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Analytical Data Package Prepared For 

Westhinghouse Hanford 

Chemical Analysis By 

Quanterra Environmental Services 

Sample Delivery Group Number: W01075 

WHC IDENTIFICATION NUMBER QUANTERRA ID NUMBER 

#6 weana(ys;5 ÎxlLi Tbcka^, , L.d 

BOHX42 

11452-001 

BOHX43 11452-002 

W / 0,5& - Q LS -53SQ 

3 

0045358 

4 

am use 

REcEM 

sou 

4% 

00 

IWA to 

V, 

st 

COPY 

00001

Quanterra Incorporated 

13715 Rider Trail North 

Earth City Missouri 63045 

314 298-8566 Telephone 

314 298-8757 Fax 

Westinghouse Hanford Company 

P.O. Box 1970 

Richland, Washington 99352 

August 30, 1996 

Attention: Karl Pool 

CERTIFICATE OF ANALYSIS 

Project number 519.136 

Date Received by Lab June 25, 1996 

Number of Samples Two (2) 

Sample Type Liquid 

SDG Number W01075 - 

Data Deliverable Summary 

I. Introduction 

iiivanterra 

Environmental 

Services 

On June 25, 1996, two (2) liquid samples were received by Quanterra, Richland and transferred to 

Quanterra, St. Louis for chemical analysis. On July 16, 1996, additional Mercury analyses were 

requested on these samples. Upon receipt, the samples were given the following laboratory ID 

numbers to correspond with the specific client ID's: 

St Louis ID WHC ID Richland ID MatrixDate of Receipt 

11452-001 BOHX42 60632401 Liquid 6/25/96 

11452-002 BOHX43 60632402 Liquid 6/25/96 

The results of the original analyses can be found with SDG W01056. This report contains only the 

results for the Mercury reanalysis. 

11. Analytical Results/ Methodology 

The analytical results for this report are presented by analytical test. Each set of data includes 

sample identification information, analytical results and the appropriate detection limits. 

Analyses requested: Mercury by EPA method 7470. 

C)cr- -Z


August 30, 1996 

Project Number: 519.136 

SDG: W01075 f 

Page 2 

Ill. Quality Control 

Cl»uanterra 

Environmental 

Services 

A Laboratory Control Sample and Method Blank were analyzed with each preparation batch. 

Matrix Spike and Matrix Spike Duplicate and/or Sample Duplicate analyses were performed per the 

protocol for each analyte. pH analysis uses only Sample Duplicate for matrix QC. 

IV. Defudtions 

The following codes are used to denote laboratory quality control samples and can be found in the 

data summary section of this report: 

QCBLK- Quality Control Blank, Method Blank 

QCLCS- Quality Control Laboratory Control Sample, Blank Spike 

V. Comments 

Shipping and Receiving 

The chain of custody arrived at the laboratory stating the sampling date as 4/17/96 making the 

samples out of holding time. Per ROD-96-0044, the samples true sampling date is 6/17/96 and the 

samples were not out of holding time. This ROD supercedes ROD-96-0035. 

Mercury 

There are no comments or nonconformances associated with this analysis. 

vc)C)C3

Westinghouse Hanford Comp any 

August 30, 1996 


SDG: W01075 

Page 

C';ivanterra 

Environmental 

Services 

I certify that this data package is in compliance with the SOW, both technically and for 

completeness, for other than the conditions detailed above. Release of the data contained in 

this hard copy data package has been authorized by the Laborato ry Manager or a designee, as 

verified by the following signature. 

Re and approved: 

7 `7 

Wade H. P ri ce 

Project Manager 

Quanteria Environmental Se rvices, Inc. 

e:\\sgdmo0I\price$\abbydave\hanfoni\hanw 1075.= 

CaZ3^-

8-07-1995 2:S3PM FROM OUANTERRA S09 375 5590 P.3 

SAMPLE DATA AND LABORATORY ADMINISTRATION 

RECORD OF DISPOSITION REV i 

DATE: July 16, 1996 LABORATORY: Quanterra 

ROD-96-0039 

Record of Disposition No. 

PROJECT TITLE/SAF #: PUREX Vessels' Flush Solutions/96-016, NCR NO.: N/A 

SAMPLE IDENTIFICATION NUMBERS: BOHX42, BOHX43 

DESCRIPTION OF EVENT: The customer has requested the Mercury for the above listed 

samples be rerun with a detection limit of less than 0.20 mg/Kg. The customer has 

requested the reruns be on a Priority turnaround. 

DISPOSITION OF SAMPLES: Quanterra is to rerun the Mercury for the above listed samples 

within the three business day priority data turnaround requirement. Quanterra can run 

the samples with a detection limit of less than 0.20 mg/Kg. 

APPROVAL SIGNATURES: 

S.M.Steele ^d ^,rL,^^ .. O July 16, 1996 

SDLA Project Coor ' a or c7rint/sign Nerve) Date 

C.N.Villalobos 

Technical Representative c print/Si gn Name) Date

7-10-1996 11:11AM 

07110/UU 08:19 

FROM CUANTERRA S09 375 5590 

C'bDN 372 1548 


RECORD OF DISPOSITION REV i WP 

>6^^4 


'5 19,/3 10 1'UC/O3-76 

R00-96-0035 

Word of Disposition No. 

Rev. 1 

PROJECT TITLFJSAF 0: PUREX Vessels' Flush Solutions/96-016 NCR NO.: N/A 


DESCRIPTION OF EVENT: The Chain of Custody for the above listed samples showed the 

samples were taken on 4/17/96. The samples arrived at Quanterra on 6/28/96. The 

difference in time from sampling to receipt at the lab exceeds the 14 day holding time 

for VOA by Method 8240, and the 28 day holding time for both Mercury by Method 7470 and 

TOC by Method 9060. 

DISPOSITION OF SAMPLES: The 4/17/96 date on the Chain of Custody was incorect. The 

samples were actually collected on 6/17/96. The holding times for the samples were not 

missed. Quanterra is to analyze the samples as received and note the discrepancy in the 

narrative. 


DRAFT 

S.M.Steele July 9. 1996 

SDLA Project Coordinator t print/siyn Na< ) Date 

C.N.Vi]lalobos 

Technical Representative (print/sign Name) Date 

P. 8 

tmuul

Quanterra June 26, 1996 03:22 pm 

Account: 10722 Project: 519.136 Quanterra-R'chl nd OAS No. 861 Rev. 

Master Sample Login- 114 

Project Mane a W. Price -) 

S 

Draft: ffnat: Entered and Reviewed byt ` PM Review:. 

Sample Header Template: 

Sample No. Client ID . C-Matrix Date: Collected Received Due Shipper Red Category Red Sample No. 

Comments 

N Container TypeArialysis Class Preservative Anal. Due Date Hold Date Site (Container Numbers:% FilLed) 

Data: 

11452-001 SONX42 Liquid 

REPORT ON A PER WEIGHT BASIS./MOTEt R101, D 10 60632401 

1 VI - Vial-40ml P.H/WO/04 

1 

TOC/9060/04 

2 VOA/8240/Q4 

1 AN - Amber GLass-11. A$/70601"' 

1 HG/7470/Q4 

1 ICAP/6010/Q4 

1 

PS/7421/Q4 

1 

SE/7740/04 

1 VI - Vial-20141 MOLD/44- 

11452-OOIDUP SONX42 Liquid 

REPORT ON A PER HEIGHT BASIS. /NOTE: RICHLAND 10 60632401 

1 VI - Viet-40ml PH/9040/94 

1 TOC19060/Q4 

11452-OOlMS BOAX42 Liquid 

REPORT ON A PER WEIGHT BASIS. /NOTE: RICHLAND ID 60652401 

1 VI - Vial-40ml TOC19060/Q4 

2 VGA/824O/Q4 

1 AN - Amber Glass-IL AS/7060/04 

1 HG/7470/CA 

1 ICAP/6010/Q4 

1 

PB/7421/04 

1 SE/7740/Q4 

11452-OOlMSD BM42 Liquid 

REPORT ON A PER HEIGHT BASIS. /NOTE: RICNLANO 10 60432401 

2 VI - vial-40141 VOA/8240/Q4 

1 AN - Amber GLass-11, AS/7060/Q4 

1 

HG/7470/Q4 

1 

ICAP/6010/Q4 

1 

P11/7421/04 

t' 1 SE/7740/04 

91452-002 BONX43 Liquid 

REPORT ON A PER WEIGHT BASIS. /NOTE: RICHLAND ID 60632402 

J= 

3-=Saaq:Le has not been rod screened. 

17-APR-96 14:00 25-JUN-96 10:00 09-JUL-96 FED-EX i Screening not Required 

S COLD 02-JUL-96 18-APR-96 R160 (236686:99) 

S COLD 02-JUL-96 15-MAY-96 R16D (236687:98) 

S COLD 02-JUL-96 01-MAY-96 1091 (236664:100 236685:100) 

S COLD 02-JUL-96 14-OCT-96 R16P (236688:1DO) 

S COLD 02-JUL-96 15-MAY-96 R160 (236688:100) 

S COLD 02-JUL-96 14-OCT-96 R16D (236688:100) 



S COLD IL-&;A-*• !!•RTt- ** R160 (236695:80) 

17-APR-96 14:00 25-JUN-96 10:00 09-JUL-96 FED-EX 1 Screening not Required 

$ COLD 02-JUL796 10-APR-96 R16D (236686:99) 

S COLD 02-JUL-96 15-MAY-96 R16D (236687:98) 

17 •APR-96 14:00 25-JUM-96 10:00 09-JUL-96 FED-EX 1 Screening not Required 

S COLD 02-JU4-96 15-14AY-96 8160 (236687:98) 

S COLD 02-JUL-96 01-MAY-96 1091 (236684:100 236685:100) 

S COLD 02-JUL-96 14-OCT-96 916D (236688:100) 

S COLD 02-JUL-96 15-MAY-96 R160 (236688:100) 

S COLD 02-JUL-96 14-OCT-96 R160 (236688:100) 

S COLD 02-JUL-96 -14-OCT-96 R160 (236688:100) 

S COLD 02-JUL-96 14-OCT-96 R160 (236688:100) 

17•APR-96 14:00 25-JUH-96 10:00 09*JUL-96 FED-EX 1 Screening not Required 

S COLD 02-JUL-96 01-14AY-96 1091 

S COLD 02-JUL-96 14-OCT-96 R16D 

S COLD D2-JUL-96 15-MAY-96 R16D 


S COLD 02-JUL-96 14-OCT-96 R160 


17-APR-96 14:00 25-JUN-96 10:00 09-JUL-96 FED-EX 3 

Page 1 

(236684:160 236685:100) 

(236688:1DO) 

(236688:100) 

(236688:100) 

(236688:100) 

(236688:100) 

Screening not Required

Project Manager; N. Price 

• 

0uanterra June 26, 1996 3:22 pm 

Account: 10722 Project: 519.136 Ouanterra-Richland OAS No. 861 Rev. 1 

Master Sample Login: 11452 

Draft: final: Entered and Reviewed by: - PM Review: 

Sample Header Template: _ 

Sample No. 

Client ID 

Comments 

# Container Type 

Data: 

i Vl - Viet -40m1 

1 

2 

1 AN - Amber Glass-1L 

1 

1 

1 

1 

1 VI - Vial-20*i 

O 

C-3 

C7 

G 

Cf1 

3* =Sample has not been red screened. 

C-Metrix Date: Collected Received Out Shipper Red Category Red Sample No. 

Analysis Class Preservative Aral. Due Date gold Date Site (Container Numbers:% filled) 

rnf Yrmy;w 

TOC/9060/04 S 

w w 

COLD 

Vc-OWI- w 

02-JUL-96 

IV n-sV n.w 

15-MAY-96 R160 

wm^•^.r 

(236692:98) 

VOA/8240/04 S COLD 02-JUL-96 01- 14AY-96 1091 (236689:100 236690:100) 

AS/7060104 S COLD 02-JUL-96 14-OCT-96 R16D (236693:100) 

HOMO/" S COLD 02-JUL-96 15-MAY-96 R16D (236693:100) 

ICAP/6010/04 S COLD 02-JUL-96 14-OCT-96 R16D (236693:100) 

1` 8/7421/04 S COLD 02-JUL-96 14-OCT-96 R16D (236693:100) 

SE/7740/04 S CDLD 02-JUL-96 14-OCT-96 R160 (236693:100) 

VOID//Q4 S COLD!l- 888-`* 11.86&-** R160 (236694:80) 

Page 2

. i e,VK r A'i- C U V, ti- 

Chain of Custody 

Record 

«"4124.1 

El No 4kd 

Ml 

"/ y72L 

I 

MEN IMIMMEMEMINISIMM 

Qvuanterra 

avim>o 

S"vk" 

ENO 

Uwr nay rr^„â^ ^.. ^. as 

H El Fiaawwbla El sma hdwa El Pasm e l Yu w 17F ro cwa u q awma er ub q n^^®Fa sw^W bn9e/ b" wa tlw 3 rnornns) _. 

nl 17,25-gt; I it. r oo I ^^r' ^..^/ I -p61 ^?' ,j a 

- Stays with dre Sample, CANARY - Re6umed to Mnl with Repod; PINK - 5&W Copy

Y ``pp\!\ 

V\ 

Westinghouse Hanford 

CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST 

.o.c (7 

100204 

Company Pyc / of 

Collector HULSE, KARL. 

MSIN S6-19 FAX 

AF Number 96-016 

SampkOrigin Du E 

f 

PiarcAOrdcrlCharseCode 

wc 

Project T1de P LIRF.X Vessels Flush Solutions Logbook# Wl/, I-Al-J05- 

Ice ched9 Temp. 

supped To (Lob) Quanterra Mc16o4 of Sidpment 

60V. 

` 

BRI of Ladln{/Alr BW No. 

Al 

outacl/Re9reslor VILLALOBOS, CARMEN reLNO. 373-4753 

protocol RCRA Data Trswarouttd PRIORITY offshe Property No. 

At 1A 

Sample No. Lab. ID a Dose Time NolType Contolatr Sample Anslyslo Peraervallre 

1301(X42 L 4117196 1400 (1) 20 P 

BONX42 L 4117196 1400 (I) 1000 ` a0 

BOHX42 L 411706 1400 ( 1) 40 sGs 

BOHX42 L 4/17196 1400 (p 40 aGs 

BOHX42 L 4/17/96 1400 (I) 40 aGs 

lIX42 L 0 (1) 40 aGs 

BOHX43 L 0 (1) 20 P 

BOHX43 L 

0 (I) 1000 a0 

BOHX43 L 0 (1) 40 aGs 

BOILX43 L 00 (1) 40 aGs 

BOHX43 L g4/17/9614"000 00 ( 1) 40 aGs 

IdX43 L I 4117!96 1 1400 (1) 40 aa, 

ACTIV IT Y SCAN (Lab Specfw) 

ICP Melak. TAL (6010) plus, Lead 97421 1 Acetic (70602 Seimium(T/40Z Mae ry (7470) 

V rô Nome 

5'7,1 Cpol to 4°C 

PH 9w 

( ) / 1 03 011, 

Nonc 

TOC 9m 

( ) 

^ 

^f ( xo ^.^C U,> r(, Cool to 4eC 

VOA (1240) .;•by 

*0s.. UJYs Cool to 4°C 

VOA (1190) n4,y 

X174 

`^ e r^ 

ACTIVITY SCAN (Lab Spmfw) Ô e6 

ICPMwk.TAL(6010)pim,Lead(7421LAmcpk(7060}Sek m.o(77401 Maeuy(7470) C^?. Ct/s 

Cod to 40C 

PH (9w) 

.J 0oat,f Nara 

TOC(9m 

) ^l/r 3,- ), 0Js/ /0A 

VOA (9240) 

VOA (r240) 

0 J 

10004 

None 

Cool to 4°C 

Cool Cod to 4eC 

Cod to 4°C 

Cool to 4eC 

OSS LE SAMPLEHAZARDSIREMARKS MSDS Yes q No ® SPECIAL INSTRUCTIONS 

Llat all Ymoww wastes. 6011X42 TCP2y elw /s IC goo/c, eaAjaiwt' , Iy +yae.7' PrwMy Txwn"autd Smn,,.y au Dalivp^RÔR"I"'YURNAROUND 2SD w /. Th is w+^ a// s+-y/c 7dt+7' caw// is ort+:+c.^ (^^ 

w"ik'A By Pria4 sips DalJfiaa Received By sips Dre/r=c Matrix• 

fffl 

B 

uupusdai By 

s 

K !. 

L.Iis 5b 0730 

lme 

W ItG. b /ZS/ `fb 100.5 

Doc/Dime 

1!--S- 

Rece BY 

Received By 

S/lllC, 

/ 7 

hs t(p 0120 

C - ^^ ^^ j^ .î / 

ime 

s 

36 

so 

SL 

W 

O 

= sod 

= sedanent 

- saw 

- Woke 

=era 

= Od 

DS 

DL 

T 

wl 

L 

V 

= DM Solids 

= ones LvIM& 

- Tmu, 

= w pr 

- l.igsud 

= Veplrim 

A Air X - Olha 

By D"Twe Roceived By Dre/Time 

FINAL SAMPLE Disp-d Metbod e.`Rcaa wcatwrx; pa lab ProeeAxa, used in prm . Disposed By Dak?imc 

DISPOSITION 

A ll ampks mMawlol batataduas tsudeak rl shall be pkked up by nyusalw and relumed le parcot euuldna er ill• rwijht 

00007 

ITY 

A-6001500 (0795)

0 

c^ 

0 

00 

Client Sample Screening Results 

25-Jun-96 

CLIENT CODE ID MATRIX RECEIVED DETECTOR ACQ DATE SAMPLE 161INUTES CNTS A NET CPAI A CNTS B NET C PA1 B 

WI1C BOHX42 6/29 19% 10:00:00 AAI QUAD2IA 3675:19% I:29:32 Pb1 BDHX42 30 5 0.10541667 147 3.9875 

LIQUID Ug: 6125/1996 4:05:51 AM BKO 800 49 0.06125 730 0.9125 

Aal Wit: 6/25/ / 19% Tot Sa, AIq: I.00E+DO 3 1.00E+01 Alp; (DpwJ 1.75E-0 1 (uCY 7.28E-D6 (pCY 7.88E+00 ± 2.0E+01 CAT 3.2E+00 Lab 

Ppt m8: 0 3 UARS: L ml Bep AIq): 7.88E+00 Sa} 3.55E-04 1.4g): 3.55E+02 ±3.6E+01 I 1.4E-01 q 

WIIC BOWN43 6.'25 1 199610:00:OOAM QUAD21B 3 6!25 11 9961:20:00 Phi BOHX43 20.01 16998 849.430262 1186811 59309.957 

LIQUID Ilk : 6125/19964:05:51 AM BKG 800 36 0.045 750 0.9375 

,WDatc: 6,2511996Tat Sa,Atq: 2.50E-0 1 1.00E+00V Alp; (DpuJ 7.99ErO2 (uCl/ 9.00E-02 (pCY 3.60E+05 ±4.7E+03 CAT 6.9E-05 Lab 

Ppt m8: 8.6 Ualta: 

m1 Bet; AIq): 1.16E+05 $a): 1.31E+01 1.. 5.22E+07 ± 4.8E+04 111 

9.6E-07 AIq 

149 

RPc1ewej W ? 51 c 

^ 

25-Jun-96 J

.') 

