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Cargill Township carbonatite complex, District of ... - Geology Ontario

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R. P. SAGE<br />

cores to magnesio-arfvedsonite rims. The amphibole composition is richer in Fe<br />

and alkalies and poorer in Ca and Mg as differentiation proceeds (Twyman 1983,<br />

p. 103). Twyman (1983, p. 100) reported little or no Mn, Ti, and Al in the amphi-<br />

boles. At <strong>Cargill</strong> the K content <strong>of</strong> the amphiboles was observed to increase with<br />

differentiation (Twyman 1983, p. 146).<br />

Allen (1972, p.105) reported rare zircon, diopside, and ankerite in this rock<br />

unit. Rare zircon and very rare pyrochlore were reported by Twyman (1983,<br />

p.97, 140). Probe analysis <strong>of</strong> this rare pyrochlore indicates Ta, U, and light rare<br />

earth elements increase and Nb and Ca decrease from core to rim (Twyman<br />

1983, p. 143). Twyman (1983, p. 143) correlated the pyrochlore at <strong>Cargill</strong> with<br />

the early formed pyrochlore found at the nearby Argor <strong>carbonatite</strong>.<br />

Sharpe (1987) completed microprobe analyses on both the carbonate and<br />

mafic silicate phases. Microprobe analysis <strong>of</strong> one sample from International Min<br />

erals and Chemical Corporation Limited diamond drill hole 23, drilled in the<br />

centre <strong>of</strong> the southern <strong>complex</strong> indicated the presence <strong>of</strong> vesuvianite (Sharpe<br />

1987, p.27). This is the first known occurrence <strong>of</strong> vesuvianite within a car<br />

bonatite <strong>of</strong> which the author is aware. Sharpe (1987, p.26, 27, 32, 37, 38, 43,<br />

44, 54) presented in tabular form considerable microprobe and chemical data on<br />

the <strong>Cargill</strong> <strong>carbonatite</strong> to which the reader may wish to refer.<br />

Silico<strong>carbonatite</strong><br />

With increasing accessory mineral content, sovite grades into Silico<strong>carbonatite</strong>. In<br />

thin section the Silico<strong>carbonatite</strong> is fine to medium grained, equigranular, hypid<br />

iomorphic to allotriomorphic, with straight to curved grain boundaries.<br />

An estimate <strong>of</strong> the mode is 5 to 5596 phlogopite, l to 3096 magnetite, O to<br />

1096 clinohumite, 15 to 5096 carbonate, O to 596 apatite, O to 3096 olivine, and 2<br />

to 7096 amphibole.<br />

Phlogopite forms anhedral to subhedral grains, and commonly displays a<br />

darker reddish brown rim similar to that observed in the sovite. Some grains<br />

display kinking or bending <strong>of</strong> the (001) cleavage.<br />

Magnetite forms anhedral to subhedral grains. The magnetite occurs as dis<br />

seminated grains and also as granular aggregates.<br />

Clinohumite occurs as anhedral grains along fractures within, and along grain<br />

boundaries <strong>of</strong> olivine. The clinohumite has a distinctive yellow color in thin sec<br />

tion.<br />

Carbonate grains form an anhedral interlocking mosaic. Twin planes on the<br />

carbonate grains may be bent in those samples displaying cataclastic textures.<br />

Apatite occurs as rounded bead-like grains and as rounded elongated grains.<br />

Olivine occurs as anhedral to crudely euhedral grains. Trace to minor serpen<br />

tine may also be present.<br />

Amphibole occurs as acicular crystals with a pale green color. Slight changes<br />

in birefringence between core and rims <strong>of</strong> some grains suggests that the amphi<br />

bole may, at least locally, be compositionally zoned.<br />

Rauhaugite<br />

Within the central zone <strong>of</strong> the <strong>complex</strong>, dolomite becomes the most abundant<br />

carbonate phase. The presence <strong>of</strong> dolomite was confirmed by X-ray diffraction<br />

by W. Hicks, Geoscience Laboratories, <strong>Ontario</strong> Geological Survey. The<br />

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