ions:<br />
Only well trained people should ha ndle chemical products. The EPI’s should be Approval Certified. When<br />
chemical product is handled, follow strictly all recommended operational and safety instructions inform ed by the<br />
manufacturer of the chemical prod uct. Never reuse empty containers of chemical products for storing foods.<br />
Monitor the people exposure in area where chemical products are handled. Adopted monitoring procedure shall<br />
be in accordance with PPRA (Environmental Risk Prevention Program) from NR -9.<br />
Hygiene Measures :<br />
Clean clothes and shoes thoroughly after use. General control methods app lie d in Industrial Hyg iene should<br />
minimize product exposure. Do not smoke, consume food or drinks when che mical products are handled.<br />
9. PHYSICAL AND CH EMICAL PROPERTIES<br />
Physical state : Liquid<br />
Color: transparent<br />
Smell: Characteristic<br />
pH: Not applicable, non -aqueous solvent<br />
Specific temperatures or temperature ranges where occurs changes in the physical state :<br />
Melting Point (°C): N.d.<br />
Decomposition Temperature (°C): N.d.<br />
Flash Point (close cup °C): 29<br />
Self-ignition Temperature (°C): 400 - 500<br />
Density, 25°C: 0,98 ±0,03 g/cm 3<br />
Solubility: non-water soluble<br />
Octanol/water division coefficient : N.d.<br />
The information indicated abo ve was derived from components present in higher concentrat ion levels.<br />
Specific Conditions :<br />
10. STABILITY AND RECTIVITY<br />
Instability: Stable under normal ambient and anticipated storage and handling<br />
<strong>WEG</strong> TINTAS<br />
Rodovia BR 280, Km 50 - Fone: (47) 3276-4000 - Fax: (47) 3276-5500 - CEP 89270-000 - Guaramirim <strong>–</strong> SC<br />
EMERGÊNCIA: (11) 5012 -5311 - E-mail: tintas@weg.net - www.weg.net
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong> <strong>–</strong> <strong>MSDS</strong><br />
<strong>Product</strong> <strong>Name</strong>: DILUENT POLI W 1104 EXP<br />
Last revision date:10/12/08 Page: 5 / 7<br />
Dangerous reactions :<br />
conditions of temperature and pressure. Instable in temperature abo ve<br />
the flash point .<br />
No dangerous rea ction occurs when product is store d, handled and<br />
processed correctly.<br />
Conditions to be avoid :<br />
Avoid exposing product to extremely high temperatures and to open flames .<br />
Material with which pr oduct is incompatible:<br />
Not to store with explosive materials, inflammable and/or toxic gases, oxidantes, corro sive and material<br />
substances that can suffer spontaneous combustion.<br />
Requirement for addition of additives and inhibitors :<br />
Not required.<br />
Dangerous decomposition products :<br />
In high temperatures (above of 300°C) can result dangerous products of decomposition as dioxide of carbon and<br />
smoke.<br />
11. TOXICOLOGICAL INFORMATION<br />
Information in accordance with the different exposure conditions :<br />
Acute Toxicity<br />
Chronic Toxicity:<br />
The exposition of solvent vapors of the components in superior concentrations to the<br />
applicable limits of occupational exposition can have an adverse effect to the health, as<br />
irritation of t he mucous and the respiratory tract, harmful effect in the kidneys, liver an d<br />
central nervous systems. The symptoms include headache, confusion, dizziness and<br />
unconsciousness. May cause dermatitis on contact and absorption by skin. The product<br />
that sneeze in the eyes can cause irritation. Toxic produ ct.<br />
Xylene N-metil-pirolidona<br />
rat, oral: 4300 mg/kg rat, oral: 3600 mg/kg<br />
DL50 rabbit, dermal: > 1700 rabbit, dermal:<br />
mg/kg<br />
8000mg/kg<br />
CL50<br />
rat, inhalation: 5000<br />
ppm por 4 horas<br />
rat, inhalation: 5,1mg/l<br />
por 4 horas<br />
A4 <strong>–</strong> Non classified as A4 <strong>–</strong> Non classified as<br />
Carcinogenicity carcinogenic for carcinogenic for<br />
human<br />
human<br />
Mutagenicity<br />
Non classified as<br />
mutagenic product<br />
Non classified as<br />
mutagenic product<br />
Teratogenicity<br />
Non classified as<br />
Teratogenic <strong>Product</strong><br />
Non classified as<br />
Teratogenic <strong>Product</strong><br />
Prolonged contact of the product with the skin removes the oil from the skin and may<br />
cause skin fissures, dryness , dermatitis and eczema. The most common disturbs<br />
relating to Toluene are fat igue, headaches, irritability, dizziness, fat igue, weakness,<br />
unconsciousness, som nolence, humming, humor and equilibrium disturbs, nauseas and<br />
appetite loss. Also the respiratory system may be affected by chronic bronchitis and<br />
reduction of the breathing volume. The product may also cause infertility , fetal<br />
abnormalities, and renal pathologies in kids whose mothers have been exposed to t he<br />