Soil/Solid Samples 

Sample A BOHX43 Total Grams per sample 430 

isotope 

G 

in pCi/G Bq/G KBq/G KBq/ pCi/ Ltd Qty Unity for 

sample sample Value in MBq Ltd Qty 

Total Alpha .002 745 27.5650 0.0276 11.8530 0.3204 0.0020 0.6000 

Toatl Beta 20 43100 1,594.7000 1.5947 685.7210 18.5330 20.0000 0.0034 

Cs-137 '500 21300 788.1000 0.7881 338.8830 9.1590 500.0000 0.0001 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

0,0000 0.0000 0.0000 0.0000. 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

TOTAL 65,145.00 2,410.3650 2.4104 1,036.4570 28.0124 0.6035 

M 

0 

0 

CJ 

0

Sat, Jun 22, 1996 6:47 PM 

SAMPLE INQUIRY by GROUP 

Company Name: PUREX Programs Westinghouse Hanford Company Project Code: U3 Group #: 96 

Parameter 

Rep Result Unit %Recov Date Analyst 

------------------------------------------------------------------------------------- 

Sample #: S96P000086 • Sample ID: BOHX42 

Actinium-228 by GEA 0 < 1.224e-04 uCi/mL 06/18/96 eat 

Ac-228 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Alpha in Liquid Samples. 0 4.21E-07 uCi/mL 06/19/96 dgg 

Alpha Liq.- Rel. % Count Error 0 1.21E+02 % Ct. Error 06/19/96 dgg 

Americium-241 by GEA 0 < 1.622e-04 uCi/mL 06/18/96 eal 

Am-241 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eal 



Beta in Liquid Samples 0 < 1.69E-06 uCi/mL 06/19/96 dgg 

Beta Liq.- Rel. % Count Error 0 5.00E+02 % Ct. Error 06/19/96 dgg 

Bismuth-212 by GEA 0 < 3.275e-04 uCi/mL 06/18/96 eal 

Bi-212 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 



Cadmium-109 by GEA 0 < 4.668e-04 uCi/mL 06/18/96 eal 

Cd-109 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Ce/Pr-144 by GEA 0 < 2.177e-04 uCi/mL 06/18/96 eal 

Ce/Pr-144 GEA Rel % Count Err 0 n/a % Ct. Error 06/18/96 eal 

Cobalt-56 by GEA 0 < 2.360e-05 uCi/mL 06/18/96 eal 

Co-56 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eal 


Co-57 GEA Rel. % Count Error 0 n/a • - % Ct. Error 06/18/96 eal 



Cesium-134 by GEA 0 < 2.19le-05 uCi/mL 06/18/96 eal 

Cs-134 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eal 

Cesium-137 by GEA 0 < 6.04le-05 uCi/mL 06/18/96 eal 


Europium-152 by GEA 0 < 9.094e-05 uCi/mL 06/18/96 eal 

Eu-152 GEA Rel % Counting Err 0 n/a % Ct. Error 06/"18/96 eal 

Europium-154 by GEA 0 < 7.154e-05 UCi/mL 06/18/96 eal 

Eu-154 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 


Eu-155 GEA Rel % Counting Err 0 n/a . % Ct. Error 06/18/96 eal 

Mercury-203 by GEA 0 < 1.92Ie-05 uCi/mL 06/18/96 eal 

Hg-203 GEA Rel % Counting Err 0 n/a 

11 

% Ct. Error 06/18/96 eal 

Iodine-131 by GEA 0 < 2.436e-05 uCi/mL 06/18/96 eal 

Ir131 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Potassium-40 by GEA 0 < 9.284e-04 uCi/mL 06/18/96 eal 

K-40 GEA Rel. % Count Error 0 n/a I % Ct. Error 06/18/96 eal 

Sodium-22 by GEA 0 < 2.457e-05 uCi/mL 06/18/96 eal 

Na-22 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eal 


Na-24 GEA Rel. % Count Error 0 n/a , t;.- % Ct. Error 06/18/96 eal 

Niobium-94 by GEA 0 < 2.041e=05 uCi/mL 06/18/96 eal 

Nb-94 GEA Ref % Counting Error 0 n/a % Ct. Error 06/18/96 eal 

Neptunium-237 by GEA 0 < 1.476e-04 uCi/mL 06/18/96 eal 

Np-237 GEA Rel % Counting Err 0 n/a I I % Ct. Error 06/18/96 eal 


00010 

Pag

... r... r.. .... .. ...v ♦.ate J. J ua. V .] t—w - ^ V VJ 

Sat, Jun 22, 1996 6:47 PM 


Company Name: PUREX Programs Westinghouse Hanford Company Project Code: U3 

Parameter Rep Result Unit %R g^cov Date Analyst 

------------------------------------------------------------------------------------- 

Sample #: S96P000086 Sample ID: BOHX42 [Continue"d} 

Np-239 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Protactinium-233 by GEA 0 < • 4.734e -05 uCi/mL 06/18/96 eal 

Pa-233 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Protactinium-234m by GEA 0 < 3.44le-05 uCi/mL 06/18/96 eal 

Pa-234m GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Lead-212 by GEA 0 < 4.486e-05 uCi/mL 06/18/96 eal 

Pb-212 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Lead-214 by GEA 0 < 1.149e-04 uCi/mL 06/18/96 eal 


Plutonium-239 by GEA 0 < 1.919e- 0 1 uCi/mL 06/18/96 eal 

Pu-239 GEA Rel % Counting Err 0 n/a t % Ct. Error 06/18/96 eal 

Radium-224 by GEA 0 < 4.62ie-04 uCi/mL 06/18/96 eal 

Ra-224 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Radium-226 by GEA 0 < 4.274e-04 uCi/mL 06/18/96 eal 

Ra-226 GEA Rel % Counting Err 0 n/a :`-I '% Ct. Error 06/18/96 eal 

Ruthenium-103 by GEA 0 < 2.045e-05 uCi/mL 06/18/96 eal 

Ru-103 GEA Rel % Count Error 0 n/a % Ct. Error 06/18/96 eal 

Ru/Rh-106 by GEA 0 < 4.328e-04 uCi/mL 06/18/96 eal 

Ru/Rh-106 GEA Rel. % Count Err 0 n/a % Ct. Error 06/18/96 eat 

Selenium-75 by GEA 0 < 3.023e-05 uCi/mL 06/18/96 eal 

Se-75 GEA Rel. % Count Error 0 n/a I % Ct. Error 06/18/96 eal 

Tin-113 by GEA 0 < 3.434e-05 uCi/mL 06/18/96 ehl 

Sn-113 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Strontium-85 by GEA 0 < 2.613e-05 uCi/mL 06/18/96 eal 

Sr-85 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eal 

Thorium-228 by GEA 0 < 1.576e = 03 uCi/mL 06/18/96 eal 

Th-228 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eat 

Thorium-229 by GEA 0 < 6.639e-05 uCi/mL 06/18/96 eat 

Th-229 GEA Rel % Counting Err 0 n/a . % Ct. Error 06/18/96 eal 

Thorium-234 by GEA 0 < 8.867e-04•6Ci /18/96 /mL 06 eal 

Th-234 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Thallium-208 by GEA 0 < 2.802e-04 uCi/mL 06/18/96 eal 

TI-208 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Uranium/Thorium-233 by GEA 0 < 1.489e-02 uCi/mL 06/18/96 eal 

U/Th-233 GEA Rel % Count Err 0 n/a % Ct. Error 06/18/96 eal 

Uranium-235 by GEA 0 < 2.622e-05 uCi/mL 06/18/96 eal 

U-235 GEA Ref % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Yttrium-88 by GEA 0 < 2.565e-05 uCi/mL 06/18/96 eal 

Y-88 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eal 

Zr/Nb-95 by GEA 0 < 3.938e-05 uCi/mL 06/18/96 gal 

Zr/Nb-95 GEA Rel % Count. Err 0 n/a % Ct. Error 06/18/96 eal 

Sample #: S96P000087 Sample ID: BOHX43 

Actinium-228 by GEA 0 < 1.002e-Q4 uCi/mL 06/18/96 eal 

Ac-228 GEA Rel % Counting Err 0 n/a " ••i:4 •% Ct. Error 06/18/96 eal 

Alpha in Liquid Samples 0 7 a5F-OA uCi/mL -7 • ,i s x toZ 06/19/96 dgg 

Alpha Liq.- Rel. % Count Error 0 2.74E+00 % Ct. Error 06/19/96 dgg 




0001.1 

Pag 

Group #: 96

Sat, Jun 22, 1996 6:47 PM 

Parameter 

Sample #: S96P000087 Sample ID: 

Am-243 GEA Rel. % Count Error 

Beta in Liquid Samples 

Beta Liq.- Rel. % Count Error 

Bismuth-212 by GEA 

Bi-212 GEA Rel % Counting Err 



Cadmium-109 by GEA 

Cd-109 GEA Rel % Counting Err 

Ce/Pr-144 by GEA 

Ce/Pr-144 GEA Rel % Count Err 

Cobalt-56 by GEA 

Co-56 GEA Rel. % Count Error 





Cesium-134 by GEA 

Cs-134 GEA Rel. % Count Error 



Europium-152 by GEA 

Eu-152 GEA Rel % Counting Err 




Ea-155 GEA Rel % Counting Err 

Mercury-203 by GEA 

Hg-203 GEA Rel % Counting Err 

Iodine-131 by GEA 

1-131 GEA Rel % Counting Err 

Potassium-40 by GEA 

K-40 GEA Rel. % Count Error 

Sodium-22 by GEA 

Na-22 GEA Rel. % Count Error 



Niobium-94 by GEA 

Nb-94 GEA Rel % Counting Error 

Neptunium-237 by GEA 

Np-237 GEA Rel % Counting Err 



Protactinium-233 by GEA 

Pa-233 GEA Rel % Counting Err 

Protactinium-234m by GEA 

Pa-234m GEA Rel % Counting Err 

Lead-212 by GEA 

Pb-212 GEA Rel % Counting Err 




Rep Result Unit %Recov Date Analyst 

- ---------------------------------------------------- 

BOHX43 [Continued] 

0 n/a % Ct. Error 06/18/96 eal 

0 6.44E-02— uCi/mL -4vow v ix o^ 06/19/96 dgg 

0 2.07E-01 % Ct. Error 06/19/96 dgg 

0 < 3.750e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.136e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.228e-03 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 6.107e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 2.349e-0 5 uCi/mL 06/18/96 eal 

0 n/a .. % Ct. Error 06/18/96 eal 

0 < 4.042era5 UCi/mL 06/18/96 eal 

0 n/a x Ct. Error 06/18/96 eal 

0 < 2.87le-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 4.758e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 9 130e-09 uC.i/mL 7.11 ioti 06/18/96 eal 

0 1.50 % Ct. Error 06/18/96 eal 

0 < 8.134e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 5.834e-05 uCi/mL 06/18/96 eal 

0 n/a - •- % Ct. Error 06/18/96 eal 

0 < 1.677e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 6.20le-05 uCi/mL 06/18/96 eal 

0 n/a rc % Ct. Error 06/18/96 eal 

0 < 7.454e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 8.997e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eat 

0 < 2.014e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.982e-05 uC1/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 2.271e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 3.743e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.577e-04. uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.389e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 5.306e-05 6Ci/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.164e-04 uCi/mL 06/18/96 eat 

0 n/a % Ct. Error 06/18/96 eal 

0 < 3.02le-04 uCi/mL 06/18/96 eal 

00012 

Pag

Sat, Jun 22, 1996 6:47 PM 



Parameter 

Sample #: S96P000087 Sample ID 


Plutonium-239 by GEA 

Pu-239 GEA Rel % Counting Err 

Radium-224 by GEA 

Ra-224 GEA Rel % Counting Err 



Ruthenium-103 by GEA 

Ru-103 GEA Rel % Count Error 

Ru/Rh-106 by GEA 

Ru/Rh-106 GEA Rel. % Count Err 

Selenium-75 by GEA 

Se-75 GEA Rel. % Count Error 

Tin-113 by GEA 

Sn-113 GEA Rel % Counting Err 

Strontium-85 by GEA 

Sr-85 GEA Rel. % Count Error 

Thorium-228 by GEA 

Th-228 GEA Rel % Counting Err 





Thallium-208 by GEA 

T1-208 GEA Rel % Counting Err 

Uranium/Thorium-233 by GEA 

U/Th-233 GEA Rel % Count Err 

Uranium-235 by GEA 

U-235 GEA Ref % Counting Err 

Yttrium-88 by GEA 

Y-88 GEA Rel. % Count Error 

Zr/Nb-95 by GEA 

Zr/Nb-95 GEA Rel % Count. Err 

Rep Result' '' Unit %Recov Date Analyst 

---------------- ---------------- ---------------------- 

BOHX43 [Continued] 

0 n/a % Ct. Error 06/18/96 eal 

0 < 5.575e-01 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.290e-03 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.278e-03 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 6.930e-05 uCi/mL 06/18/96 eal 

0 n/a - % Ct. Error 06/18/96 eal 

0 < 9.13le-04 uCi/mL 06118/96 eal 

0 n/a , % Ct. Error 06/18/96 eal 

0 < 8.328e-05 uCi/mL 06/18/96 eal 

0 n/a "'°';' % Ct. Error 06/18/96 eal 

0 < 1.033e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 6.957e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 3.910e-03 uCi/mL 06/18/96 eal 

0 n/a I % Ct. Error 06/18/96 eal 

0 < 1.781e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 2.527e-03 uCi/mL 06/18/96 eal 

0 

0 

0 

n/a 

< 8.152e =04 

n/a 

% Ct. Error 

uCi /mL 

% Ct. Error 

06/18/96 

06/18/96 

06/18/96 

eal 

eal 

eal 

0 < 4.681e702 uCi/mL 06/18/96 eal 

0 n/•a _ % Ct. Error 06/18/96 eal 

0 < 7.793e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eat 

0 < 1.484e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 5.770e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

00013 

Fag 

Group #: 96

RADIOACTIVE SHIPMENT RECORD 3. Pape I at, 334 4 

1. SHIP TO 

^l 

Company 

2. SHIP FROM U .S. DEPT. OF ENERGY C/O 

4. Ship Prepaid q Collect 

^Vgr^v^^^ Address 2a= 464^-2^%K!Y:. 

Company /y$.liwel--t-,t^1^ .a-, Fuw( 

Address^Z f'^ II `^ 

Via Moto 

q Excl. Use 

q Air Psgr 

q Air Cargo 

Ci ty, State, Zip Qr ctilMal . 1AIA Ci ao -Is 

Attention-°'^^' 

Ci ty, State, ZW W 

ZIP 

q UPS Surface q Mail 

El Site Carrier 

J1A ¢t cAv0t= wr, Contact K-J--/G"e, 

SHIPMENT AUTHORIZATION NUMBER 

Phone 9a5- 3-75-3131 Phone M09 -1cx:,d 7- 

5. HM Proper Thipping Name: Radioac tive Mate rial, 

excepted package . empty packaging 7 UN2910 

excepted package - instruments or ar ticles 7 UN2910 

excepted package . gmited quan tity of mate rial7 UN2910 

excepted package - ar ticles manufactured from 

natural or depleted uranium or natur al tho rium 

7 UN2910 

Special Farm. n.o.s. 7 UN2974 

Low Specific S ecific Activi Activity. n.o.s. - 7 UN2912 

8. Markings Applied 

Package O rientation 

Gross Weight 

q 

Radioactive . LSA q 

Type A q 

Type B q 

7. For Normal Form 

Iden tify ' 

Physic al Form Bo Liquid q Gas 

q Solid 

Chemical Form q Metal q Oxide 

n.o.s. s. 

Fsa 

(other) 

n.o.s. 

7 

? 

UN2982 

UN291 8 

8. Addition al RAM Deae. 

Limited Quantity 

Radioac tive Material 

Highway Routs C] 

Controlled Quan 

C3 Elemental 

Other 

9. Placards Applied q Yes 

If Rail Specify Placards 

q^N1'trate 

a 

L! Mixture 

^y 

LJ No 

ti ty 

I Ia. TYPE PACKAGE I ib. CONSTRUCTION I Ia. FISSILE CLASS 11 d. Labels Applied 

Strong Tight 

Type A El 

q 

q Box, FB 

El Wood 

q Steel 

Non-Fissile. 

Fossils Exempt 

Fissile 1 

Empty 

q Radioac 

q 

q Route Mm q yes No 

ti Type B 

Type B(U) q C1 Drum Fisal Ile II 

ve White 1 

Radioac tive Yellow II 

q Radioac 

10. EMERGENCY RESPONSE 

ti Type e(M) q Cl CasJ^ 

Other T' I^ 1Z-Crc 

Fissile ill 

Gms Fssile 

ve Yellow II! 

q Subsidi Hazard 

IJ 

Telephone 

q 

t50'7 ) 3^3 . 73900o 

Emergency Response Guide(s): 

Ej 3k ref 

Warning - Assile Class g! Shipment Do Not Load More Than A/A-Packagas Per 140hide. /n Load7ng and Stcarge A reas, Keep at Least 10 Feat 

From Other Packages Bearing Radioac tive Labe/a. 

12. No. Pk a. Model Package COCIS ec Se rial No. Seal No. T.I. Isotopes Curies/PkL Gr. Wt. 

I 41i v NL{ _^5 A TI FA cs- 13^ to x sLdS 

arb 

S.nF - 3t el L. -G Ito ,,, 1 io. tt• S014-A L-IT. 13 KX-13 

CcC - ii I o Z^Î 

(Shipper may desc ribe package in deta ll on one of the unused gross abo ve) TOTALS N t V3te1:.13 Q^j CBS 

13. This is to certify that the above named mate rials are prope rly clessiriad, desc ribedackaged, marked and labeled, and are in proper condi tion for 

transp tta tion, according to the applicable federal, state loc al and interna ti on al regula tions for the transpo rtation of hazardous mate rials. 

Corti is Sig Lure On beh alf of DOE-RL Date Organiza tion Complete Cost Code lino. End Func tion) 

1 , Co . G -LS - cr(de , — tAAot=•Iz L ê s KPSOF 514 100 

74- Dose Rate-oi?ackage Doss Rate at 1 Mater from Su rface Smears of Outer TRUCK LOAD OR EXCLUSIVE USE 

of Package 

,®

0 

0 

"THIS PACKAGE CONFORMS TO THE 

CONDITIONS AND LIMITATIONS 

SPECIFIED IN 49 CFR 173.421 FOR 

RADIOACTIVE MATERIAL"

Figure 1 

SAMPLE CHECK-IN LIST 

it hr 57+PP IN Ca LSMOO 

Date/Time Received Z/7-/S=^^llJ Client Name 

Project/Client # 

/ 

9C —4!9 Ao 

Batch or Case I 

ri/ 

WHC-SOW-93-0003 

Revision 4 

- Cooler ID (if noted on outside of cooler) _5^ -- e^7 1S&r44 / 9 

1. Condition of shipping container? 

2. Custody Seals on cooler intact? Yes [ No [ ] 

3. Custody Seals dated and signed? Yes (J No [ j 

4. Chain of Custody record is taped on inside of cooler lid? Yes [^.J' No [ J 

5. Vermiculite/packing material is: Wet [ ] Dry [ 

6. Each sample is in a plastic bag? Yes [ No [ J 

7. Number of sample containers in cooler: 

a. Samples have: tape hazard labels 

custody seals appropriate sample 

labels 

9. )Samples are: X in good condition leaking 

broken have air bubbles 

other 

10. Coolant Present? Yes ( No [ ] Sample Temperature L^ C 

11. The following paperwo should be Accounted for (N/A if not applicable): 

Chain of Custody N(s) 

Request for Analysis f(s) 

Airbill t Carrier 

12. Have any anomalies been identified above? Yes [ ] No 

13. Memos have been initiated for all anomalies identified above? Yes l[, 

Printed Name/Signature Date/Time 

33 0 01 0 16 

(`

Qwnterm 

SFafflso êse^l a 

J^ 

•ann 

Coaditlon Upon Rec eipt Variance Report 

St. Louis Laboratory 

TA& No.' ^^7 X- 

Client: 'L^ Date: b —.Z i3O 9 G ©, o f 

Project No •J^ /`^^^ Initiated by: H'1 

Shipper/No: /= eo %x /4 `l 2 6 Y9- ? 6 t RFA/COC Numbers: a 

Condidon/Variance (Cbecb all tbat apply): 

1. q Samp le received brokenfle king. 

2. q Samp le received without proper preservative. 

q Coo ler temperature not within 4C t 2C 

Record temperature: 

q pH 

q other. 

3. q Sample received in improper cooaimer. 

4. q Sample received without proper paperwork. Explain: 

S. q Paperwork received w ithout samp le. 

6. q No sample ID on samp le 

7. E3— CWWdy tape diswrbe /bi 

q No vartuaces were noted daring sample reaipt. 

Notes: A C'_+ r V t 1! v 1 ' C_., ^ s hey 

Corrective Action: 

8. q Sample ID on couamar does not match samp le ID 

on paperwork. Explain: 

9. q Ali coolers an sirbiil tat received wih shipment. 

