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Ph. D. THESIS 2009

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a b<br />

Figure 21 a) Optical image of gold nanowires deposited on an polyimide coated<br />

substrate, b) SEM view of two wires of the network<br />

Thus, the wires always remain uniform and straight before as well as after the<br />

washing step. The regular shape aspect of the wires is another positiv point of<br />

the polyimide glass coated surface influence, comparatively with the untreated<br />

glass one. The preservation of wires characteristics is illustrated in Figure 21b).<br />

4.4. The thermal effect<br />

Ablated<br />

polyimide<br />

region<br />

15<br />

Polyimide<br />

underlayer<br />

Gold nanowire deposition<br />

on polyimide layer<br />

a b<br />

Figure 22. AFM measurements of a typical double line: a) 3D view of a two double<br />

lines fabricated with 60mW and 65 mW; b) detail of 3D view of the double line at 60<br />

mW<br />

The profile of a double line can be seen below:<br />

Figure 23. AFM profile for the fabricated line (Cross-section)<br />

4.5 The overcoming of the thermal effect<br />

The nucleation and growth experiment, associated with absorption spectra in<br />

solid state, suggested us an "optimum" of experimental conditions which can<br />

lead to good quality lines without ablation. For our case a laser power of 15

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