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PDF (1941) - CaltechCampusPubs

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CHEMISTRY AND CHEMICAL ENGINEERING 203<br />

structure of molecules and its correlation with the chemical and physical properties<br />

of substances.<br />

It is planned that the seminar be held in <strong>1941</strong>-42, and every third year thereafter.<br />

iext: The Nature of the Chemical Bona, Pauling.<br />

In charge: Pauling.<br />

Ch. 222 a, b, c. Seminar on Thermodynamics and Statistical Mechanics,<br />

with Chemical Application.. 6 units; nrst, second, and third terms.<br />

A thorough discussion of the fundamental principles and methods of thermodynamics<br />

and statistical mechanics, followed by their application to the practical<br />

problems of modern chemistry, including the calculation of thermodynamic properties<br />

of substances from spectroscopic and structural data.<br />

ihis seminar will be held in 1942-43, and every third year thereafter.<br />

In charge: Dickinson, Yost, Badger.<br />

Ch. 223 a, b. Kinetic. of Homogeneou. and Heterogeneous Reaction.<br />

(Seminar). 6 units; first and second terms.<br />

Lectures and discussions relating to homogeneous and heterogeneous chemical<br />

reactions, absorption, and contact catalysis.<br />

ihis seminar will be held in 1940-41, and every third year thereafter.<br />

In charge: Dickinson, Badger.<br />

Ch. 224 a, b, C, d. Statistical Mechanics (Seminar). 6 units; four terms.<br />

A discussion of statistical mechanics and its applications to physics and chemistry.<br />

The topics treated will include a sufficient exposition of classical and quantum<br />

theory mechanics to serve as a foundation for statistical mechanics and the relations<br />

between statistical mechanics and thermodynamics.<br />

Text: Principles of Statistical Mechanics, Tolman.<br />

In charge: Tolman.<br />

Ch. 226 a, b, c. Introduction to Quantum Mechanics, with Chemical<br />

Application.. 9 unit.; first, second, and third terms.<br />

A review of Lagrangian and Hamiltonian mechanics and of the old quantum<br />

theory is first given, followed by the discussion of the development and significance<br />

of the new quantum mechanics and the thorough treatment of the Schr5dinger wave<br />

equation, including its solution for many simple systems such as the rotator, the<br />

harmonic oscillator, the hydrogen atom, etc. During the second and third terms<br />

various approximate methods of solution (perturbation theory, the variation method,<br />

etc.) are discussed and applied in the consideration of the resonance phenomenon,<br />

the structure of many-electron atoms and of simple molecules, the nature of the<br />

covalent chemical bond, the structure of aromatic molecules, and other recent<br />

chemical applications.<br />

It is planned that this subject be given in 1942-43, and every third year thereafter.<br />

Text: Introauction to QUrlntu1II Mtchrlnics, 1Vith Applications to Chemistry,<br />

Pauling and Wilson.<br />

Instructor: Pauling.<br />

Ch. 227 a, b, c. The Structure of Crystals. 9 units; first, second, and<br />

third terms.<br />

Thc following topics arc discussed:<br />

The nature of crystals and X-rays and their interaction. The various experimental<br />

methods of investigation-Bragg, Laue. oscillation, Weissenberg, etc. ihe

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