10. q Other (expla in below): 

Coolie Tempsramrs Upew Receipt: Z; C- 

,rb ifah 

q Client's Name: Im4ormed verba lly on: By: 

q C ' 's Name: Wormed m writing on: By: 

Sample(s) protested 'as W. 

q Sample(s) on bold u ntil: It released. nottlyy- 

Sample Cont rol Supervisor 

Project Manageme nt Review: 

SL•ADKN-0004. Revved i 1124/9f 

r 

3 

00017

METALS 

., a 

.t v r 

.^Si°.7 4

Ouanterro-Richland 


P.O. Box 1970 

Richland, WA 99352 

Q%'Iuanterra 

Environmental 

Services 

Project: 519.136 

Category: Mercury Sample Date : 06/17/96 

Method: EPA 7470 Receipt Date : 06/25/96 

Matrix: LIQUID Report Date : 08/15/96 

Client Ouenterro Blank Sample Prep. Analyses Detection 

ID ID Analyte CAS Number Name Date Date Result Unit Qua(. Limit Dil. 

BOHX42 1 Mercury OCBLK 07/17/96 07/17/96 UG/L U 

BOHX42 11452-OOlMS Mercury 7439-97-6 QCBLK106918-1 07/17/96 07/17/96 106 %REC 1 

BOHX42 11452-OOlMSD Mercury 7439-97-6 QCBLK106918-1 07/1719 16 07/17/96 107 XREC 1 

ROHX43 11452-002 Mercury 7439.97-6 QCBLK106918-1 07/17/96 07/17/96 4.1 UG/L 0.20 1 

MA OCLCS106918.1 Mercury 7439-97-6 QCBLK106918-1 07/17/96 07/17/96 110 KREC 1 

MA QCBLK106918.1 Mercury 7439-97.6 OCOLK106918-1 07/17/96 07/17/96 0.10 UG/L U 0.20 1 

00019

Color Before: 

Color After: 

Comments: 

^,,,^ ^,^ U.S. EPA - CLP 

1 EPA SAMPLE NO. 

INORGANIC ANALYSES DATA SHEET 

B0HX42 

Lab Name: QUANTERRA MO Contract: 519.136 

Lab Code: ITMO lase o.: SAS No.: OG No.: W01 

Matrix (soil/water): WATER ^b Sample ID: 11452011 

Level (low/med): LOW Date Received: 06/25/96 

t Solids: 0.0 

Concentration Units (ug/L or mg/kg dry weight): UG/L_ 

CAS No. Analyte Concentration C 

4^ Mercury_ 0.10 

Clarity Before: 

Clarity After: 

nRM I - IN 

U 

Q 

M 

CV 

Texture: 

Artifacts: 

SW-846 

00020

Lab Name: QUANTERRA MO 

Lab Code: ITMO -Case o.: 

Matrix (soil/water): WATER 

Level (low/med): LOW 

k Solids: 0.00 

Color Before: 

Color After: 

Comments 

U.S. EPA - CLP 

1 EPA SAMPLE NO. 


CAS No. Analyte Concentration C Q 

BOHX43 

Contract: 519.136 

SAS No.: –MG No.: W010 

^f,aa Sample ID: 11452-002 — 

Date Received: 06/25/96 


lry erc 

4.1 



IN 

_I 

Texture: 

Artifacts: 

SW-846 

00021

Analyte 

I h erc 

Initial 

Calib. 

Blank 

(ug/L) 


3 

BLANKS 

Lab Name: QUANTERRA MO Contract: 519.136_ 

Lab Code: ITMO Case No.: SAS No.: SDG No.: W01075 

Preparation Blank Matrix (soil/water): WATER 

Preparation Blank Concentration Units (ug/L or mg/kg): UG/L_ 

Continuing Calibration 

Prepa- 

Blank (ug/L) 

ration 

C 1 C 2 C 3 C Blank C M 

FORM III - IN 

00022 

SW-846


5A EPA SAMPLE NO. 

SPIKE SAMPLE RECOVERY 

—I BOHX42S 

Lab Name: QUANTERRA_MO Contract: 519.136 


Matrix (soil/water): WATER_ Level (low/med): LOW 

°s Solids for Sample: —0.0 

Analyte 


Control 

Limit 

%;R 

Spiked Sample 

Result (SSR) C 

Sample 

Result (SR) C 

Spike 

Added (SA) %-R 

Mercury— $120 1.0600 0. 1 000 U 1^,0 

Comments: 

Q M 

F V art 1 - IN SW-846 

00023




BOHX42SD 

Lab Name: QUANTERRA MO Contract: 519.136 _ ^ I 


Matrix ( soil /water): WATER Level (low/med): LOW — 

k Solids for Sample: _0.0 

Analyte 

Concentration Units ( ug/L or mg/kg dry weight): UG/L 

Control 

Limit 

%-R 

Spiked Sample 

Result ( SSR) C 

Sample 

Result ( SR) C 

Spike 

Added (SA) %;R 

Mercury 8 U- 1.0700 0.1000 U 1.00 

Comments: 

Q M 

FORM V art 1 - IN SW-846 

00024



MATRIX SPIKE DUPLICATES 


B0RX42S 


Matrix (soil/water): WATER Level (low/med): LOW 

Solids: 0.0 

Percent recoveries: 

Control Matrix Matrix Spike 

Analyte Limit Spike (S) Duplicate (SD) RPD 

106.00 107.00 

FORM VI - IN 


0-n025 

M

Analyte 

Mercury_ 

Aqueous (u /L) 

True Found %R 


7 

LABORATORY CONTROL SAMPLE 


Lab Code: ITMO_ Case No.: SAS No.: SDG No.: W01075 

Solid LCS Source: 

Aqueous LCS Source: SOL+/CHEMPUR 

Solid (mg/kg) 

True Found C Limits %R 

FORM VII - IN 

SW-846 

Of) o?F

August 9, 1996 

Karl Pool 

low 

Buyer's Technical Representative 

Zfv 


AUS MG 

P.O. Box 1970 RECEIVED 

2355 Stevens Drive 


SDLA 

Reference: Contract MPV-SVV-239000. 

Dear Mr. Pool: 

Accompanying this letter are the Data Package Deliverable for chemical analysis on the 

following WHC samples: 

SDG NUMBER SAF NUMBER 

W01056 96-016 

If you have any questions regarding this data package or require any additional information 

please contact me at 375-3131. 

Sincerely, 

Jodie Carnes 

Document Control Officer 

Receipt of this letter and the packages are acknowledged by: 

Name Date Time 

XC: Vicki Parr 

Wade Price 

Van Pettey File

Analytical Data Package Prepared For 


Chemical Analysis By 

St. Louis Laboratory 

Quanterra Enviromental Services 

Sample Delivery Group Number: W01056 

4 

An Is 

WHC IDENTIFICATION NUMBER QUANTERRA ID NUMBER 

BOHX42 11452-001 

BOHX43 11452-002 

+ 

^^ Y 

i 

J 

^.11 

fir..


13715 Rider Trail North 

Earth City, Missouri 63045 

314 298.8566 Telephone 

314 298-8757 Fax 


P.O. Box 1970 


July 12, 1996 







SDG Number W01056 



Qsiaanterra 

Environmental 

Services 

On June 25, 1996, two (2) liquid samples were received by Quanterra, Richland and transferred 

to Quanterra, St. Louis for chemical analysis. Upon receipt, the samples were given the 

following laboratory ID numbers to correspond with the specific client ID's: 

St Louis ID WHC ID Richland ID Matrix Dateo _ f Receipt 

11452-001 BOHX42 60632401 

Liquid 6/25/96 

11452-002 BOHX43 60632402 Liquid 6/25/96 




Analyses requested: pH by EPA method 9040. TOC by EPA method 9060. VOA by EPA 

method 8240. TAL ICP Metals by EPA method 6010. Arsenic by EPA 

method 7060. Lead by EPA method 7421. Selenium by EPA method 

7740. Mercury by EPA method 7470.


July 12, 1996 


SDG: W01056 

Page 2 

M. Quality Control 

V%%uanterra 

Environmental 

Services 


Matrix Spike and Matrix Spike Duplicate and/or Sample Duplicate analyses were performed per 

the protocol for each analyte. pH analysis uses only Sample Duplicate for matrix QC. 

IV. Definitions 

The following codes are used to denote laboratory quality control samples and can be found in 

the data summary section of this report: 



MKO oITO f-/.. 



samples out of holding time. Per ROD-96-0044, the samples true sampling date is 6/17/96 and 

the samples were not out of holding time. This ROD supercedes ROD-96-0035. 

General Reporting 

The results are reported in mg/L for the TOC analysis and mg/kg or ug/kg for all other analyses 

due to sample matrix. The Density of both samples was determined to be 1.00 g/ml. This value 

can be used to convert each result to the desired units. 

Volatiles 

There are no comments or nonconformances associated with this analysis.


July 12, 1996 


SDG: W01056 

Page 3 

"'uanterra 

Fn "AM=W 

serwces 

Noels 

The matrix spike recovery in sample 11452- 001 was outside the 80-120 % limit for Iead 

(137.5%) with an Relative Percent Difference for the Matrix Spike/Matrix Spike Difference of 

39.4%. The associated data for lead was flagged with an "N". 

Percent solids was not determined for the samples in SDG W01056. Due to softwar e, 

configuration, the CLP forms list solid sample result uni ts as " dry weight" and % solids as 

100 ". The results on the forms are actually mg/Kg as is and are not corrected for percent 

solids. The figure of 100 was used as percent solids for calcula tion purposes only and does not 

represent measured solids content of the samples. 

Wet chef is ry 

The Rela tive Percent Difference could not be calculated for the TOC analysis due to the sample 

concentrations being below the detec tion limit. 

I certify that this data package is in compliance with the SOW, both technically and for 

completeness, for other than the conditions detailed above, Release of the data contained in this 

hard copy data package has been authorized by the Laborato ry Manager or a designee, as 

verified by the fo ll 

owing signature. 


Quanterra Environmental Services, Inc. 

.:^^gdmo0ripeiceSVbbydsveUunfordllvnW 1036.w 

00007/

Project ID/Client: t 

1 01Q^^ LOG i 7/ ;; 

LABORATORY NONCONFO MAN F F^fO (N M) 

Ouanterra Incorporated 

NCM Initiated b y/Date:Project Manager: 

Sample Numbers / QC 

batch or lot numbers 

L^ 

- 7?--- 

Tests: C O 

Analytical 1 / ( •Q. 

q Sample control q GC WVelt/chemistryDoty review 

q Organic preparation q HPLC 

;LY Metals q Radiochemistry 

q Inorganic preparation /iq GCIMS q Reporting q 

Nonconformance (check appropriate area ): To be completed by ana{vsr 

Holding Time Violations (exceeded by 47.24 ays) Quality AssuranedQuality Control 

Category I: Laboratory Independent Cl 20. QC data reported outside of controls 

1. Holding time expired in transit q 21. Incorrect procedure used 

Cl 2. Sample recd > 48 his after sampling. or 'A holding time has q 22. SOP intentionally modified with QA and tech approval 

expired 

q 3. Test added by client after expiration q 23. Invalid instrument calibration 

Category 11: Laboratory Dependent Cl 24. Received insu fficient sample for proper analysis 

q 4. Instrument failure q 5. Analyst error Incorrect or Incomplete Client Deliverable 

q 6. Log-in error q 7. Miscommunication Cl 25. Hardcopy deliverable error 

8. Other (expl anation required) q 26. Electronic deliverable error 

Reported Detection Lbn& Elevated Due to: 

Category X.- Analysts Reruns (QA/QC) q 27. Sample matrix: Does not include high analyte content 

q 9. Surrogates q 10. Inte rn al standards Cl 28. Insu ffi cient sample volume 

Cl 11. Spike recoveries q 12. Blank q 29. Other (explanation required) 

contamination 

Category IV. Analysis Reruns (Confirmation) Mlaeeilaneous 

q 1 3. Second column q 14. Contamination q 30. Instrumenttequipment Tag-out 

check 

q 1 5. Confirmation of matrix e ffects q 31. Other (explanation required) 

q 16. Other (expl anation required) 

Category V: Analvsis Reruns (Dilution) 

Cl 17. Over calibration q 18. Under ca libration 

Cl 19. Other (explanation required) 

Notification (check appropriate areal: Po'k wired q Not Required To be completed by project manager 

Client notified by (name and date): MW 6 -4:^ Client's name and response: 

in writin g q By facsimile 

q By telep ne q Other (explain) 

Project manager ( signature and date): 

PAGE of 

q Process "as is" Cl Re-sample 

q On hold until q Other (explain)

QUANTERRA LABORATORY NONCONFORMANCE MEMO LOG=: L7 70 

Corrective Action: To be completed and r assrates nvol e 

Problem Descrlpdo t Cause 

Aghor's ' ' ials 

Corrective Actions (Short Term) Author's initials and date: 

Corrective Actions to Prevent Reoccurrence (Long Term) 

Corrective Action approved by (Supe rvisor/Group Leader) and date: 

Additional Comments: 

Corrective Ac tion to be completed by (if other than Supervisor/Group Leader): 

Date Corrective Action is to be completed: 

C 

gdkpall 

O •ality Asanrsnee Pjiview To be completed by a QA associate 

Anomaly q Deficiency 

q Further action required: 

Further action assigned to: 

q Notified Ops/Sys Manager (Initials) 

QA signature:. ^^.`^3 Date: 

Corrective Action Veriite.ttne, To be completed by a QA associate 

HCr Verification not mqui" or requested 

q Verified / CA completitRon: by 

q Cannot verify (specify reason) 

Ve rified by: 

Nonconformance Memo Closure: 

QA signature. Date: Z —^ 

Date: 

77u Office of QwIlly Asswann m intatm a copy ofMis NCW MWCanag 'UpnW status. 

PAGE 2 OF 2 

C cC:G CC

UBi UY/`J4 us: Ij WOU'J J / LIa4b wool 


RECORD OF DISPOSITION REV 1 

DATE: August 7, 1996 LABORATORY: Chtanturra 

ROD-96-0044 

Record of Diswst6on No, 

PROJECT TITLEISAF fie 96- 016 1 NCR NO.: NIA 

SAMPLE IDENTIFICATION NUMBERS: SONX42 and BCHX43 

DESCRIPTION OF EVENT: 

The chain of custody (COC) that Was sent with the samples Inco rrectly listed the sampling 

date as 4117196. The sample collection date, as verified by the field samplers log book data 

entries, was 6117196. The incorrect listing on the CDC of the samp ling date has resulted in the 

laboratory noting that sample holding times had been missed and the result data sheet 

showing a sampling date of 4117196. 

DISPOSITION OF SAMPLES: 

l 

This ROD is to serve as documentation from WHC that the sampling date of 4/17196, as listed 

on the COC, is inco rrect and that the correct sampling date is 6117196. The WHC customer has 

asked that the result data repo rt, the original and p rio ri ty re-run, be corrected to show the 

sampling date of 6117196. The case narrative Is to be re-written to report the data results using 

the co rrect sampling date (61171%). 


zoo 

Post-it' Fu Note 7871 B; 0"" 

n r 

ear. nun.. 

^ i vsc t 

}- / 

Sharon teele L/^^^ 2 ?or ss. $/7! 96 

SOLA Project Coordinator (P ria1/8 19n Name) Date 

C. N. Vi llalobos 

Technical Representative (Pdntrsyn Name) Date 

G^ ^' .T

Project W. Price 

Draft: final: Entered and ReVleued Dyt PH 

Sample Header Template: 

Sample No. Client 110 G-iietrix 

coassents 

Container Type Analysis 

Data: 

11452-001BOH1142 Liquid 

REPORT ON A PEP WIGHT lASW /MOY9t NICNLANO 10 60632401 

1 VI - Viet-40ne1 PN19040144 

1 TOC/9D60/04 

2 V0A/8240/04 

AN - Amber Gloee 11. 

MG/7470/Q4 

1 ICAP/6010/04 

1 Pe/7421/Q4 

1 SE/7740/Q4 

1 VI - Vial-20e11 MOLD/144 

11452. 00IDW -. BONX42:: .. Liquid 

REPORT ON A PER YUGUT BA5M NOTE: MICNLANO 10 60.632401 

1 Vt - Vial-4041 PN/9440/04, 

1 TOC/9060/04 

11452-001NS - 4M42. Liquid . 

REPORT ON A:PEb t(ELGNT . BABIg./MOT F.: RIOHLAMO TO 60632401 

1 vi - Yialr4pNl 74C19060/6S 

2 VOA/8240/Q4 

1 AN - Amber 61awll, AS/706Q/O4 

1 HG/7470/04 

1 

ICAP/6010/Q4 

1 Pe/7421/Q4 

I 

SE/7740/04 

11452-DOINM 9QKXA2 Liquid 

REPORT ON A PER MIGHT BASH ; ,/NOTE. RICi1LAN0 10 60632401 

2 

1 

YI - visl-40m1 

AN - Amber Gloss-it, 

VOA/6240/Q4 

AS/7060/04 

NG/7470/04 

1 

1 

iCAP/6010/Q4 

PS/7421/Q4 

SE/7740/04 

11452-OOINSORDI SONX42 Liquid 

REPORT ON A PER iBiIG6T BASIS./NOTE: RICHLA* 14 6063.2401 

1 'n 3-=Sample has not been rod screened. 

Quanterra August as 

Account: 10722 Projecn 519.136 Ouanterra-Richland QAS No. 861 Rev. 1 

Raster Saaple Login: 11.452 

t 

Oate: . CBilected Received Due Shipper Rod Category Rad Sompte No. 

Class Preservative Anal. Due Date Hold Date Site (Container Numbers.% Filled) 

1T- W46 14700 25- 4101-96 1400 09• 40L-96 fED-EX 1 Screening not Required 

S COLD 02-JUL•96 18-APR-96 R161) (236686:99) 

S COLD 02-JUL-96 15-MAY-96 8160 (236667.98) 

S COLD 02-JUL-96 01-MAY-96 1091 (236684:100 236685:100) 

$ COLD QY-JOL-96 141QCT•96 4160 (236668:100) 

S COLD 02-JUL-96 15-)NY-96 R160 (236686:100) 

S COLD 02-JUL-96 14-OCY-96 R16D (236688:100) 

S COLD 02-JUL-96 14-OCT-96 R160 (236688:100) 


S COLD 11-Rii-*e Il,Ldl ax RIM (236695:80) 

17-JUN-94 14:00 25- JNi•96 10000 09-JM-96 FED-EX 1 Screening not Required 

S COW 02-JUL-94 18-APR-96 R16D (236686:99) 

S COLD 02-JUt-96 15-MY-96 R160 (236687:98) 

17-JtRt,96 14. 25-JAM-96 10:00 09- JOL-96 MIX 1 Screening not Required 

6 COLD. 02-N!,'.96 15.10AY•96 4144 (236687:96) 

S COLD 02-JUL-96 01-"AY-96 1091 (236684:100 236685:100) 

S COLD 02•JUL-96 14.00T-96 9160 (236688;100) 

S COLD 02-JUL-96 15-IMY-96 R160 (236688:100) 

S COLD 02-JUL-96 14-OCT-96 R160 (236688:100) 

S COLD 02-JUL-96 14-OCT-96 R160 (236688:100) 


.: 17-JON-96 14:00 25TJUM•96 10:00 09-JVL. 96 fED• EX 1. Scraanino not Required 

S COLD 02-JUL-96 01-NAY-96 1091 (236684:100 236645000) 

6 COLD 02-JUL-96 14.00T-96 R16D (236688:100) 

5 COLD 02-JUL-96 15-MAY-96 R16D (236688:100) 

S COLD 02-JUL-96 14-OCT-96 R160 (236688:100) 

S COLD 02-JUL-96 14-OCT-96 R160 (236688:100) 


17-JUN-96 14:00 25-JW-94 10;00 09-J(N,•46 fED • EX i Screening not Required 

Page 1

iw 

l^ 

^ll 

Project M"94r: M. Price 

Draft; Finst:.. Entered and RevieMed Py; 

Sample Reader Teaptate: 

Account: 10722 

$aspic No. Client to C R+trix: 

Comwenti 

e Container Type Analysis 

Data: 

11452-00111SRD1 10Ri142 4iquid: 

REPORT DR A PER 4E10T gItSM Mittbt 1:10 ANA i0 60632501 

519.136-Guanterrs-R 

Nester Semple Login: 

PM 

raw 

GAS No. 861 Rev. 1 

Dater Cyttected Received pus -.Shipper Red Category Red Sample No. 

