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2011 - Cooperative Institute for Research in Environmental Sciences ...

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Milestone 4. Analyze balloon-borne measurements of water<br />

vapor <strong>in</strong> the UTLS to reveal multiple-year trends and<br />

attempt to attribute them to geophysical processes.<br />

A statistical analysis of the 30-year record of stratospheric<br />

water vapor mix<strong>in</strong>g ratios over Boulder, Colo., was per<strong>for</strong>med<br />

to quantify multiple-year trends [Hurst, et al., <strong>2011</strong>].<br />

The record was compiled from more than 300 balloon flights<br />

carry<strong>in</strong>g the NOAA frost po<strong>in</strong>t hygrometer. The long measurement<br />

record was divided <strong>in</strong>to four dist<strong>in</strong>ct time periods<br />

(roughly 1980–1989, 1990–2000, 2001–2005 and 2006–2010)<br />

and analyzed <strong>for</strong> trends <strong>in</strong> 2-km altitude layers. Overall,<br />

stratospheric water vapor <strong>in</strong>creased by 1±0.2 ppmv (27±6%)<br />

from 1980 to 2010. Net <strong>in</strong>creases were found <strong>for</strong> all but the<br />

2001–2005 period, when water vapor mix<strong>in</strong>g ratios dropped<br />

precipitously due to a decl<strong>in</strong>e <strong>in</strong> tropical tropopause temperatures<br />

driven by <strong>in</strong>creased tropical upwell<strong>in</strong>g. Increased<br />

methane oxidation <strong>in</strong> the stratosphere dur<strong>in</strong>g 1980–2010<br />

can expla<strong>in</strong> only 30 percent of the net water vapor <strong>in</strong>crease.<br />

Attempts to f<strong>in</strong>d a long-term warm<strong>in</strong>g trend <strong>in</strong> tropical<br />

tropopause temperatures that would cause an <strong>in</strong>crease <strong>in</strong><br />

stratospheric water vapor have been unsuccessful. It has<br />

been suggested that a gradual widen<strong>in</strong>g of the tropics and/<br />

or <strong>in</strong>crease <strong>in</strong> the strength of the Brewer-Dobson circulation<br />

dur<strong>in</strong>g Northern Hemisphere summer would br<strong>in</strong>g additional<br />

moisture from the troposphere <strong>in</strong>to the stratosphere.<br />

Recent water vapor sound<strong>in</strong>gs over Boulder <strong>in</strong>dicate that<br />

stratospheric water vapor mix<strong>in</strong>g ratios had nearly recovered<br />

to pre-2001 values by the end of 2010 and cont<strong>in</strong>ued<br />

to <strong>in</strong>crease dur<strong>in</strong>g the first half of <strong>2011</strong>. Work cont<strong>in</strong>ues to<br />

determ<strong>in</strong>e the causal mechanisms <strong>for</strong> these significant variations<br />

<strong>in</strong> midlatitude stratospheric water vapor abundance.<br />

CSV-03 Stratospheric Ozone Depletion<br />

n CSD-04 Photochemical and Dynamical Processes That<br />

Influence Upper Troposphere/ Lower Stratosphere Ozone<br />

n GMD-05 Ozone Depletion<br />

CSD-04PhotochemicalandDynamicalProcesses<br />

thatInfluenceUpperTroposphere/Lower<br />

StratosphereOzone<br />

FEDERAL LEAD: KAREN ROSENLOF<br />

CIRES LEAD: CHRISTINE ENNIS<br />

114 CIRES Annual Report <strong>2011</strong><br />

Figure 2: Smoothed representation<br />

of the 30-year ‘Boulder<br />

Record’ of stratospheric water<br />

vapor mix<strong>in</strong>g ratios. A net<br />

<strong>in</strong>crease of 1.0±0.2 ppmv<br />

(27±6%) was determ<strong>in</strong>ed<br />

<strong>for</strong> 1980–2010 [Hurst, et al.,<br />

<strong>2011</strong>].<br />

NOAA Goal 2: Climate<br />

Project Goal: Improve theoretical capabilities to predict the<br />

natural and human <strong>in</strong>fluences on the stratospheric ozone<br />

layer. Characterize the photochemical reactions relat<strong>in</strong>g to the<br />

anthropogenic loss of ozone <strong>in</strong> the stratosphere. Carry out <strong>in</strong><br />

situ studies of the photochemical and dynamical processes<br />

that <strong>in</strong>fluence the stratospheric ozone layer.<br />

Milestone 1. Use ozone data from flights of the National<br />

Center <strong>for</strong> Atmospheric <strong>Research</strong> HIAPER Gulfstream-V<br />

aircraft and the Global Hawk unmanned aircraft system<br />

to exam<strong>in</strong>e transport and photochemical processes <strong>in</strong> the<br />

upper troposphere and lower stratosphere. Impact: The<br />

data and <strong>in</strong>tercomparisons with high-resolution models<br />

will offer new <strong>in</strong>sights <strong>in</strong>to how ozone can be used to constra<strong>in</strong><br />

transport and photochemical processes <strong>in</strong> global<br />

models.<br />

In situ measurements of ozone <strong>in</strong> the upper troposphere<br />

and lower stratosphere (UTLS) have been made <strong>in</strong> the<br />

past several years from the NCAR/NSF HIAPER G-V<br />

(High-per<strong>for</strong>mance Instrumented Airborne Plat<strong>for</strong>m <strong>for</strong><br />

<strong>Environmental</strong> <strong>Research</strong> Gulfstream V) and the NASA<br />

Global Hawk UAS (Unmanned Aircraft System) <strong>in</strong> the Pacific<br />

Ocean and Arctic regions, spann<strong>in</strong>g a latitude range<br />

from 85° N to 67° S. These measurements provide an<br />

excellent data set <strong>for</strong> comparison with satellite measurements<br />

and high-resolution models. To date, the data from<br />

one of the HIAPER Pole-to-Pole Observations (HIPPO)<br />

missions have been compared with output of the Realtime<br />

Air Quality Model<strong>in</strong>g System (RAQMS). RAQMS<br />

simulates ozone based on model physics and chemistry,<br />

Global Forecast System meteorology and constra<strong>in</strong>ts<br />

from assimilated Ozone Monitor<strong>in</strong>g Instrument cloudcleared<br />

total column ozone and Microwave Limb Sounder<br />

stratospheric ozone profiles from the NASA Aura satellite.<br />

Initial comparisons between the satellite-constra<strong>in</strong>ed<br />

RAQMS <strong>for</strong>ecasts (2° x 2° grid) and <strong>in</strong> situ ozone measurements<br />

<strong>in</strong>dicate that 1) the model does not fully reproduce<br />

the variability observed throughout the extratropical<br />

UTLS region and 2) the model exhibits a low bias <strong>in</strong> the<br />

high-latitude lower stratosphere. The model-measurement<br />

differences exceeded 40 percent <strong>for</strong> nearly one-third of the<br />

extratropical UTLS data. Some of these discrepancies are<br />

likely related to the systematic profil<strong>in</strong>g of the G-V aircraft<br />

near the tropopause <strong>in</strong> the extratropics where the vertical<br />

ozone gradients are large and significant variations occur<br />

at scales not resolved by RAQMS.

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