product. Exposure of pregnant women to concentrations above the tolerance limits may<br />
cause miscarriage. The product may also cause anemia and affect the central<br />
nervoussystem a nd the peripheral nervous system , causing vascular and nervous<br />
injuries,headaches, irritability, visual disturbs, uncons ciousness, wild, convulsion, lost<br />
themotor s and sensorial functions. Toxi c to kidney and digestive disturbs.<br />
12. ECOLOGICAL INFORMATION<br />
<strong>Product</strong> behavior a nd impact on the environ ment:<br />
As the product is not totally biodegradable, do not contaminate sewer and river beds, soils and watercourses.<br />
Bioacummulation: <strong>Product</strong> is not potentially bioaccumulative .<br />
<strong>WEG</strong> TINTAS<br />
Rodovia BR 280, Km 50 - Fone: (47) 3276-4000 - Fax: (47) 3276-5500 - CEP 89270-000 - Guaramirim <strong>–</strong> SC<br />
EMERGÊNCIA: (11) 5012 -5311 - E-mail: tintas@weg.net - www.weg.net
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong> <strong>–</strong> <strong>MSDS</strong><br />
<strong>Product</strong> <strong>Name</strong>: DILUENT POLI W 1104 EXP<br />
Last revision date:10/12/08 Page: 6 / 7<br />
Ecotoxicity: The product is harmful to fauna and flora. It contaminates ground waters .<br />
13. DISPOSAL AND TREATMENT CONSIDERATIONS<br />
Treatment Methods for Disposal<br />
Do not discard the product into sewers, rivers, lakes and watercourses. Dispose it in<br />
<strong>Product</strong>:<br />
landfills or incinerate it in accordance with the local regulations.<br />
<strong>Product</strong> residues:<br />
Do not discard the product residues in watercourses. Dispose it in landfills or<br />
incinerate it in accordance with the local regulations.<br />
Used containers : Discard them in authorized installation. Do not reuse empty containers .<br />
14. TRANSPORTATION INFORM ATION<br />
National and International Reg ulations:<br />
Truck/rail<br />
ONU 1263<br />
Hazard Category 3<br />
Hazard Class Number 30<br />
Packing Group III<br />
Proper Shipping <strong>Name</strong> Paint<br />
Ocean<br />
IMDG/GGVsea/ONU 1263<br />
Hazard Category 3<br />
Hazard Class Number 30<br />
Packing Group III<br />
EMS F-E,S-E<br />
Air<br />
ONU 1263<br />
Hazard Category 3<br />
Hazard Class Number 30<br />
Packing Group III<br />
Proper Shipping <strong>Name</strong> Paint<br />
15. REGULATORY INFORMATION<br />
Information about hazard and safety as indicated on label :<br />
<strong>Product</strong> is labeled in accordance with decree law 120/92 dated 06.30.92 and administrative ruling 1164/92 dated<br />
12.18.92.<br />
Hazard Class:<br />
Inflammable<br />
16. ADDITIONAL INFORMATION<br />
Used Abbreviations<br />
Glossary:<br />
F + Highly inflammable<br />
T Toxic<br />
Xn harmful<br />
Xi Irritant<br />
N Harmful to the environment<br />
CAS Chemical Abstr act Service<br />
VO Organic vapors<br />
NEC National Electrical Code<br />
IEC International Electrical Commis sion<br />
ABNT Brazilian Association of Technical Standards<br />
ACGIH American Conference of Governmental Industrial Hygienists<br />
TLV Threshold Limit Value<br />
TLV/TWA Threshold Limit Value/Time Weighted Average<br />
<strong>WEG</strong> TINTAS<br />
Rodovia BR 280, Km 50 - Fone: (47) 3276-4000 - Fax: (47) 3276-5500 - CEP 89270-000 - Guaramirim <strong>–</strong> SC<br />
EMERGÊNCIA: (11) 5012 -5311 - E-mail: tintas@weg.net - www.weg.net
<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong> <strong>–</strong> <strong>MSDS</strong><br />
<strong>Product</strong> <strong>Name</strong>: DILUENT POLI W 1104 EXP<br />
Last revision date:10/12/08 Page: 7 / 7<br />
TLV/STEL Short Term Exposure Limit<br />
TLV/C Threshold Lim it Value / upper limit<br />
EPI Personal protective equipment<br />
CA Approval Certification<br />
PPRA Pre vention Program for Environment Hazard<br />
NR Regulatory Standard<br />
NFPA National Fire Protection Agency<br />
mmHg Millimeters of mercury <strong>–</strong> pressure unit<br />
DL50 Lethal average dose<br />
CL50 Average lethal concentration<br />
ppm parts per m illion<br />
N. A. Not available<br />
The information contained here is based on our current knowledge on the product and is in accordance with<br />
standard NBR 14725. Howe ver the working conditions adopted by the user are out of our knowledge and<br />
control. The product should not be used for other purposes, without previous written authorization by<br />
manufacturer than its application through the current available and proven sui table methods. User is responsible<br />
for meeting all regulatory requirements.<br />
<strong>WEG</strong> TINTAS<br />
Rodovia BR 280, Km 50 - Fone: (47) 3276-4000 - Fax: (47) 3276-5500 - CEP 89270-000 - Guaramirim <strong>–</strong> SC<br />
EMERGÊNCIA: (11) 5012 -5311 - E-mail: tintas@weg.net - www.weg.net