Class Preservative Mat. Due Date Notd Date Site (Container Numbers:% Fitted) 

17-046 14.00 25-JUN-94 10:00 09-OK-96 FEO-E% 1 Screening not Required 

11452-001RD4 101X42 i.iquid 11-JUN-96 14;00 25-JUN-96 10;00 09 • JUL,96 FED-EN : 1 Screening not Required 

REPORT OR A PER WIGHT SASIS•1M0 TE; RTt7N,AR0 1D-6.06:12401 

11452 .002 4=43 41g4ld 17-11!-96 1400 25-J0N-96 10:00 09 -JM -94 FED-EX 3 Screening not Required 

REPORT ON A PER HEIDXT WIS./NOTE: RICMLAUR ID 6.WAR - -. 

1 VI - Viat-4014 PN/9040/04 'S C04P 02-AX-94 18-APR-96 R160 (236691199) 

1 TOC/9060/04 S COLD 02-JUL-96 15-MAY-96 R160 (236692:98) 

2 VOA/824O/G4 S COLD 02-JUL-96 01-MY-96 1091 (236689:100 236690:100) 

1 AN - Amur Glaes• 14 AS/706 M S COLD 02-JUL-96 14.00T 796 8160 (236693:100) 

1 NG/7470/G4 S COLD 02-JUL-96 15-MAY-96 R160 (236693:100) 

1 ICAP/6010/G4 S COLD 02-JLIL-96 14-OCT-96 R160 (236693:100) 

1 PS/7421/44 S COLD 02-JUL-96 14-OCT-96 R160 (236693:100) 

1 SE/7740/04 S COLD 02-JUL-96 14-OCT-96 R16D (236693:100) 

1 VI - vial-2011 NOW104 S COLD 14.111-"e !I•LSAr"' R16D (236694:80) 

11452-002801 1OX7(43Liquid ^ 17-JINN-96 14:00 25-AN-96 N 10:00 09-JUL-96 FED - EX 3 Screening not Required 

REPORT 00 A PER W9I49T 1ASIS./NO TE: RICHLAND 10 60632402 

J 3"=Saspte has not been rad screened. 

n 

Page 2

l Cam ►' r2 C- Cw1C G^ 


Record 

0" 4124 t 

• 

40 

/ 

`7 (-( 9 L 

60 

t^Du-Lo Quanterra 

F.rw;,.+nmix,tal 

;i/^Î^Gi,/ZÎIIâ 7 _ . ^!.1^ n nn.nnnnnn n 

i. LZ^ "' `Ì n^^^'u^^Li'^ 

nnnnnnnnn^n 

2 4 

1 / r3 

P 

gymn.nson..n Mn...nnnnnn. 

^mn: nn:^ C:n IN 

gym.. 

:DC":: 

ONE MEN nnnMMnn n.n 

n....n.n.nn.nnn..n.n...nn.nn 

n': liffilmomm 

CCn::n n 

'^:EMNON 

^Mnnnnnn n. n.n...nnCn 

^mn.nnnn....n..n...nn..nn 

.^.M..nn....n.............. 

YawsaadW aarnpW rp ra7aYêtl 

Pabm B EUnM"own I LST/tePxn ^ Tu owv q a...w &, Aa6 q .4 a. Far Uamhs (^,..,,o. m,.^^. 

WHITE - Slays with the Semple, a~Y - Ralumad to Ckmf with Raport, PWK - FmW Copy 

: vO I 9-lx h I (p-) 6-211 49 F'0 a

Y' 

^y 

'V 

r> 

O.0 M 

Westinghouse Hanford 100204 

Company 

CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST 

Collector HULSE, KARL antac Rtl1estat VILLALOBOS, CARMEN a No 373.4753 MSIN S6-19 FAX 

AF Number 96-016 

Samp le 

O ri 

g in 

Putt X 

Purcbas Oder/Cluarge Code 

lae CbealN Temp. 

Pmjtct Title PUREX Vessels Flush Solutions tACb"k# W11C-N -?OS 

' pped To (Lab) QUa1161ra Method of SWpneal SW of WIag1Alr 80 No. 

reload RCRA Data PRIORITY rt6Ye Property No 

Samp le Na, lab. ID a Date Tim NwType Container Sample Analysis pdn adve 

I 

IN 

80 IIX42 

L 4/17/% 1400 (1) 20 P 

8010(42 L 4/17/% 1400 (1) 1000 all 

e 

BOHX42 

L 4/17/96 1400 (1) 40 aOs 

BOfUC42 L 4/171% 1400 (p 40 aOs 

B01IX42 L 4117196 1400 (1) 40 a6s 

IIX42 L 4/17196 1400 (p 40 aOs 

BOHX43 L 4(17/96 1400 (1) 20 P 

1 

` 

/ 

BOlIX43 L 4117196 1400 (I) 1000 all 

BOHX43 L ,4/171 96 1400 (() 40 aOs 

ACTIVITY SCAN (Lab Spccifu) G U eè 

ICP Mwb, TAL (6010) plan, Lead 97421), Aaenic (7060) Scknium (7740), Mercury (7470) 

Now 

S la] Cool to 4°C 

tell ( 

) 1 03% Nams 

TOC(9060) 

(sOCo 3^2 ) ubY. Cad to,eC 

VOA (8240) 

V J1i 

VOA (8240) l^ r/ 

Cool to 40C 

Cod to 46C 

ACTIVITY SCAN (Lab Specific) Ô(e^ N ow, 

ICP Ma.b.TAL(6010) plus. Lud(7421} Antic (70601 3ckaiu,(72401 Me"" (7470) ^ `^? 5-r 

J 

Pit (900) 

t 

Cool go 40C 

BOIIX47 L 4/17/96 1400 (t) 40 a0s (t^) (i ^^ ^j ^ < ()J^h Cod to 46C 

8010143 L 4/17196 1400 (1) 40 aas 

VOA (H40) 

10 a Cod to 4°C 

tIX43 L 4/17/96 1400 (1) 40 a(ds 

VO I") ` U J°^ Coda4-C 

OSS L66AMPI.EHAZARDSIREMARKS MSDS Yes ( No ti SPECIALINSDRUCTIONS 

Lbt oB bnawm.easies. Coffx V2 TeP/r)e).4 Ij. 3 6er1/e e.n /Ais_v ,1r .e

0 

Client Sample Screening Results 

25-Jun-96 

CLIENT CODE ID MATRIX RECEIVED DETECTOR ACQDATE SAMPLE MINUTES CNTSA NETCPMA CNTSB NETCPINB 

WIIC BOHX42 05/1996 10.00:00AM QUAD2IA 36:25f19%1:29:32PM BOHX42 30 5 0.10541667 147 3.9875 

LIQUID &c8: 6!25/1996.4:05:51 AM BKG 800 49 0.06125 730 0.9125 

Ad We: 6 125/19% TN Sa, Alq: 1.00E+00 , 1.00E+01 Alp (Dptni 1.75E-01 (uCY TUE-06 (pCY 7.88E+00 t 2.0E+01 CAT 3.2E+00 LA 

?Pt a8: 0 3 t du: L , d &R All): 7.88E+00 Sa). 3.55E-04 Lk): 3.55E+02 ± 3.6E+01 I 1.4E-0 1 

All 

4t 

WUC BOHX43 6/2 5 199610:OO:OOAM QUAD216 3 6R5 119 6 1:20:OOPAI BOUX43 20.01 16998 849.430262 1186811 59309.957 

LIQUID Bht: 6/25/19%4:05:51 AM BKG 800 36 0.045 750 0.9375 

Ad Doe. 6,25/19% Tat Sa,Alq: 2.50E-0 1 1.00E+00+ Alp (DpW 7.99E+02 (aCY 9.00E-02 (PCY 3.60E+0S ±4.7E+03 CAT 6.9E-05 Lab 

Ppl at: 2.6^ U nite: d &y Alq): 1.16E+0S Sa): 1.31E+01 14& 532E+07 ±4.8E+04 4.2E+04 

RPI I P.t"CC! W z 5--/ f C 

N 

2i-Jun-96 

III 

`^

J 

4Znil/ 4Zn1,A Q2mnloe 

Sample N BOHX43 Total Grams per sample 430 

isotope in pCi/G Bq/G KBq/G KBq / pCi/ Ltd Qty Unity for 

G sam le sample Value in MB Ltd Qt 

Total Alpha .002 745 27.5650 0.0276 11.8530 0.3204 0.0020 0.6000 

Toatl Beta 20 43100 1,594.7000 1.5947 685.7210 18.5330 20.0000 0.0034 

Cs-137 '500 21300 788.1000 0.7881 338.8830 9.1590 500.0000 0.0001 

.0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000. 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 „ ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

0.0000 0.0000 0.0000 0.0000 0.0000 ?? 

TOTAL 65,145.00 2,410.3650 2.4104 1,036.4570 28.0124 0.6035 

tr\ 

Q/^ 

`V

Sat, Jun 22, 1996 6:47 PM Pag 


Company Name: PUREX Programs , Westinghouse Hanford Company Project Code: U3 Group Y 96 

Parameter Rep Result Unit %Recov Date Analyst 

Sample N: S96P000086 • Sample ID: BOHX42 

Actinium-228 by GEA 

Ac-228 GEA Rel % Counting Err 

0 

0 

< 1.224e-04 

n/a 

uCi/mL 

% Ct. Error 

06/18/96 

06/18/96 

eal 

eal 

Alpha in Liquid Samples, 0 4.21E-07 uCi/mL 06/19/96 dgg 

Alpha L1q.- Rel. % Count Error 0 1.21E+02 % Ct. Error 06/19/96 dgg 



Americium-243 by GEA 


0 

0 

< 4.138e-05 

n/a 

uCi/mL 

% Ct. Error 

06/18/96 

06/18/96 

eal 

eal 

Beta in Liquid Samples 0 < 1.69E-06 uCi/mL 06/19/96 dgg 

Beta Liq.- Rel. % Count Error 0 5.00E+02 % Ct. Error 06/19/96 dgg 




Bi-214 GEA Rel % Counting Err 0 n/a • ": % Ct. Error 06/18/96 eal 

Cadmium-109 by GEA 0 < 4.668e- 64 uCi/mL 06/18/96 eal 

Cd-109 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 









0 

0 

< 2.394e-05 

n/a 

uCi/mL 

% Ct. Error 

06/18/96 

06/18/96 

eal 

eal 

Cesium-134 by GEA 0 < 2.19le-A5 uCi/mL 06/18/96 eal 

Cs-134 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eat 

Cesium-137 by GEA 0 < 6.041e-05 uCi/mL 06/18/96 eal 


Europium-152 by GEA 0 < 9.094e 705 uCi/mL 06/18/96 eal 


Europium-154 by GEA 0 < 7.154e-05 UCi/mL 06/18/96 eal 

Eu-154 GEA Rel % Counting Err 0 n/a I % Ct. Error 06/18/96 eal 


Eu-155 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96" eat 

Mercury-203 by GEA 0 < 1.92le-05 uCi/mL 06/18/96 eal 

Hg-203 GEA Rel % Counting Err 0 n/a 

I 

% Ct. Error 06/18/96 eal 

Iodine-131 by GEA 0 < 2.436e-05 uCi/mL 06/18/96 eal 

I-131 GEA Rel % Counting Err 0 n/a '% Ct. Error 06/18/96 eal 


K-40 GEA Rel. % Count Error 0 n/a I % Ct. Error 06/18/96 eal 


Na-22 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eal 


Na-24 GEA Rel. % Count Error 0 n/a , t:: % Ct. Error 06/18/96 eal 

Niobium-94 by GEA 0 < 2.041e-05 uCi/mL 06/18/96 eal 

Nb-94 GEA Rel % Counting Error 0 n/a % Ct. Error 06/18/96 eal 




C/ 

o^ ( 7

Sat, Jun 22, 1996 6:47 PM Pag 



Parameter Rep Result Unit %Rgcov Date Analyst 

------------------------------- 

Sample #: S96P000086 Sample ID 











Pu-239 GEA Rel % Counting Err 






Ru-103 GEA Rel % Count Error 




Se-75 GEA Rel. % Count Error 


Sn-113 GEA Rel % Counting Err 


Sr-85 GEA Rel. % Count Error 








T1-208 GEA Rel % Counting Err 

Uranium/Thorium-233 by GEA 

U/Th-233 GEA Ref % Count Err 


U-235 GEA Ref % Counting Err 


Y-88 GEA Rel. % Count Error 






Alpha in Liquid Samples 

Alpha Liq.- Rel. % Count Error 




BOHX42 [ContrnuedJ 

0 n/a % Ct. Error 06/18/96 eal 

0

Sat, Jun 22, 1996 6:47 PM 



Parameter Rep Result Unit %Recov Date 

---------------- 


Am-243 GEA Ref. % Count Error 




























Hg-203 GEA Rel % Counting Err 


I-131 GEA Rel % Counting Err 


















Pb-212 GEA Ref % Counting Err 


Pag 

Group #: 96 

Analyst 

-------------°=-- --------------------------------- 

BOHX43 (Continued] 

0 n/a % Ct. Error 06/18/96 eal 

0 6.44E-02 uCi/mL -4w* 4-mx%o`4 06/19/96 dgg 

0 2.07E-01 % Ct. Error 06/19/96 dgg 

0 < 3.750e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.136e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.228e-03 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 6.107e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 2.349e-05 uCi/mL 06/18/96 eal 

0 n /•a „ % Ct. Error 06/18/96 eal 

0 < 4.042e45 uCi/mL 06/18/96 eal 

0 n/a X Ct. Error 06/18/96 eal 

0 < 2.87le-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 4.758e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 7-'3n,o'+ 06/18/96 eal 

0 1.50 % Ct. Error 06/18/96 eal 

0 < 8.134e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 5.834e-05 uCi/mL 06/18/96 eal 

0 n/a •- % Ct. Error 06/18/96 eal 

0 < 1.677e-04 uC1/mL 06/18/96 eal 

0 n/a % Ct. Error 06 / 18/96 eal 

0 < 6.201e-0 5 uCi/mL 06/18/96 eal 

0 n/a yy % Ct. Error 06/18/96 eal 

0 < 7.454e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 8.997e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06 / 18/96 eal 

0 < 2.014e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06 / 18/96-eal 

0 < 1.982e-05 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 2.27le-05 uCi/mL 06/18/96 eat 

0 n/a % Ct. Error 06 / 18/96 eal 

0 < 3.743e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06 / 18/96 eal 

0 < 1.577e-04. uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06 / 18/96 eal 

0 < 1.389e-04 uCi/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 5.306e-05 4Ci/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 1.164e-04 uC1/mL 06/18/96 eal 

0 n/a % Ct. Error 06/18/96 eal 

0 < 3.021e-04 uCi/mL 06/18/96 eal 

L°^C'G (CQ

Sat, Jun 22, 1996 6:47 PM 


Company Name PUREX Programs Westinghouse Hanford Company Project Code: U3 Group M: 96 

Parameter 

Rep Result' Unit %Recov Date Analyst 

------------------------------- ------------------------------------------ 

Sample #: S96P000087 Sample ID: BOHX43 [Contint ied] 

Pb-214 GEA Rel % Counting Err 0 n/a % Ct. Error 

06/18/96 eal 


0 < 5.575e-01 uCi/mL 

06/18/96 eal 

Pu-239 GEA Rel % Counting Err 0 n/a % Ct. Error 

06/18/96 eal 


0 < 1.290e-03 uCi/mL 

06/18/96 eal 

Ra-224 GEA Rel % Counting Err 0 n/a % Ct. Error 

06/18/96 eal 


0 < 1.278e-03 uCi/mL 

06/18/96 eal 


06/18/96 eal 


0 < 6.930e-05 uCi/mL 

06/18/96 eal 

Ru-103 GEA Rel % Count Error 0 n/a M % Ct. Error 

06/18/96 eal 


0 < 9.131e-04 uCi/mL 

06/18/96 eal 

Ru/Rh-106 GEA Rel. % Count Err 0 n/a % Ct. Error 

06/18/96 eal 


0 < 8:328e-05 uCi/mL 

06/18/96 eal 

Se-75 GEA Rel. % Count Error 0 n/a - % Ct. Error 

06/18/96 eal 


0 < 1.033e-04 uCi/mL 

06/18/96 eal 

Sn-113 GEA Rel % Counting Err 0 n/a % Ct. Error 

06/18/96 eal 


0 < 6.957e-05 uCi/mL 

06/18/96 eal 

Sr-85 GEA Rel. % Count Error 0 n/a % Ct. Error 

06/18/96 eal 


0 < 3.910e-03 uCi/mL 

06/18/96 eat 

Th-228 GEA Rel % Counting Err 0 n/a % Ct. Error 

06/18/96 eal 


0 < 1.78le-04 uCi/mL 

06/18/96 eal 


06/18/96 eal 


0 < 2.527e-03 uCi/mL 

06/18/96 eal 


06/18/96 eal 


0 < 8.152e=04 uCi/mL 

06/18/96 eal 

T1-208 GEA Rel % Counting Err 0 n/a % Ct. Error 

06/18/96 eal 

Uranium/Thorium-233 by GEA 0 < 4.681e702 uCi/mL 

06/18/96 eal 

U/Th-233 GEA Rel % Count Err 0 n/a % Ct. Error 

06/18/96 eal 


0 < 7.793e-05 uCi/mL 

06/18/96 eal 

U-235 GEA Rel % Counting Err 0 n/a % Ct. Error 

06/18/96 eal 


0 < 1.484e-05 uCi/mL 

06/18/96 eal 

Y-88 GEA Rel. % Count Error 0 n/a % Ct. Error 

06/18/96 eal 


0 < 5.770e-05 uCi/mL 

06/18/96 eal 


0 n/a % Ct. Error 

06/18/96 eal 

Pag

RADIOACTIVE SHIPMENT RECORD 

1. SHIP TO 2. SHIP FROM u.S. DEPT. OF ENEROy c/C 

Company 

3. Pape I of 1 334 54 

4. Ship ff Prepaid q Ca lleat 

^Varc{.r. r.► Company wvSl^•..,t-r.^5ti 1'1-a.. r a..i( r^ 

Via Moto q A ir Papr 

Address Address LsZ G.F ^ °] q Excl. Use q Air Cargo 

ZC,p W q UPS Su rface q Mai 

City. State. 21P Q 'c. 6%IA t . WA Cney 152 city, State, zip 

0 She cam" 

Attention Contact y SHIPMENT AUTHORIZATION NUMBER 

Phone 'S V5 - 3-)S - 3 13 1 Phone 3C7^t - ^'TS - 1 wZ 

S. HM Pier Shipping Nam•: Radioactive Mate rial, 

excepted package - empty packaging 7 UN2910 

excepted package - instruments or ar ticles 7 UN2910 

excepted package . limited quantity of mate rial 7 UN2910 

excepted package - ar ticles manufactured from 7 UN2910 

natural or depleted ura nium or natural thorium 

Special Fonn,7 UN29 

Low Specific Activity, n.o.s. 7 UN2912 

n.o.s. 7 UN2992 

Fissile, n.o.s. ? UN291S 

(other) 

6. Markings Applied 

P ac kage O rientation 

Grose Weight 

Radioactive - LSA q 

Type A q 

Type 8 q 

S. Additional RAM Dove. 

Limited Quantity 

R ad ioactive Material 

Highway Route 

Controlled Quan tity 

11 a. TYPE PACKAGE 11b. CONSTRUCTION t td. FISSILE CLASS 11 d. Labels Appli ed 

q 

7. For Normal Form 

Iden tify ^,/ 

Physical Farm I_l LiQuid q Gas 

q Solid 

Chemical Form q Metal q Oxide 

Other 

q Elemental q^ Nitrate 

t.7 hNzture 

S. Placards Appli ed C1 Yes 

^ 

t.-'7 INo 

if Rail Specify Pla cards 

Strong Tight 

Type A 

q 

t^1l Box, FS 

L.0 Wood 

q 

Non-Fissile 

Fissile Exempt 

Empty 

q 

q 

q Route Plan q Yes No 

Radioac tive White 1 Type B 

Type BIU) q 

Steal 

q Drum 

Fissile 1 

Fissile II 

Radioactive Yellow If 

q Radioactive Yellow Ili 

q 10. EMERGENCY RESPONSE 

q 

q Telephone (5001 ) 3 Type SIM) q q Casl 

Other) 

Fissile III 

Gme Fissile 

q SubsidiW Hazard 

N/A 

-73 - 3900 Emergency Response Guide(s): 

3f' LEI 

Warning - Rssile Class A/ Shipmen t. Do Hot Load Man Than 6LA-Packages Par Vjhide. /a Loading and Stearge Areas, Keep at Least 20 Feet 

From Other Packages Bearing Red/oact/ve Cabals. 

