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2011 - Cooperative Institute for Research in Environmental Sciences ...

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INNOVATIVE RESEARCH PROGRAM<br />

The CIRES Innovative <strong>Research</strong> Program (IRP) encourages novel, unconventional or fundamental<br />

research that might otherwise be difficult to fund. Funded projects are <strong>in</strong>ventive, sometimes opportunistic<br />

and do not necessarily have an immediate practical application or guarantee of success. This<br />

program supports pilot or exploratory studies, which may <strong>in</strong>clude <strong>in</strong>strument development, lab test<strong>in</strong>g,<br />

field observations or model advancement. There were six IRP w<strong>in</strong>ners <strong>in</strong> <strong>2011</strong>.<br />

Secondary organic aerosol <strong>for</strong>mation<br />

from evaporated crude oil<br />

Joost de Gouw (CIRES) and<br />

Jose-Luis Jimenez (CIRES)<br />

In this project, the evaporation of crude oil and the<br />

subsequent <strong>for</strong>mation of secondary organic aerosol (SOA)<br />

from the result<strong>in</strong>g hydrocarbons are studied <strong>in</strong> the laboratory.<br />

The study simulates the <strong>for</strong>mation of organic aerosol<br />

observed downw<strong>in</strong>d from the Deepwater Horizon Oil<br />

Spill <strong>in</strong> the Gulf of Mexico <strong>in</strong> 2010, which was attributed<br />

to hydrocarbons of a specific range <strong>in</strong> vapor pressures.<br />

The objective of the study is to f<strong>in</strong>d which hydrocarbons<br />

<strong>in</strong> crude oil are most important <strong>for</strong> SOA <strong>for</strong>mation <strong>in</strong> the<br />

polluted atmosphere and how these precursors and products<br />

can be measured with state-of-the-art <strong>in</strong>struments.<br />

78 CIRES Annual Report <strong>2011</strong><br />

NOAA BEN MILLER<br />

A novel cryogenic analyte<br />

preconcentration module <strong>for</strong><br />

trace gas and isotopic analyses<br />

Ben R. Miller (CIRES/ESRL GMD), Jason W<strong>in</strong>okur<br />

(INSTAAR), Bruce Vaughn (INSTAAR),<br />

Steve Montzka (CIRES/ESRL GMD)<br />

and Pieter Tans (CIRES/ESRL GMD)<br />

A new air sample preconcentration technology, applicable<br />

to atmospheric trace gas and isotopic analyses,<br />

is be<strong>in</strong>g developed to enhance the ability to <strong>in</strong>crease<br />

signal-to-noise ratios, remove <strong>in</strong>terferences and add new<br />

compounds to the suite of current species. This development<br />

will allow the researchers to analyze a wider<br />

range of sample types and characteristics, with improved<br />

precision and calibration accuracy. Results are expected to<br />

improve the study of the sources and s<strong>in</strong>ks of greenhouse<br />

gases and ozone-deplet<strong>in</strong>g substances.

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