12. No. Pk s. 

1 

Model Package 

4 f4 Y 

COC/S sc 

Nfi- 

Se rial No. 

9S 

aa^ 

Se al No. T.I. 

M A 

isotopes 

Cs - 13-'7 

Cu riesJPk 

U u 

Gr. Wt. 

4-S 44S 

Sttr= - ¢ 4 -Gill. fa. it C301^X4Z Q riX^13 

CGG - t3- t O Z.GÎ 

IShipp•r may describe package in dotal nu 

an are, of the used 1101-' abav 1 TOTALS N , t.1 

tQ3toKQ 4^s L. BS 

13. This is to cer tify that the above named mate rials are prope rly classified, desc ri bed packag ed, mark ed and label ed, and are in proper condi ti on for 

transD na tion, &cording to the applicable federal, state loc al and interna ti onal regula ti ons for the transpo rtation of hazardous mate rials. 

CsrtiT is Sip tur• On behalf of DOE-RL Date Organization Complete Cost Code (Inc. End Func tion) 

w r Ga - ZS -4ta. ^.,, t AAc b tc 1r^4 IC P SO F 8 H' 1(= 

14. u rface Dose Rate•ai?ack&go Dose Rata at 1 Motet from Surface 

of Package 

.®

'A/ 

"THIS PACKAGE CONFORMS TO THE 

CONDITIONS AND LIMITATIONS 

SPECIFIED IN 49 CFR 173.421 FOR 

RADIOACTIVE MATERIAL"

Figure 1 

SAMPLE CHECK-IN LIST 

17 M sNnir CwntreW 

Date/Time Received ^^1 _/,62J' ^1 Client Name 

/ 

Project/Client # 90 / 

Batch or Case # 

WHC-SOW-93-0003 

Revision 4 

- Cooler ID (if noted on outside of cooler) S'/7 ^3-9SO^l•CI/9 

1. Condition of shipping container? 

2. Custody Seals on cooler intact? Yes [ No [ ] 

3. Custody Seals dated and signed? Yes J No [ ] 

4. Chain of Custody record is taped on inside of cooler lid? Yes IyNo [ ] 

S. Vermiculite/packing material is: Wet [ ] Dry [ 

6. Each sample is in a plastic bag? Yes No [ ] 

C 

7. Number of sample containers in cooler: 4L 

8. Samples have: tape hazard labels 

custody seals appropriate sample 

labels 

9. Samples are: _^ in good condition leaking 

broken have air bubbles 

other 

10. Coolant Present? Yes [ No [ ] Sample Temperature 

11. The following paperwo should be accounted for (N/A if not applicable): 

Chain of Custody #(s) 

Request for Analysis #(s) 

Airbill # Carrier 

12. Have any anomalies been identified above? Yes [ ] No 

13. Memos have been initiated for all anomalies identified above? Yes 

Printed Name /Signature Date/Time 

33 

C 

CC G 2^

W 

6aYa^âal 

^.. 

G1 n î 

Ely. 2:;b 

CooMm Upon Recdpt V'artasce Report 

SL Louis Laboratory 

nods No.: //yam 

Client J&Lp&^ Due -)- 6- 2 G p ^'0 0 

Project No: .711 / •/S l/ Initiated by 

Sbipper/No:P- e o L x 16 2 Z 6 55, 9 4 1 RFA/COC Numbers: SY 4 Q a 

Coodhioo/varta= (Check all Hut apply): 

1. q Samp le received bmtediaking. 

2. q Sample received withag ptopet praervadve. 

q Cooler amperaw a net wi ds 4C t 2C 

Record temperamrs 

q PH 

q otber, 

3. q Samp le received is imps op ar wamiea. 

4. q Samp le received w id n - proper paperwork. F.rplaW 

S. q Paperwork received wthotx sample. 

6. q No sample ID on sample container. 

7. E — Cu stody taps 

q No variances were goad dirYR $W*k ncWPL 

Noes: 4 (14 t es t i-v C G.* ^ s he r 

Convedve Acdm* 

S. q Sample ID on cooai mer does not mash samp le ID 

on paperwork. Expki: 

9. q All coolers oa airM'II not received wid shipmear. 

10. q Odw (explain below): 

Cedar Tasaprasae IIpo Reclirt z^ L 

,Ralf 13 r4iitn 

q Client's Name:. 1 rmed verbally ore: 

a C ' 's Name: W"md in write0g'&c 

Samples) Processed *as is'. 

q Somple(s) on hold unto: 

if released, now. 

Sample Control Supervisor Rsvisw: 

Darr !o 'l 6 -^^ 

Project Manageme nt Review: 

^f 

// t - Dam: 

O/ 

s SL-ADMW-0004. Revi d 

OaIGrNA I MUST' ai MARAD fN THE !lOJWT !OS 

Hy: 

By: 

A L 

ì 

(ncnGZ

VOLATILE ORGANICS 

00022

Category: Votatiles 

Method: EPA 8240 

Matrix: LIQUID 

Client ID: BOHX42 

Analyte 

Quanterra-Richland 


P.O. Box 1970 



Blank Sample Prep. Analyses 

CAS Number Name Date Date Result Unit Qual 

Chloromthane 74-87-3 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG 

Bromomethane 74-83-9 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG 

Vinyl Chloride 75-01-4 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG 

Chloroethane 75-00-3 QCSLK105677-1 07/01/96 07/01/96 10 UG/KG 

Methylene Chloride 75-09-2 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Acetone 67-64-1 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG 

Carbon Disulfide 75-15-0 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,1-Dichloroethene 75-35-4 QCSLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,1-Dichloroethane 75-34-3 QC8LK105677-1 07/01/96 07/01/96 5 UG/KG 

1,2-Dichloroethene (total) 540-59-0 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Chloroform 67.66-3 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,2-Dichloroethane 107.06-2 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

2-Butanone (MEK) 78-93-3 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG 

1,1,1-Trichloroethane 71-55-6 OCOLK105677-1 07/01/96 07/01/96 5 UG/KG 

Carbon Tetrachloride 56.23-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

eromodichloromethane 75.27-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,2-Dichloropropane 78-87-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

cis-1,3-Dichloropropene 10061-01-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Trichloroethene 79-01.6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Dibromochloromethane 124-48-1 QCBLK1056T7 . 1 07/01/96 07/01/96 5 UG/KG 

1,1,2-Trichloroethane 79-00-5 QCSLK105677-1 07/01/96 07/01/96 5 UG/KG 

Benzene 71-43-2 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

trans- 1 ,3-Dichloropropene 10061-02-6 QCSLK105677-1 07/01/96 07/01/96 5 UG/KG 

Bromoform 75-25-2 QCSLK105677-1 07/01/96 07/01/96 5 UG/KG 

4-Methyl-2-Pentanone (MIRK) 108-10-1 QCBLX105677-1 07/01/96 07/01/96 20 UG/KG 

2-Hexanone 591-78-6 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG 

Tetrachloroethene 127-18-4 QCBLK105677-1 07101/96 07/01/96 5 UG/KG 

1,1,2,2-Tetrachloroethane 79-34.5 OCELK105677-1 07/01 196 07/01/96 5 UG/KG 

Toluene 108-88-3 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Chlorabenzene 108-90-7 QCBLK10567r-1 07/01/96 07/01/96 5 UG/KG 

EthylBenzene 100-41-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Styrene 100-42-5 QCBLX105677-1 07/01/96 07/01/96 5 UG/KG 

Xylene (total) 1330-20-7 QCBLK1056T7-1 07/01/96 07/01/96 5 UG/KG 

Toluene-d8 (SURR) 2037-26-5 QCBLK105677-1 07/01 196 07/01/96 103 %REC 

Bromofluorobenzene (SURR) 460-00-4 QCBLK105677-1 07/01/96 07/01/96 101 %REC 

1,2-Dichloroethane-d4 (SURR) 17070-07-0 QCBLK105677-1 07/01/96 07/01/96 114 %REC 

,Vivanterra 

Environmental 

Services 

Sample Date : 06/17/96 

Receipt Date : 06/25/96 

Report Date : 08/15/96 

Quanterra ID : 11452-001 

Detection 

Limit Dilution 

000 &Z^)

Category: Votatiles 




Quanterra-Richtand 


P.O. Box 1970 



Vjuanterra 

Environmental 

Services 




Quanterra ID : 11452.00lMS 

Blank SampLe Prep. Analyses Detection 

AneLyte CAS Number Name Date Date Result Unit Qual. Limit Dilution 

1,1-Dichloroethene 75-3S-4 QCBLK1056 -1 07/01/96 07/01/96 7 XREC 1 

Trichloroethene 79-01-6 QCBLK105677-1 07/01/96 07/01/96 106 XREC 1 

Benzene 71.43-2 QCBLK105677-1 07/01/96 07/01/96 112 XRE.0 1 

Toluene 10848-3 QCSLK105677-1 07/01/96 07/01/96 102 %REC 1 

Chlorobenzene 108-90-7 QCBLK105677-1 07/01/96 07/01/96 98 XREC 1 

Toluene-d8 (SURR) 2037-26-5 QCBLK105677-1 07101/96 07/01/96 104 XREC i 

Bromofluorobenzene (SURR) 460.00-4 QCBLK105677 . 1 07/01/96 07/01/96 98 XREC 1 

1,2-DichLoroethene-d4 (SURR) 17070-07-0 QCBLK105677-1 07/01/96 07/01/96 113 XREC 1

Category: Volatiles 



Client ID: SONX42 



P.O. Box 1970 



,I"ivanterra 

Environmental 

Services 




Quanterra ID : 11452-OOlMSO 

Blank Sample Prep. Anatyses Detection 

Analyte CAS Number Name Date Date Result Unit Qual. Limit Dilution 

1,1-0 chloroethene 75-35-4 QCBLK105677-1 07/01/96 07/01/96 155 XAEC 

Trichloroethene 79-01-6 QCSLK105677-1 07/01/96 07/01/96 104 %REC 1 

Benzene 71-43-2 QCBLK105677-1 07/01/96 07/01/96 112 %REC 1 

Toluene 108-88-3 QCBLK105677-1 07/01/96 07/01/96 105 %REC 1 

Chlorobenzene 108-90-7 QCBLK105677-1 07/01/96 07/01/96 98 %REC 1 

Toluene-d8 (SURR) 2037-26-5 QCBLK105677-1 07/01/96 07/01/96 105 %REC 1 

Bromofluorobenzene (SURR) 460-00.4 QCBLK105677-1 07/01/96 07/01/96 100 %REC 1 

1,2-Dichloroethane-d4 (SURR) 17070-07-0 QCBLK105677-1 07/01/96 07/01/96 114 %REC 1




Client I0: ROHX43 

Analyte 



P.O. Box 1970 



Qiivanterra 

Environmental 

Services 




Quenterra ID : 11452-002 

Blank Sample Prep. Analyses Detection 

CAS Number Name Date Date Result Unit QuaL. Limit Dilution 

Bromomethane 74-83-9 QCBLK105677-1 07101/96 07/01/96 10 UG/KG U 10 

Vinyl Chloride 75-01-4 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG U 10 

Chloroethane 75-00-3 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG U 10 

Methylene Chloride 75-09-2 QCBLK105677-1 07/01 196 07/01/96 5 UG/KG U 5 

Acetone 67-64.1 QCBLK105677-1 07/01/96 07/01/96 49 UG/KG 20 

Carbon Disulfide 75-15-0 QCBLK1056TT-1 07/01/96 07/01/96 5 UG/KG U 5 

1,1-DichLoroethene 75-35-4 QCBLK105677-1 07/01/96 07101/96 5 UG/KG U 5 

1,1-Dichloroethane 75-34-3 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

1,2-Dichloroethene (total) 540-59-0 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

Chloroform 67-66-3 QCBLK105677-1 07101/96 07101/96 5 UG/KG U 5 

1,2-Dichloroethane 107-06-2 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

2-Butanone (MEK) 78-93-3 QCBLK105677-1 07/01/96 07/01 196 20 UG/KG U 20 

1,1,1-Trichloroethane 71-55-6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

Carbon Tetrachloride 56-23-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

Bromodichloromethane 75-27-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

1,2-Dichloropropane 78-87-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

cis-1,3-DichLoropropene 10061-01-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

Trichloroethene 79-01-6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

Dibromochloromethane 124-48-1 QCBLK105677-1 07/01/96 07101/96 5 UG/KG U 5 

1,1,2-Trichloroethane 79-00-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

Benzene 71-43-2 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

trans-1,3-Dichloropropene 10061-02-6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

Bromoform 75-25-2 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

4-Methyl-2-Pentanone (MIBK) 108-10-1 QCBLK1056TT-1 07/01/96 07/01/96 20 UG/KG U 20 

2-Hexanone 591-78-6 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG U 20 

Tetrachloroethene 127-18-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 

1,1,2,2-Tetrachloroethane 79-34-5 QCBLK105677-1 07/01 196 07/01/96 5 UG/KG U 5 

Toluene 108-88-3 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 

5 

Chlorobenzene 108-90-7 QCBLK105677-1 07101/96 07/01/96 5 UG/KG U 

5 

EthytSenzene 100-41-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 

5 

5 

Styrene 100-42-5 QCSLK105677-1 07/01/96 07/01/96 5 UG/KG U 

Xylene (total) 1330-20-7 QCBLK105677-1 07/01/96 07101/96 5 UG/KG U 5 

Unknown TIC-2 QCBLK105677-1 07/01/96 07/01/96 25 UG/KG J 

Toluene-d8 (SURR) 2037-26-5 QCBLX105677-1 07/01/96 07/01/96 102 %REC 

Bromofluorcbenzene (SURR) 460-00-4 QCBLK105677-1 07/01/96 07/01/96 100 %REC 

1,2-Dichloroethane-d4 (SURR) 17070-07-0 QCBLK105677-1 07101/96 07/01/96 111 %REC 

Ocoac^




Client ID: NA 

Analyte 

QUanterra-Richland 


P.O. Box 1970 



Blank Sample Prep. Analyses 

CAS Nudger Name Date Date Result Unit Qual 

Chloromethane 74-8T-3 QCBLK105677-1 07/01/96 07/01/96 10 UG/xG 

Bromomethane 74-a3-9 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG 

Vinyl Chloride 75-01-4 QCBLK1056TT-1 07/01/96 07/01/96 10 UG/KG 

Chloroethane 75.00.3 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG 

Methylene Chloride 75.09-2 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Acetone 67.64-1 OCOLK105677-1 07/01/96 07/01/96 20 UG/KG 

Carbon Disulfide 75-15.0 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,1-Dichloroethene 75-35.4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,1-Dichloroethene 75-34-3 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,2-Dichloroethene (total) 540-59.0 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Chloroform 67-66.3 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,2-Dichloroethane 107-06-2 OCOLK105677-1 07/01 196 07/01/96 5 UG/KG 

2-Butanone (HEX) 78-93-3 QCSLK105677-1 07/01/96 07/01/96 20 UG/KG 

1 1,1-Trichloroethane 71.55-6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Carbon 1 Tetrachloride 56-23-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Bromodichtoromethane 75-27-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

1 7 2-Dichloropropene 78-87-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

c1s-1,3-Dichloropropene 10061-01-5 QCSLK105677-1 07/01 196 07/01/96 5 UG/KG 

Trichloroethene 79-01-6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Dibromochloromethane 124.48-1 QCSLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,1,2-Trichtoroethane 79-00-5 QCSLK105677-1 07/01/96 07/01/96 5 UG/KG 

Benzene 71.43-2 QCBLK105677-1 07101/96 07/01/96 5 UG/KG 

trans- 1 ,3-Dichloropropene 10061-02-6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Bromoform 75-25-2 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

4-Methyt-2-Pentanone (MIRK) 108-10-1 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG 

2-Hexenone 591-78-6 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG 

Tetrachloroethene 127-18-4 QCSLK105677-1 07/01/96 07/01/96 5 UG/KG 

1,1,2,2-Tetrachloroethane 79-34-5 QCBLK105677-1 07101/96 07/01 196 5 UG/KG 

Toluene 108-88-3 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Chlorobenzene 108-90-7 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

EthylBenzene 100-41-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Styrene 100-42-5 QCBLK105677-1 07/01/96 07/01 196 5 UG/KG 

Xylene (total) 1330-20-7 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG 

Toluene-dB (SURR) 2037-26-5 QCBLK105677-1 07/01/96 07/01/96 102 %REC 

Bromofluorobenzene (BURR) 460-00-4 QCBLK105677-1 07/01/96 07/01/96 99 %REC 

1,2-Dichloroethane-d4 (BURR) 17070-07-0 QCBLK105677-1 07/01/96 07/01/96 106 %REC 

îûanterra 

Environmental 

Services 

Sample Date NA 

Receipt Date NA 

Report Date 08/15/96 

Quanterra ID : QCBLK105677-1 

Detection 


VC )^7

%uanterra 

Environmental 

Ouanterra-Richland Senices 


P.O. Box 1970 



Category: Yo lathes Sample Date NA 


Receipt Date : NA 



Client ID: NA 

Blank Semple 

Analyte CAS Number Naas 

1,1-Dichloroethene 75-35-4 QCBLK105677-1 

Triehtoroethene 79-01-6 QCSLK105677-1 

Benzene 71-43-2 OCBLK105677-1 

Toluene 108-88-3 OCBLK105677-1 

Chlorobenzene 108-90.7 QCBLK105677.1 

Toluene-dB (SURR) 2037-26-5 QCBLK105677-1 

Bromofluorobenzene (SURR) 460-00-4 QCBLK105677-1 

1,2-Dichloroethane-d4 (SURR) 17070-07-0 QCBLK105677-1 

Prep. 

Date 

Analyses 

Date Result Unit Oust. 

Ouanterrs ID : QCLCS105677-1 

Detection 


01/96 07/01/96 14 EC 1 

01196 07/01/96 103 %REC 1 

01/96 07/01/96 110 %REC 1 

01196 07/01/96 102 %REC 1 

01/96 07/01/96 96 %REC 1 

01/96 07/01/96 104 %REC 1 

01/96 07/01/96 100 %REC 1 

'01/96 07/01/96 114 %REC 1


lA 

^^ 1° tiJ r^ R 9 JA 

i^^r"^ 

VOLATILE ORGANICS ANALYSIS DATA SHEET 

Lab Code: ITMO Case No.: V45201 

Matrix: (soil/water) WATER 

Sample wt/vol: 5.00 (g/mL) G 

Level: (low/med) LOW 

t Moisture: not dec. 

GC Column: RTX-502.2 ID: 0.530 (mm) 

Contract: 519-136 

%e . EPA SAMPLE NO. 

BOHX42 

SAS No.: SDG No.: W01056 

Lab Sample ID: 11452-001 

Lab File ID: F5969 

Date Received: 06/25./96 

Date Analyzed: 07/01/96 

Dilution Factor: 1.0 

Soil Extract Volume: (uL) Soil Aliquot Volume (UL) 

CONCENTRATION UNITS: 

CAS NO. COMPOUND (ug/L or ug/Kg) UG/Kg 0 

74-87-3 --------- Chloromethane 

74-83-9 --------- Bromomethane 

75-01-4---------Vinyl Chloride 

75-00-3 --------- Chloroethane 

75-09-2---------Methylene Chloride 

10 

10 

10 

10 

5 

U 

U 

U 

U 

U 

67-64-1---------Acetone 

75-15-0---------Carbon Disulfide 

75-35-4 --------- 1,1-Dichloroethene 

75-34-3 --------- 1,1-Dichloroethane 

20 

5 

5 

5 

U 

U 

U 

U 

540-59-0 -------- 1,2-Dichloroethene (total) _ 

5 U 

67-66-3---------Chloroform 5 U 

107-06-2 -------- 1,2-Dichloroethane 5 U 

78-93-3 --------- 2-Butanone 20 U 

71-55-6 --------- 1,1,1-Trichloroethane 5 U 

56-23-5---------Carbon Tetrachloride 5 U 

75-27-4 --------- Bromodichloromethane 5 U 

78-87-5 --------- 1,2-Dichloropropane 5 U 

10061-01-5 ------ cis-1,3-Dichloropropene 5 U 

79-01-6 --------- Trichloroethene 5 U 

124-48-1 -------- Dibromochloromethane 5 


71-43-2---------Benzene 5 U 

10061-02-6 ------ trans-1,3-Dichloropropene 5 U 

75-25-2 --------- Bromoform 5 U 

108-10-1 -------- 4-Methyl-2-Pentanone 20 U 

591-78-6 -------- 2-Hexanone 20 U 

127-18-4 -------- Tetrachloroethene 5 U 

79-34-5 --------- 1,1,2,2-Tetrachloroethane 5 U 

108-88-3--------Toluene 5 U 

108-90-7 -------- Chlorobenzene 5 U 

100-41-4 -------- Ethylbenzene 5 U 

100-42-5--------Styrene 5 U 

1330-20-7 ------- Xylene (total) 5 U 

FORM I VOA 000293/90

a ^. t lE ^;i"s a`^ EPA SAMPLE NO. 


TENTATIVELY IDENTIFIED COMPOUNDS 

BOHX42 

Lab Name: QUANTERRA MO Contract: 519-136 

Lab Code: ITMO Case No.: V45201 SAS No.: SDG No.: W01056 

Matrix: ( soil /water) WATER Lab Sample ID: 11452-001 

Sample wt /vol: 5.00 ( g/mL) G Lab File ID: F5969 

Level: ( low/med) LOW Date Received: 06/25/96 

°s Moisture: not dec. Date Analyzed: 07/01/96 

GC Column: RTX-502.2 ID: 0.530 ( mm) Dilution Factor: 1.0 

Soil Extract Volume: ( uL) Soil Aliquot Volume: (uL) 


Number TICS found: 0 ( ug/L or ug /Kg) UG/Kg 

-_CAS _NUMBER-- _-- COMPOUND -NAME --_-___ _ --RT_ -- EST. _CONC. Q-- 

FORM I VOA-TIC 00030 3/90

IA 



Lab Code: ITMO Case No.: V45201 SAS No.: 

Matrix: (soil/water) 

Sample wt/vol: 

Level: (low/med) 

Moisture: not dec. 

GC Column: RTX-502.2 

Soil Extract Volume: 

CAS NO. 

WATER 

5.00 (g/mL) G 

LOW 

ID: 0.530 (mm) 

COMPOUND 

(uL) 

EPA SAMPLE NO. 

BOHX43 

SDG No.: W01056 






Soil Aliquot Volume: (UL) 


(ug/L or ug/Kg) UG/Kg Q 

74-87-3 --------- Chloromethane 10 U 

74-83-9 --------- Bromomethane 10 U 

75-01-4---------Vinyl Chloride 10 U 

75-00-3 --------- Chloroethane 10 U 

75-09-2---------Methylene Chloride 5 U 

67-64-1---------Acetone 

75-15-0---------Carbon Disulfide 5 U 

75-35-4 --------- 1,1-Dichloroethene 5 U 

75-34-3 --------- 1,1-Dichloroethane 5 U 

540- 59-0 -------- 1,2- Dichloroethene (total) _ 

5 U 

67-66-3---------Chloroform 5 U 

107-06-2 -------- 1,2-Dichloroethane 5 U 

78-93-3 --------- 2-Butanone 20 U 





10061-01-5 ---- --cis-1,3-Dichloropropene 5 U 

79-01-6 --------- Trichloroethene 5 U 

124-48-1 -------- Dibromochloromethane 5 U 


71-43-2---------Benzene 5 U 


75-25-2 ----- ---- Bromoform 5 U 


591-78-6 -------- 2-Hexanone 20 U 

127-18-4 -------- Tetrachloroethene 5 U 

79-34-5 --------- 1,1,2,2-Tetrachlorcethane 5 U 

108-88-3--------Toluene 5 U 



100-42-5--------Styrene 5 U 

1330-20-7 ------- Xylene (total) 5 U 

FORM I VOA 00031 3/90 

49

lE ^r$J ii^4Jlî - EPA SAMPLE NO. 



BOHX43 









Soil Extract Volume: (uL) 

Number TICs found: 1 







Soil Aliquot Volume: (uL) 


(ug/L or ug/Kg) UG/Kg 

CAS NUMBER COMPOUND NAME RT EST. CONC. Q 

---------------------------- -------- ------------- ----- 

1 UNKNOWN 23.31 25 J 

FORM I VOA-TIC 0 00 32 3/90

2A 

WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY 



page 1 of 1 

01 

02 

03 

04 

05 

06 

EPA SMCi SMC2 SMC3 OTHER TOT 

SAMPLE NO. (TOL)# (BFB)# 

-------- ---- -- ---- ------ (DCE)# OUT 

------------ ------ ------ ------- ----- ---- ------ -- --- 

BOHX42 

103 101 114 0 0 

BOHX43 102 100 111 0 0 

VSPK01 104 100 114 0 0 

BOHX42MS 104 98 113 0 0 

B0HX42MSD 105 100 114 0 0 

VBLKOI 102 99 106 0 0 

QC LIMITS 

SMC1 (TOL) - Toluene-d8 4 

( 80-120) 

SMC2 (BFB) = Bromofluorobenzene ( 80-120) 

SMC3 (DCE) = 1,2-Dichloroethane-d4( 76-120) 

# Column to be used to flag recovery values 

* Values outside of contract required QC limits 

D System Monitoring Compound diluted out 

FORM II VOA-1 3/90 

00033

3A 

WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY 



Matrix Spike - EPA Sample No.: BOHX42 

SPIKE SAMPLE MS MS QC 

ADDED CONCENTRATION CONCENTRATION k LIMITS 

COMPOUND (ug/Kg) (ug/Kg) (ug/Kg) REC # REC. 

1,1-Dichloroethene 50.00 0 78.56 157 1-234 

Trichloroethene 50.00 0 53.06 106 71-157 

Benzene 50.00 0 55.87 112 37-151 

Toluene 50.00 0 50.82 102 47-150 

Chlorobenzene 50.00 0 49.14 98 37-160 

SPIKE MSD MSD 

ADDED CONCENTRATION %; k QC LIMITS 

COMPOUND (ug/Kg) (ug/Kg) REC # RPD # RPD REC. 

1,1-Dichloroethene 50.00 77.61 155 1 14 1-234 

Trichloroethene 50.00 51.73 104 2 14 71-157 

Benzene 50.00 56.06 112 0 11 37-151 

Toluene 50.00 52.32 105 3 13 47-150 

Chlorobenzene 50.00 49.22 98 0 13 37-160 

# Column to be used to flag recovery and RPD values with an asteri6R 

* Values outside of QC limits 

RPD: 0 out of 5 outside limits 

Spike Recovery: 0 out of 10 outside limits 

COMMENTS: 

FORM III VOA-1 0003,4 3/90

lA EPA SAMPLE NO. 


Lab Name: QUANTERRA MO Contract: 519-136 l 

BOHX4 2MS 


Matrix: (soil/water) WATER Lab Sample ID: 11452-OOlMS 





Soil Extract Volume: (UL) 

CAS NO. COMPOUND 










75-01-4---------Vinyl Chloride 65 



67-64-1---------Acetone 20 U 


75-35-4 --------- 1,1-Dichloroethene 79 

75- 34- 3 --------- 1,1- Dichloroethane 5 U 

540-59- 0 -------- 1,2- Dichloroethene(tot— 5 U 

67-66-3---------Chloroform 58 

107-06-2 -------- 1,2-Dichloroethane 56 

78-93-3 --------- 2-Butanone 44 


56-23-5---------Carbon Tetrachloride 59 




79-01-6 --------- Trichloroethene 53 



71-43-2---------Benzene 56 


75-25-2 --------- Bromoform 5 U 


591-78-6 --------- 2-Hexanone 20 U 

127-18-4 -------- Tetrachloroethene 50 


108-88-3-:------Toluene 51 

108-90-7 -------- Chlorobenzene 49 


100-42-5--------Styrene 5 U 

1330-20-7 ------- Xylene (total) 5 U 

FORM I VOA 00035 3/90

lA 



Lab Code: ITMO Case No.: V45201 SAS No.: 

Matrix: (soil/water) 

Sample wt/vol: 

Level: (low/med) 

t Moisture: not dec. 

GC Column: RTX-502.2 

Soil Extract Volume: 

CAS NO. 

WATER 

5.00 (g/mL) G 

LOW 

ID: 0.530 (mm) 

COMPOUND 

(UL) 


BOHX42MSD 

SDG No.: W01056 

Lab Sample ID: 11452-OOIMSD 













67-64-1---------Acetone 20 U 


75-35-4 --------- 1,1-Dichloroethene 78 

75-34-3 --------- 1,1-Dichloroethane 5 U 

540-59- 0 -------- 1,2-Dichloroethene (total)_ 5 U 

67-66-3---------Chloroform 58 

107-06-2 -------- 1,2-Dichloroethane 56 

78-93-3 --------- 2-Butanone 58 






79-01-6 --------- Trichloroethene 52 

124-48-1 -------- Dibromochloromethane 5 


71-43-2---------Benzene 56 


75-25-2 --------- Bromoform 5 U 


591-78-6 -------- 2-Hexanone 20 U 

127-18-4 -------- Tetrachloroethene 53 


108-88-3--------Toluene 52 



100-42-5--------Styrene 5 U 

1330-20-7 ------- Xylene (total) 5 U 

FORM I VOA 00036 3/90





GC Column: RTX-502.2 ID: 0.530(mm) 

Instrument ID: MSF 

COMMENTS: 


VOLATILE METHOD BLANK SUMMARY 


VBLK01 


Lab Sample ID: QCBLK105677 

Time Analyzed: 0650 

Heated Purge: (Y/N) N 

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS AND MSD: 

page 1 of 1 

EPA 

SAMPLE NO. 

------------ 

01 BOHX42 

02 BOHX43 

03 VSPK01 

04 BOHX42MS 

05 BOHX42MSD 

SAMPLE ID 

11452-001 

11452-002 

QCSPK105677 

11452-OOIMS 

11452-OOlMSD 

FILE ID 

-------------- 

F5969 

F5972 

F5968 

F5970 

F5971 

ANALYZED 

1504 

1634 

1434 

1534 

1604 

FORM IV VOA 3/90 

00037


IA EPA SAMPLE NO. 






k Moisture: not dec. 



VBLK01 


Lab Sample ID: QCBLK105677 


Date Received: 



Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) 


CAS NO. COMPOUND (ug/L or ug/Kg) UG/Kg r 

74-87- 3 --------- Chloromethane 

74-83- 9 --------- Bromomethane 

75-01-4---------Vinyl Chloride 

75-00- 3 --------- Chloroethane 

75-09-2---------Methylene Chloride 

67-64-1---------Acetone 

10 

10 

10 

10 

5 

20 

U 

U 

U 

U 

U 

U 

75-15-0---------Carbon Disulfide 

75-35- 4 --------- 1,1-Dichloroethene 

75-34- 3 --------- 1,1- Dichloroethane - 

5 

5 

5 

U 

U 

U 

540-59- 0 -------- 1,2- Dichloroethene (total) _ 

5 U 

67-66-3---------Chloroform 5 U 

107-06- 2 -------- 1,2-Dichloroethane 5 U 

78-93- 3 --------- 2-Butanone 20 U 

71-55- 6 --------- 1,1,1-Trichloroethane 5 U 


75-27- 4 --------- Bromodichloromethane 5 U 

78-87- 5 --------- 1,2-Dichloropropane 5 U 

10061-01- 5 ------ cis-1,3-Dichloropropene 5 U 

79-01- 6 --------- Trichloroethene 5 U 



71-43-2---------Benzene 5 U 

10061-02- 6 ------ trans-1,3-Dichloropropene 5 U 

75-25- 2 --------- Bromoform 5 U 


591-78- 6 -------- 2-Hexanone 20 U 

127-18- 4 -------- Tetrachloroethene 5 U 

79-34- 5 --------- 1,1,2,2-Tetrachloroethane 5 U 

108-88-3--------Toluene 5 U 


100-41- 4 -------- Ethylbenzene 5 U 

100-42-5--------Styrene 5 U 

1330-20-7--- ---- Xylene (total) 5 U 

FORM I VOA 3/90 

00038

lE EPA SAMPLE NO. 



VBLK01 



Matrix: (soil/water) WATER Lab Sample ID: QCBLK105677 

Sample wt/vol: 5.00 (g/mL) G Lab File ID: F5953 

Level: (low/med) LOW Date Received: 

o Moisture: not dec. Date Analyzed: 07/01/96 

GC Column: RTX-502.2 ID: 0.530 (mm) Dilution Factor: 1.0 

Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) 


Number TICS found: 0 (ug/L or ug/Kg) UG/Kg 

CAS NUMBER COMPOUND NAME RT__-^--EST. 

-CONC^-I--Q-- 

FORM I VOA-TIC 00039 3/90

9A-LCS 

VOA WATER LCS RECOVERY 



EPA Sample No.: VSPK01 Level:(low/med) LOW 

COMPOUND 

1,1-Dichloroethene 

Trichloroethene 

Benzene 

Toluene 

Chlorobenzene 

SPIKE LCS LCS QC 

ADDED CONCENTRATION %- LIMITS 

(ug/Kg) (ug/Kg) REC # REC. 

--------- 

50 

------------- 

74 

------ 

147 

------ 

1-234 

50 52 103 71-157 

50 55 110 37-151 

50 51 102 47-150 

50 48 96 37-160 

# Column to be used to flag recovery values with an asterisk. 

* Values outside of QC limits. 

D Detected. 

NG: Not Given. Determined by QC Charting Procedures. 

Note: Additional compounds may be spiked whose recoveries are neither 

calculated nor controlled upon. 

FORM IX VO-1 00040


lA EPA SAMPLE NO. 








Soil Extract Volume: (uL) 

CAS NO. COMPOUND 


VSPKOI 


Lab Sample ID: QCSPK105677 


Date Received: 






74-87- 3 --------- Chloromethane 10 U 

74-83- 9 --------- Bromomethane 10 U 




67-64-1---------Acetone 20 U 


75-35- 4 --------- 1,1-Dichloroethene 74 

75-34- 3 --------- 1,1- Dichloroethane 5 U 

540-59- 0 -------- 1,2- Dichloroethene (total) _ 

5 U 

67-66-3---------Chloroform 57 

107-06- 2 -------- 1,2-Dichloroethane 56 

78-93- 3 --------- 2-Butanone 50 



75-27- 4 --------- Bromodichloromethane 5 U 

78-87- 5 --------- 1,2-Dichloropropane 5 U 

10061-01- 5 ------ cis-1,3-Dichloropropene 5 U 

79-01- 6 --------- Trichloroethene 52 



71-43-2---------Benzene 55 

10061-02- 6 ------ trans-1,3-Dichloropropene 5 U 

75-25- 2 --------- Bromoform 5 U 


591-78- 6 -------- 2-Hexanone 20 U 

127-18- 4 -------- Tetrachloroethene 51 

79-34- 5 --------- 1,1,2,2-Tetrachloroethane_ 5 U 

108-88-3--------Toluene 51 



100-42-5--------Styrene 5 U 

1330-20-7 ------- Xylene (total) 5 U 

FORM I VOA 

00041 3/90

METALS 

00042 

c

Category: ICAP Metals 




Blank Sample 

CAS Number Name 

7440-36-0 QCBLK105316-1 

7440-39-3 QCBLK105316-1 

7440-41-7 QCBLK105316-1 

7440-43-9 QCSLK105316-1 

7440-70-2 QCBLK105316-1 

7440-47 . 3 QCBLK105316-1 

7440-48-4 QCBLK105316-1 

7440-50-8 QCBLK105316-1 

7439-89-6 QCBLK105316-1 

7439-95 . 4 QCSLK105316.1 

7439 . 96 . 5 QCBLK105316-1 

7440-02-0 QCBLK105316-1 

7440-09-7 OCSLK105316-1 

7440-22-4 QCBLK105316-1 

7440 . 23-5 QCSLK105316-1 

7440 . 62-2 QCBLK105316.1 

7440 . 66-6 QCBLK105316-1 

U."wanterra 

Environmental 

Quanterra-Richtand Services 


P.O. Box 1970 



Sample Dale 06/17/96 



Quanterra 1D : 11452-001 

Prep. Analyses Detection 

Date Date Result Unit Qual. Limit Dilution 

06/27/96 06/27/96 5.3 MG/KG U 20.0 1 

06/27/96 06127/96 3.5 MG/KG U 6.0 1 

06/27/96 06/27/96 0.21 MG/XG B 20.0 1 

06/27/96 06/27/96 0.05 MG/KG U 0.50 1 

06/27/96 06/27/96 0.24 MG/KG U 0.50 1 

06/27/96 06/27/96 185 MG/KG B 500 1 

06/27/96 06/27/96 0.41 MG/KG U 1.0 1 

06/27/96 06/27/96 0.48 MG/KG U 5.0 1 

06/27/96 06/27/96 0.56 MG/KG U 2.5 1 

06/27/96 06/27/96 2.6 MG/KG B 10.0 1 

06/27/96 06/27/96 20.9 MG/KG G 500 1 

06/27196 06/27/96 0.12 MG/KG U 1.5 1 

06/27/96 06/27/96 0.91 MG/KG U 4.0 1 

06/27/96 06/27/96 182 MG/KG U 500 1 

06/27/96 06/27196 0.59 MG/KG U 1.0 1 

06/27/96 06/27/96 13.4 MG/KG B 500 1 

06/27/96 06/27/96 0.57 MG/KG U 5.0 1 

06/27/96 06/27/96 0.65 MG/KG U 2.0 1

Category: ICAP Metats 

Method: 

Matrix: 

EPA 6010 

LIQUID 

Client ID- BOHX42 

04anterra 

Envlronmenral 

Quanterro-Richland Services 


P.O. Box 1970 


Praieete 519.136 

samp:e uace uonrivo 

Receipt Date 06/25/96 


Quanterra ID 11452-OOINSD 


Anatyte CAS Number Name Date Date Result Unit Qual. Limit Dilution 

Atu inum 7429-90-5 QCBLK10 16-1 06/27/96 06/27/96 99 %REC 

Antimony 7440-36-0 QCBLK105316-1 06/27/96 06/27/96 1D3 %REC 1 

Barium 7440-39-3 QCBLK105316-1 06/27/96 06/27196 97 %REC 7 

Beryttium 7440-41-7 QCBLK105316-1 06/27/96 06127/96 101 %REC 1 

Cadmium 7440-43-9 QCSLK105316-1 06/27/96 06/27/96 100 %REC 1 

Chromium 7440-47-3 QCSLK105316-1 06/27/96 06/27/96 98 %REC 1 

Cobalt 7440-48.4 QCBLK105316-1 06/27/96 06/27/96 98 %REC 1 

Copper 7440-50-8 QCBLK105316-1 06/27/96 06/27/96 102 %REC i 

Iron 7439-89-6 QCBLK105316-1 06/27/96 06/27/96 99 %REC 7 

Manganese 7439.96-5 QCBLK105316-1 06/27/96 06/27/96 97 %REC 1 

Nickel 7440-02.0 QCBLK105316-1 06/27/96 06/27/96 102 %REC 1 

Silver 7440-22-4 QCBLK105316 . 1 06/27/96 06127/96 94 %REC 1 

Vanadium 7440-62-2 OC8LK105316-1 06/27/96 06/27/96 96 %REC 1 

Zinc 7440-66-6 QCBLK105316 . 1 06/27/96 06/27/96 102 %REC 1

C•"uanterra 

Environmental 

Quanterra -Rich land Se rvices 


P.O. Box 1970, 



Category: ICAP Metals Sample Date 06/17/96 

Method: EPA 6010 Receipt Date 06/25/96 

Matrix: .LIQUID Report Date 08/15/96 

Client ID: BOHX43 Quanterra ID 11452-002 


Analyte CAS Number Name Date Date Result Unit Quel. Limit Dilution 

Aluminum 7429-90-5 QCBLK10 16-1 06/27/96 06/27/96 5.3 MG/KG U 20.0 1 

Antimony 7440.36-0 QCBLK105316-1 06/27/96 06/27/96 3.5 MG/KG U 6.0 1 

Barium 7440-39-3 QCBLK105316 . 1 06/27/96 06/27/96 0.44 MG/KG 8 20.0 1 

Beryllium 7440-41-7 QCBLK105316-1 06/27/96 06/27/96 0.05 MG/KG U 0.50 1 

Cadmiun 7440-43-9 QCBLK105316-1 06/27/96 06/27/96 0.24 MG/KG U 0.50 1 

Calcium 7440-70-2 QCBLK105316-1 06/27/96 06/27/96 602 MG/KG 500 1 

Chromium 7440-47-3 QCSLK105316-1 06127/96 06/27/96 0.70 MG/KG 8 1.0 1 

Cobalt 7440-48-4 QCBLK105316-1 06/27/96 06/27/96 0.48 MG/KG U 5.0 1 

Copper 7440-50-8 QCBLK105316-1 06/27/96 06/27/96 2.5 MG/KG 2.5 1 

Iron 7439-89-6 QCBLK105316-1 06127/96 06/27/96 20.7 MG/KG 10.0 1 

Magnesium 7439-95-4 QCBLK105316-1 06/27/96 06/27/96 42.2 MG/KG B 500 1 

Manganese 7439-96-5 QCBLK105316 . 1 06/27/96 06/27/96 0.68 MG/KG B 1.5 1 

Nickel 7440-02-0 QCBLK105316-1 06/27/96 06127/96 1.1 MG/KG B 4.0 1 

Potassium 7440-09-7 QCBLK105316 . 1 06/27/96 06/27/96 182 MG/KG U Soo 1 

Silver 7440-22-4 QCBLK105316-1 06/27/96 06/27/96 0.59 MG/KG U 1.0 1 

Sodium 7440-23-5 QCBLK105316 . 1 06/27/96 06/27/96 2490 MG/KG 500 1 

Vanadium 7440-62-2 QCBLK105316-1 D6/27/96 06/27/96 0.57 MG/KG U 5.0 1 

Zinc 7440-66-6 QCBLK105316-1 06/27/96 06/27/96 1.9 MG/KG B 2.0 1

Category: ICAP Metats 



Client ID: NA 



P.O. Box 1970 



rAuanterra 

Environmental 

Services 

Sample Date : NA 

Receipt Data : NA 




Anatyte CAS Nunber Name Date Date Result Unit QuaL. Limit Dilution 

Alumnum 7429 0-5 -- QCBLK105316-1 06/27/96 06/27/96 5.3 MG/KG U 20.0 

Antimony 7440-36-0 QCSLK105316-1 06/27/96 06/27/96 3.5 MG/KG U 6.0 

Barium 7440-39-3 QCBLK105316-1 06127/96 06/27/96 -0.13 MG/KG B 20.0 

Beryllium 7440-41-7 QCSLK105316-1 06/27/96 06/27/96 0.05 MG/KG U 0.50 

Cadmium 7440-43-9 QCBLK105316-1 06/27196 06/27/96 0.24 MG/KG U 0.50 

Calcium 7440-70-2 QCSLK105316-1 06/27/96 06/27/96 2.1 MG/KG U 500 

Chromium 7440-47-3 QCBLK105316-1 06127/96 06/27/96 0.41 MG/KG U 1.0 

Cobalt 7440-48-4 QCSLX105316-1 06/27/96 06/27/96 0.48 MG/KG U 5.0 

Copper 7440-50-8 QCBLK105316-1 06127/96 06/27/96 0.56 MG/KG U 2.5 

Iron 7439-89-6 QCBLK105316-1 06/27/96 06/27/96 2.4 MG/KG B 10.0 

Magnesium 7439-95-4 OCOLK105316-1 06/27/96 06/27/96 -14.8 MG/KG B 500 

Manganese 7439-96-5 QCBLK105316-1 06/27/96 06/27/96 0.12 MG/KG U 1.5 

Nicket 7440-02-0 QCSLK105316-1 06/27/96 06/27/96 0.91 MG/KG U 4.0 

Potassium 7440-09-7 QCSLK105316-1 06/27/96 06/27/96 182 MG/KG U Soo 

Silver 7440-22-4 QCBLK105316-1 06/27/96 06/27/96 0.59 MG/KG U 1.0 

Sodium 7440-23-5 QCBLK105316-1 06/27/96 06/27/96 -11.4 MG/KG B 500 

Vanadium 7440-62-2 QCSLK105316-1 06/27/96 06/27/96 -0.87 MG/KG B 5.0 

Zinc 7440-66-6 QCBLK105316 . 1 06/27/96 06/27/96 0.65 MG/KG U 2.0




Client ID: NA 

Analyte CAS Number 

Blank Sample 

Name 



P.O. Box 1970 



Prep. 

Date 

Analyses 

Date Result Unit Qual. 

(%,rWanterra 

Environmental 

Services 

Sample Dote : NA 

Receipt Date : NA 


Quanterra ID : QCLC8105316-1 

Detection 


Alumnus 7429-90-5 QCBLK10 16-1 06/27/96 06/27/96 76 %REC 1 

Antimony 7440-36-0 QCBLK105316-1 06/27/96 06/27/96 128 %REC 1 

Barium 7440-39-3 QCBLK105316-1 06/27/96 06/27/96 93 %REC 1 

Beryltiun 7440-41-7 QCBLK105316-1 06/27/96 06/27/96 96 %REC 1 

Cadmus 7440-43-9 QCBLK105316-1 06/27/96 06/27/96 98 %REC 1 

Calcium 7440-70-2 QCBLK105316-1 06/27/96 06/27/96 103 %REC 1 

Chromium 7440-47-3 OCOLK105316-1 06/27196 06/27/96 95 %REC 1 

Cobalt 7440-48-4 QCRLK105316 . 1 06/27/96 06/27/96 98 %REC 1 

Copper 7440-50-8 QCBLK105316-1 06/27/96 06/27/96 96 %REC 1 

Iran 7439-89-6 QCBLK105316-1 06/27/96 06/27/96 92 %REC 1 

Magnesiun 7439-95-4 QCBLK105316-1 06/27/96 06/27/96 93 %REC 1 

Manganese 7439-96-5 QCBLK105316-1 06/27/96 06/27/96 95 %REC 1 

Nickel 7440-02-0 QCBLK105316-1 06/27/96 06/27/96 97 %REC 1 

Potassium 7440-09-7 QCBLK105316-1 06/27/96 06/27/96 94 %REC 1 

Silver 7440-22-4 QCBLK105316-1 06/27/96 06/27/96 106 %REC i 

Sodiun 7440-23-5 QCBLK105316 . 1 06/27/96 06/27/96 97 %REC 1 

Vanadium 7440-62-2 QCBLK105316-1 06/27/96 06/27/96 91 %REC 1 

Zinc 7440-66-6 QCBLK105316-1 06127/96 06/27/96 98 %REC 1 

^lyl3

Quanterre-Riehland 


P.O. Box 1970 


a0aanterra 

Environmental 

Services 


Category: Arsenic Sample Date 06/17/96 





Client Quanterra Blank Sample Prep. Analyses Detection 

ID ID Analyte CAS Nurber Name Date Date Result Unit Oust. Limit Dil. 

BOHX42 Arsenic QCBLK -1 06/27/96 06/28/96 MG/KG U 

BOHX42 11452-OOIMS Arsenic 7440-38-2 QCBLK105321-1 06/27/96 06/28/96 92 XREC 1 

BOHX42 11452-OOlMSD Arsenic 7440-38-2 QCBLK105321-1 06/27/96 06/28/96 97 XREC 1 

BOHX43 11452-002 Arsenic 7440-38-2 QCBLK105321-1 06/27/96 06/28/96 0.11 MG/KG U 1.0 1 

NA QCLCS105321-1 Arsenic 7440-38-2 QCBLK105321-1 06/27/96 06/28/96 105 XREC 20 

NA QCBLK105321-1 Arsenic 7440-38-2 QCBLKI05321-1 06/27/96 06/28/96 0.11 MG/KG U 1.0 1 

cc

Category: Lead 





P.O. Box 1970 



%vuanterra 

Environmental 

Services 

Semple Date : 06/17/96 



Client Quanterra Blank Sampte Prep. Analyses Detection 

ID ID AnaLyte CAS Number Name Date Date Result Unit Dual. Limit Dil. 

B HX4 Lea QCBLK 06/27/96 06/27/93 MG/KG BN 

SOHX42 r11452-001MS Lead 7439-92-1 QCBLK105321-1 06/27/96 06127/96 138 %REC N 1 

BORX42 11452-OOIMSD Lead 7439-92-1 QCBLK105321-1 06/27/96 06/27/96 92 %REC 1 

BOHX43 11452-002 Lead 7439-92-1 QCSLK105321-1 06/27/96 06/27196 2.9 MG/KG N 0.30 1 

NA QCLCS105321-1 Lead 7439-92-1 QCBLK105321-1 06/27/96 06/27/96 103 %REC 10 

NA QCBLK105321-1 Lead 7439-92-1 QCBLK105321-1 06/27/96 06/27/96 0.12 MG/KG U 0.30 1

Category: Selenium 

Method: EPA 7000 Series 




P.O. Box 1970 



10,uanterra 

Environmental 

Services 




Client Quanterra Stank Sample Prep. Analyses Detection 

ID ID Analyte CAS Nunber Name Date Date Result Unit QuaL. Limit DiL. 

BOHX42 Se enlun 7782-49-2 QCBLK105321-1 06/27/96 06/28/96 MG/KG U 

BOHX42 11452.001MS Selenium 7782-49-2 QCBLK105321-1 06/27/96 06/28/96 109 %REC 1 

BOHX42 11452-OOlMSD Selenium 7782-49-2 QCBLK105321-1 D6/27/96 06/28/96 100 %REC 1 

BOHX43 11452-002 Setenium 7782-49-2 QCBLK105321-1 06/27/96 06/28/96 0.13 MG/KG U 0.50 1 

NA QCLCS105321-1 Selenium 7782-49-2 QCBLK105321-1 06/27/96 06/28/96 95 %REC 20 

NA aCBLK105321-1 Selenium 7782-49-2 QCBLK105321-1 06/27/96 06/28/96 0.13 MG/KG U 0.50 1 

(D(-',OS I

Category: Mercury 



Cr%ivanterra 

Environmental 

Quanterra-Richland Services 


P.O. Box 1970 



Sample Dote 06/17/96 



CLient Duanterra BLank Sample Prep. Analyses Detection 

-10 ID Analyte CAS Number Name Date Date Result Unit QuaL. Limit Dil. 

BOHX42 Mercury DCSLK 06/28/96 06/28/96 MG/KG U 

BOHX42 11452-OOlMS Mercury 7439-97.6 QCBLK105509-1 06/28/96 06128/96 93 XREC 1 

BOHX42 11452-GOlMSD Mercury 7439-97-6 QCBLK105509-1 06/28/96 06/28/96 96 %REC 1 

30HX43 11452-002 Mercury 7439-97-6 QCHLK105509-1 06/28/96 06/28/96 0.05 MG/KG U 0.20 1 

NA QCLCS105509-1 Mercury 7439-97-6 QCBLK105509-1 06/28/96 06/28/96 100 %REC 1 

NA QCBLK105509-1 Mercury 7439-97-6 QCBLK105509-1 06/28/96 06/28/96 0.05 MG/KG U 0.20 1 

oco,aa


{Lûk AU 1 EPA SAMPLE NO. 


BOHX42 


Lab Code: ITMO Case o.: SAS No.: G No.: W01056-- 

Matrix (soil/water): SOIL_ ^5 Sample ID: 11452 - 001 

Level (low/med): LOW Date Received: 06/25/96 

k Solids: 100–u 

Color Before: 

Color After: 

Comments: 

Concentration Units (ug/L or mg/kg dry weight): MG/KG 

CAS No. 

4^- - 

7440-36-0 

7440-38-2 

7440-39-3 

7440-41-7 

7440-43-9 

7440-70-2 

7440-47-3 

7440-48-4 

7440-50-8 

7439-89-6. 

7439-92-1 

7439-95-4 

7439-96-5 

7439-97-6 

7440-02-0 

7440-09-7 

7782-49-2 

7440-22-4 

7440-23-5 

7440-62-2 

7440-66-6 

Analyte Concentration C Q 

uminum 

5.7 U 

Antimony_ 

3.5 U 

Arsenic_ --^.iI U 

Barium 

0.21 B 

Berylllu—m 

0.05 U 

Cadmium 

0.24 U 

Calcium 

185 B 

Chromium_ x.41 U 

Cobalt 

0.48'U 

Copper_ 

0.56 U 

Iron 

2.6 BB 

Lead —x.16 _--f- 

Magnesium 

20.9 B 

Manganese 

0.12 U 

Mercury_ 

0.05 U 

Nickel 

0.91 U 

Potassium 

182 UUUBUU 

Selenium_^^b. 

13 

Silver 

0.59 

Sodium 

13.4 

Vanadium_ 

0.57 

Zinc 

0.65 



ZI 

P 

F 

P 

P P 

P P- 

P PP 

P 

P 

Cv 

P 

P 

P P 

P PP 

Texture: 

Artifacts: 

SW-846 

00053


Lab Code: ITMO Case No.: 

Matrix (soil/water): SOIL_ 

Level (low/med): LOW 

k Solids: 1007U 

Color Before: 

Color After: 

Comments: 

CAS No. Analyte Concentration C Q 

4^- 5 

7440-36-0 

7440-38-2 

7440-39-3 

7440-41-7 

7440-43-9 

7440-70-2 

7440-47-3 

7440-48-4 

7440-50-8 

7439-89-6 

7439-92-1 

7439-95-4 

7439-96-5 

7439-97-6 

7440-02-0 

7440-09-7 

7782-49-2 

7440-22-4 

7440-23-5 

7440-62-2 

7440-66-6 

uminum 

Antimony_ 

Arsenic_ 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium_ 

Cobalt 

Copper_ 

Iron 

Lead 

Magnesium 

Manganese 

Mercury 

Nickel 

Potassium 

Selenium_ 

Silver 

Sodium 

Vanadium_ 

Zinc 



5.3 

3.5 

x.11 

0.44 

0.05 

0.24 

602 

b.70 

0.48 

2.5 

X0.7 

2.9 

X2.2 

0.68 

0.05 

1.1 

182 

—25.13 

0.59 

2490 

0.57 

1.9 



U 

U 

U B 

U 

U 

$ U 

$ BUBUUU 

U B 

—N 

IM 

P 

P 

P 

P Ppi- 

p 

P PP7- 

F- 

P 

P 

Cv 

P 

P PPPP7- 

P 


BONX43 


SAS No.: 

No" W01056 

â5 Sample ID: 11452^— 



FOR I 

Texture: 

Artifacts: 

SW-846 

00054

Initial 

Calib. 

Continuing Calibration 

Prepa- 

Blank 

Blank (ug/L) 

ration 

Analyte (ug/L) C 1 C 2 C 3 C Blank C T 

A uminum 

Antimony_ 

Arsenic 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium- 

Cobalt - 

Copper= 

Iron 

Lead 

Magnet 

Manganese 

Mercury 

Nickel - 

Potass3.um 

Selenium 

Silver - 

Sodiur 

Vanadium 

Zinc 

1.1 

1.2 

1.0 

2.4 

-71.3 

4.1 

4.8 

-TI.2 

10.5 

1.2 

1.4 

0.1 

1924.0 

1.3 

5.9 

-91.7 

5.7 

6.5 


3 

BLANKS 



Preparation Blank Matrix (soil/water): SOIL_ 

Preparation Blank Concentration Units (ug/L or mg/kg): MG/KG 

34.6 

1.1 

1.2 

1.0 

2.4 

-71.3 

5.4 

4.8 

5.9 

13.1 

1.2 

X5.1 

1.2 

0.2 

9.1 

19$4.0_ 

1.3 

5.9 

7 

5.7 

6.5 

U 

B BUUBUBB 

U UBUUUUUUU 

53.2 

34.6 

1.1 

1.2 

1.1 

2.4 

X1.3 

4.1 

4.8 

8.3 

-71.8 

1.2 

-95.1 

1.2 

0.1 

9.1 

19$4.0 

1.3 

5.9 

-91.7 

5.7 

6.5 

U 

B 

U UBB 

U BUUUU 

U 

U 

U 

U 

FORM III - IN 

1.1 

1.2 

^1. 

15-- 

3.460 F 

0.110 F 

-0.127 P 

0.050 P 

0.240 P 

2.130 P- 

0.410 P 

0.480 P- 

0.560 P 

2.435 P 

0.120 F 

_-f4 .844 P 

0.120 F 

0.050 CV 

0.910 P 

X92.400 P 

0.130 F 

0.590 P 

---I1.451 P- 

-0.866 P 

0.650 P 

00055 

SW-846


SA EPA SAMPLE NO. 


BOHX42S 

Lab Name: QUANTERRA MO Contract: 519.136_ I _ 


Matrix ( soil /water): SOIL_ Level (low/med): LOW 

Solids for Sample: 100.0 

Analyte 

u^ 

Antimony 

Arsenic_ 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium_ 

Cobalt 

Copper_ 

Iron 

Lead 

Magnesium 

Manganese 

Mercur y 

Nickel 

Potassium 

Selenium_ 

Silver 

Sodium 

vanadium_ 

Zinc 

Comments: 

Concentration Units ( ug/L or mg/kg dry weight): MG/KG 

Control 

Limit 

IsR 

-12 

80-120 

80-120 

80 - 120 

80-120_ 

80-120_ 

$^0 

80 - 120 

80 - 120 

80-120_ 

80-120- 

$qtr 

80 - 120 

80-120- 

^^ 

80-120- 

8 ^1^0 

80-120 _ 

Spiked Sample 

Result ( SSR) C 

197.23 30 

51.0250 

3.6870 

156.5840 

5.1340 

-5.0870- 

19.5560 

49.1490 

-25.3750- 

102.4200 0 

_ 

_ _ 

_ 

-_ 

_ 

_ 

_ 

_ 

_ 

Sample 

Result (SR) C 

5. 5.3200 

3.4600 

0.1100 

0.2100 

0.0500 

0.2400 

10 0 

0.4800 

0.5600 

2.5990 

0.1620 

U 

U B 

U U 

U 

U BB 

Spike 

Added (SA) %R 

2b07 0 

50 . 00 

4.00 

TO.00 

^ 

5.00 

5.00 

50.00 

25.00 

100 . 00 

2.00 

48.661 .1 

0.4635 

0.0500 U 

0.50 

0.9100 U- 

0 . 00 

_ 

1. ____ .1 U mil. ^ 

0.5900 U 

5.00 

48.1920 

51.1990 0.6500 U 

TUB 

50.00 

^^ 

1_ 02.0 

_92.2 

98.2 

102.7 

-101.7 

_^7^ 

98.3 

_101.5 

99.8 

_137.5 

92.7 

-_300.5 

_1^9 

_92.6 

6 .4 

102.4 

HW 

_ 15 

_ PFP 

_ P 

- P 

_NR 

_ P 

_ P 

_ P 

Ff F 

NR 

P 

_ Cv 

NR 

_ FP 

_ 

NR 

_ P 

FORM art 1 - IN SW -846 

00056




Lab Name: QUANTERRA MO Contract: 519.136_ 

BOHX42SD 


Matrix (soil/water): SOIL_ Level (low/med): LOW_ 

k Solids for Sample: 100.0 


Control 

Limit Spiked Sample I Sample 

Spike 

Analyte %R Result (SSR) ClResult (SR) C Added (SA) %-R 19M 

_ 

um 80-1 

99.1 .P 

Antimony_ 80-120 51.5600 

3.4600 U 50.00 103.1 

Arsenic_ 80-120 

3.8740 

0.1100 U 4.00 '- 96.8 _ FP 

Barium 80-120 174.9420 

0.2100 B -Eb0.00 L97.4 _ P 

Beryllium 80-120 

5.0700 

0.0500 U 5.00 _101.4 _ P 

Cadmium 80-120 

5.0170 

0.2400 U 5.00 100.3 

Calcium 

`g" _ PNR 

Chromium`_ TU --= 

15.53 _ 0.4100 U _ P 

Cobalt 80-120 

49.0790 

0.4800 U 50.00 98.2 _ P 

Copper` 80-120 

25.5420 - 0.5600 U 25.00 102.2 _ P 

Iron 80-120 101.9770 _ 2.5990 B 100.00 99.4 

Lead 80-120 

2.0050 

0.1620 B 2.00 92.2 F 

Magnesium 

_ NR 

Manganese 8y-1'ET-- 

48.30 _ .1 

P 

Mercury_ 80-120 

0.4820 _ 0.0500 U 0.50 96.4 _ Cv 

Nickel 80-120 X0.9660 

0.9100 U -0.00 101.9 P- 

Potassium 

Selenium 

1. 

U _lam. 3 _ FP 

Silver - 80-120 

4.7070 

0.5900 U 5.00 94.1 

Sodium` 

P 

Vanadium_ OV-IM 

47.93 0 

. 70 U 50. UU _ P 

Zinc 80-120 

50.9850 

0.6500U 

50.00 102.0 

Comments: 

Part 1 - IN SW-846 

00057



MATRIX SPIKE DUPLICATES 


BOHX42SD 


Matrix (soil/water): SOIL Level (low/med): LOW 

t Solids: 100.0 

Analyte 

Control 

Limit 

Percent recoveries: 

Matrix 

Spike (S) 

Al - î v- .1 

'Sb '20$^ 

103.10 

As 20 

96.80 

'Ba 20^ 

97.40 

-Be- -20 

101.40 

Cd -20 

100.30 - 

Ca2 0 %-^ 

Cr -20$ 0 

'Co '20gi 

'Cu -201;- 

'Fe -20k' 

'Pb '20% 

Mg 20 %- 

Mn -20 

_HI '20$ 

Ni _20% 

'K20& 

98.20 

102.20 

99.40_ 

92.20 - 

96.40 

_ _ 

-_ 

_ _ 

- 

_- 

_ 

101.90 -- 

'Se 20^ 1 

A_ g 20 

94.10 - 

Na 20^ 

V 20 

102.00 

Zn - 20% - 

_ 

_- 

_ 

FORM VI - IN 

Matrix Spike 

Duplicate (SD) RPD 

102.00 

92.20 

98.20 

102.70 

101.70 - 

98.30 

101.50 

99.80_ 

137.50 - 

92.70 

_ 

-_ 

_ _ 

- 

- 

-_ 

100.5 

-- 

0 

1 -_ 

92.60- 

_- 

96.4U- _ 

102.40 

o 

'_1.1 

4.9 

-0._ 8 

'_1.3 

1.4 - 

_0.1 

_0.1 

_0.7 

0.4 

X9.4 _ 

- - 

---T.7- 

'_ 3.9 

1. 4- 

8 -1.6- 

OT 

'0.4 

00058 

Q 

-_ 

_ 

_ _ 

_ 

- 

_ 

-_ 

- 

- 

-_ 

- NR 

-_ 

- 

_ 

M 

P- 

P 

P- 

P 

NR 

P 

F 

NTZ 

P 

CV 

P 

F P 

N17 

P

Analyte 

A - r uminum_ 

Antimony_ 

Arsenic 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium_ 

Cobalt 

Copper- 

Iron 

Lead 

Magnesium 

Manganese 

Mercury' 

Nickel 

Potassium 

Selenium_ 

Silver 

Sodium` 

Vanadium_ 

Zinc 


True Found %-R 


7 




Solid LCS Source: ERA 

Aqueous LCS Source: 

Solid ( mg/kg) 

True Found C Limits %-R 

4590.0 

39.8 

51.0 

45.4 

1$90.0 

71.0 

49.6 

112.0 

-5160.0 

^_ 0-. -U 

154.0 

-6-9.4 

11f20.0 

_1196.0 

65.9 

134.0 

FORM VII - IN 

3464.7 

- 51.0 

49.0 

44.4 

_1Y31.0 

67.4 

48.4 

108.0 

-$437.7 

_1082.7 

146.2 

_ 

_ _ 

_ 

_ 

_ 

_ 

x.18.2 

--1740.8 -- 

_-f155.7 

60.1 

131.0 

_ _ 

_22 .0 

8.4 

11.7 

11.9 

_75.0 

38.0 

29.8 

63.9 

X60.0 

107.0 

-$80.0 

-_-956.8 

32.0 

72.2 

7590.0 

119.0 

90.3 

79.0 

X50.0 

_100.0 

70.5 

162.0 

1000.0 

208.0 

--1-970.0 

-_3435.2 

88.9 

199.0 

n0059 

SW-846 

7 

128.1 

_96.1 

97.8 

103.2 

_94.9 

_97.6 

_96.4 

92.1 

94.9 

-3776 

-94.4 

_96.6 

_91.2 

97.8

Analyte 


True Found !kR 


7 






A -T-innum um 

Antimony 

Arsenic_ 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium— 

Cobalt - 

Copper_ 

Iron 

Lead 

Magneium 

Manganese 

Mercury_ 

Nickel 

Potassium 

Selenium 

Silver 

Sodium 

Vanadium 

Zinc 

Solid (mg/kg) 

True Found C Limits %R 

FORM VII - IN 

0.4 2.4 100.0 

111.1 

SW-846


Analyte 

Alum inum_ 

Antimony_ 

Arsenic 

Barium 

Beryllium 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper_ 

Iron 

Lead 

Magnesium 

Manganese 

Mercury_ 

Nickel 

Potassium 

Selenium 

Silver – 

Sodium 

Vanadium_ 

Zinc 


True Found &R 


7 



Lab Code: ITMO_ Case No.: SAS No.: SDG No.: W01056 



Solid (mg/kg) 

True Found C Limits %-R 

—^ 7 9 ^ ^^ 110 10^ . 4 

FORM VII - IN 

0OO6i 

108.0 5^1 

SW-846

WET CHEMISTRY 

00062

Category: pH 



Ouanterro-Richland 


P.O. Box 1970 



j>uanterra 

Environmental 

Seniors 




Client Ouanterra Blank Sample Prep. Analyses Detection 

1D ID Analyte CAS Number Name Date Date Result Unit Dust. Limit Dil. 

B HX4 pH PH OCBLK 06/27/96 06/27/96 PH 

BOHX42 11452-OOIDUP pH PH QCBLK105343-1 06/27/96 06/27/96 6.53 PH 0.10 1 

BOHX43 11452-002 pH PH QCBLK105343-1 06/27/96 06/27/96 11.30 PH 0.10 1 

NA OCBLK105343-1 pH PH QCBLK105343-1 06/27/96 06/27/96 5.50 PH 0.10 1 

000 k.D

Category- Total Organic Carbon 





P.O. Box 1970 



Ci"ruanterra 

Environmental 

son ices 


Receipt Date 06/25/96 



ID ID Analyte CAS Number Name Date Date Result Unit Qual. Limit Dil. 

B HX 11452-001 Total Organic C TOC QCBLK 06/Z7/96 06/27/96 MG/L U 

BOHX42 11452-OOIDUP Total Organic C TOC QCBLK105350-1 06/27/96 06127/96 1.00 MG/L U 1.00 1 

BOHX42 11452-001MS Total Organic C TOC QCBLK105350-1 06/27/96 06/27/96 98 XREC 1 

BOHX43 11452-002 Total Organic C TOC QCBLK105350-1 06/27/96 06/27/96 48.9 MG/L 1.00 1 

NA QCBLK105350-1 Total Organic C TOC QCBLKI05350.1 06/27/96 06/27/96 1.00 MG/L U 1.00 1 

NA QCLCS105350-1 Total Organic C TOC QCBLK105350-1 06/27/96 06/27/96 98 %REC I



R00-96-0039 



PROJECT TITLE/SAF #: PUREX Vessels' flush Solutions /96-016 INCR NO.: N/A 






within the Of business day priority data turnaround requirement. 


Quanterra can run 


S.R.Steele Ya July996 

SDLA Project Coo a'tor (Print/Sign Nor) Date 

r N Villalobos 

Technical Representative (Print/sign Name) 

Date






P.O. Box 1970 

Richtand, WA 99352 


110wanterra 

Environmental 

services 





ID ID Analyte CAS Number Name Date Date ResuLt Unit QuaL. Limit Dit. 

BOHX42 11 Mercury QCBLK106918-1 077/17/96 07/ / UG/L U 0. zr1 

BOHX42 11452-OOlMS Mercury 7439-97-6 QCBLK106918-1 07/17/96 07/17/96 106 %REC i 

SONX42 11452-OOlMSD Mercury 7439-97-6 QCBLK106918-1 07/17/96 07/17/96 107 %REC 1 

BOHX43 11452-002 Mercury 7439-97-6 QCBLK106918-1 07117/96 07/17/96 4.1 UG/L 0.20 1 

NA OCLCS106918-1 Mercury 7439-97-6 QCBLK106918-1 07/17/96 07/17/96 110 %REC 1 

NA QCBLK106918-1 Mercury 7439-97-6 QCBLK106918 . 1 07/17/96 07/17/96 0.10 UG/L U 0.20 1




1 

R00-96-0035 

RecordI °t otapostcton x°. 

Rev. 

PROJECT TITLE/SAF #: PUREX Vessels' Flush Solutions/96-016 NCR NO.: N/A 







DISPOSITION OF SAMPLES: The 4/17/96 data on the Chain of Custody was incorect. The 



narrative. 


S.M.Steele / '' July 9. 1996 

SOLA Project Coordinator (Print/Sign Mai-0 Data 

C.N.Villalobos JV 7/ l ^/Q(r 

Technicai Representa tive (Prins/Sign xaa,e) Date



DATE: August 7, 1996 LABORATORY: Quanterra 

ROD-96-0944 

Record of Disposi tion No. 

PROJECT TITLE/SAF #: 96-016 NCR NO.: NIA 

SAMPLE IDENTIFICATION NUMBERS: BOHX42 and BOHX43 


The chain of custody (COC) that was sent with the samples incorrectly listed the sampling 

date as 4117/96. The sample collection date, as verified by the field samplers log book data 

entries, was 6117196. The incorrect listing on the COC of the sampling date has resulted in the 

laborato ry noting that sample holding times had been missed and the result data sheet 

showing a sampling date of 4/17/96. 


This ROD is to se rve as documentation from WHC that the sampling date of 4117/96, as listed 

on the COC, is incorrect and that the correct sampling date is 6 117/96. The WHC customer has 

asked that the result data report, the original and priority re-run, be corrected to show the 

sampling date of 6117/96. The case narrative is to be re-wri tten to report the data results using 

the correct sampling date (6117/96). 


Sharon Steele Aii^,Y// &_-r"' °r^ C 5S' 

}— c^ 1p 

SDLA Project Coordinator (Print/Sig Name) Date 

C. tj Villalobos 

0013/-7(1 

Technical Representative (Print/Sign Name) Date

Author: Karl B Hulse at -WHC121 

Date: 7/30/96 12:38 PM 

Priority: Normal 

TO: Carmen N Villalobos at -WHC139 

Subject: Re: PUREX Tank U3 RCRA Concerns 

------------------------------------ Message Contents 

Karl, 

Could you please respond to the appropriate below through cc:mail? I 

know you already spoke to me about it, but I would like to have it 

documented. 

Thanks, 

Carmen 

Forward Header 

Subject: PUREX Tank U3 RCRA Concerns 

Author: Carmen N Villalobos at "WHC139 

Date: 7/16/96 8:25 AM 

Sharon, 

I have reviewed the data package for samples BORX42 & BOHX43 and have 

some concerns. Could you please address these concerns? 

Karl H, 

Could you please assist in addressing concerns #2 & 3? 

1. Certificate of Analysis: 

Section V, Shipping and Receiving, states that the samples arrived out 

of holding time and the samples were analyzed and reported as 

received. As you know the chain of custody (COC) incorrectly 

indicated the sample collection date as April 17 instead of June 17, 

thus this is the reason for the "out of holding time". 

- Could you please have Quanterra rewrite the narrative to note that 

the holding times were indeed met? 

Section V, Wet Chemistry, states that "the samples arrived unpreserved 

as determined by a pH taken prior to analysis". As you know, these 

samples require no preservation except to be maintained at 4 degrees 

Celsius. 

- Unless Quanterra has a different reason for stating this, could you 

please have them remove this section. It could lead one to believe 

that the samples were not handled accordingly. 

2. Quanterra's Condition Upon Receipt Variance Report St. Louis Laboratory 

notes that the activity scans (custody tape) had seals broken. 

- Could you please investigate the reason for this? 

Karl Hulse could you please provide some assistance. 

Carmen: I talked with Karen the sample receiver at Quanterra 

Richland. She told me that it is standard practice for the activity 

scan to be opened and checked at Quanterra in Richland. The activity 

scan is sent along with the sample to St.Louis to keep the sample all 

together if there are no other rad analysis. The activity scan bottle 

is not resealed with tamper tape by Quanterra Richland.

3. As you know the chain of custody states the sampling date for samples 

BOHX42 and BOHX43 as being 4/17/96 instead of 6/17/96. 

- An ROD was prepared addressing this anomoly. 

Karl H., could you please ensure that the COC, log books, etc. specify the 

correct sample date? 

Karl H., the received date reads 6/25/96 7:30, shouldn't it read 

6/17/96 since it is the day actually received by you? 

Carmen: The samples were taken by me on 6/17/96 and remained in my 

custody (locked in a refrigerator) until I delivered them to 

Quanterra. I relinquished custody on 6/25/96 at Quanterra at which 

time they were received by the sample custodian for Quanterra. 

4. The Master Sample Login 11452 printout states 4/17/96 sample date. 

- Could you ensure this is corrected? 

5. Quanterra's Laboratory Nonconformance Memo page 2 notes the expired 

holding times and that no corrective actions were taken. 

- Could you please ensure that Quanterra rewrite this memo to state the 

original concern and to note the corrective action as noted in the second 

ROD? Since in reality the holding times were not exceeded, could you 

please have them rewrite page 1 so it doesn't reflect a nonconformance. 

6. Mercury was analyzed with a detection limit of 0.20 mg/kg. 

- Could you please request a priority rerun of mercury with a detection 

limit of less than 0.20 mg/kg? 

I realize that this is quite a list. However, these are concerns that 

Ecology has noted in the past. If you have any questions, please call me 

at 373-4753. 

Thanks for your help!!! 

Carmen

t 

CORRESPONDENCE DISTRIBUTION COVERSHEET 

W056- 67,5 S -535' 

O 

Author Addressee Correspondence No. 

C. N. Villalobos, 373-4753 J. E. Mecca, RL 9653803 

subject: TRANSMITTAL OF PLUTONIUM URANIUM EXTRACTION PLANT TANK U3 FLUSH 

ANALYTICAL RESULTS 

INTERNAL DISTRIBUTION 

Approval Date Name Location u/att 

A-6001-538 (01/95) WEF008 

Correspondence Control A3-01 X 

R. W. Bailey S6-15 

R. J. Bliss B3-04 

D. G. Hamrick S6-15 X 

D. G. Harlow S6-19 

J. P. Hayfield S6-18 

/^ly/1 G. J. LeBaron S6-19 X 

S. R. Moreno 133-06 

W. A. Peiffer S6-19 

M. J. Stephenson H6-20 

C. N. Villalobos S6-19 X 

DGH:CNV File/LB

W Westinghouse 

Hanford Company 

P.O. Box 1970 Richland, WA 99352 

September 18, 1996 9653803 

J. E. Mecca, Director 

Transition Programs Division 

U.S. Department of Energy 

Richland Operations Office 


Dear Mr. Mecca: 

TRANSMITTAL OF PLUTONIUM URANIUM EXTRACTION PLANT TANK U3 FLUSH ANALYTICAL 

RESULTS 

Reference: Letter, D. G. Hamrick, WHC, to J. E. Mecca, RL, "Transmittal of 

Plutonium Uranium Extraction Plant U Cell Vessels and F11 System 

Vessels, Part II (Tank F-18) Loop Flush Analytical Results," 

dated April 25, 1996. 

Attachment 1 are laboratory analytical results conducted on the final flush 

for the Plutonium Uranium Extraction (PUREX) Plant Tank U3. These results are 

transmitted in accordance with U.S. Department of Energy, Richland Operations 

Office/Westinghouse Hanford Company agreement with State of Washington 

Department of Ecology (Ecology) and the U.S. Environmental Protection Agency 

(EPA). 

A copy of the Predetermination Report, designating the final flush solution 

based on the analytical results, is also included in Attachment 1. The final 

flush for this tank was designated as non-dangerous waste. 

This is the last of the analytical results from vessel flushes as defined in 

the reference and in WHC-SD-EN-TI-283, Revision 0, "Data Quality Objectives 

for PUREX Deactivation Flushing." 

uaaaaore Hanford Operations and Engineering Contractor for the US Department of Energy

Mr. J. E. Mecca 9653803 

Page 2 

September 18, 1996 

Attachment 2 is a letter for your transmittal of these results to Ecology and 

the EPA. 

If you have any questions, please contact Mr. G. J. LeBaron (373-1792) of my 

staff. 

Very truly yours, 

D. G. Hamrick, Director 

PUREX Transition Project 

Transition Projects Division 

sah 

Attachments 2 

DOE-HQ - J. E. Newson (w/o attachments) 

RL - w/ 

G. 

B. 

J. 

B. 

L. 

P. 

S. 

A. 

0 

M. 

F. 

B. 

E. 

D. 

J. 

J. 

H. 

ttachments 

Bell 

Burton, Jr. 

George 

Hill 

Romine 

Valcich 

Veitenheimer 

Wirkkala

9653803 

ATTACHMENT 1 

TRANSMITTAL OF PLUTONIUM URANIUM EXTRACTION PLANT 

TANK U3 FLUSH ANALYTICAL RESULTS 

Page 1 of 44

PUREX TANK U3 RCRA ANALYTICAL DATA 

TABLE OF CONTENTS 

PAGE 

DESCRIPTION 

RCRAAnalytical Data Summary . . . . . . . . . . . . . . . . . . . . . . 1 

PROCESS SCREENING DATA 

Process Screening Sample P3706-P3709 . . . . . . . . . . . . . . . . . . . 3 

Chainof Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 

RAD SCREENING SAMPLE 

RAD Screening Sample by 222-5 lab 

. . . . . . . . . . . . . . . . . . . . 13 

RCRA PROTOCOL SAMPLE 

Certificate of Analysis . . . . . . . . . . . . . . . . . . . . . . 17 

Analytical Data Summary: Metals 

ICAP Metals for Field Sample Blank (BOHX42) . . . . . . . . . . . . 22 

ICAP Metals Matrix Spike . . . . . . . . . . . . . . . . . . 23 

ICAP Metals Matrix Spike Duplicate . . . . . . . . . . . . 24 

ICAP Metals for RCRA Protocol Sample (BOHX43) . . . . . . . . . . . 25 

ICAP Metals Quality Control Blank . . . . . . . . . . . . 26 

ICAP Metals Quality Laboratory Control Blank . . . . . . . . . . . . 27 

Arsenic Analysis (incl. all spikes/QC blanks) . . . . . . . . . . . 28 

Lead Analysis (incl. all spikes/QC blanks) . . . . . . . . . . . 29 

Selenium Analysis (incl. all spikes/QC blanks) . . . . . . . . . . . 30 

Mercury Analysis (incl. all spikes/QC blanks) . . . . . . . . . . . 31 

Analytical Data Summary: Wet Chemistry 

pH Analysis for RCRA Protocol Sample (incl. QC blanks) . . . . . 33 

Total Organic Carbon (TOC) Analysis (incl. all spikes/QC blanks) 34 

Analytical Data Summary: Volatile Organics 

VOA for Field Sample Blank BOHX42) . . . . . . . . . . . . . . . . . 36 

VOAMatrix Spike . . . . . . . . . . . . . . . . . . . . . . 37 

VOA Matrix Spike Duplicate . . . . . . . . . . . . . . . . 38 

VOA for RCRA Protocol Sample (BOHX43) . . . . . . . . . . . . . . . 39 

VOA Quality Control Blank . . . . . . . . . . . . . . . . 40 

VOA Quality Laboratory Control Blank . . . . . . . . . . . . . . . . 41 

Request for Mercury Re-Analysis . . . . . . . . . . . . . . . . . . . . . . 42 

Certificateof Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . 43 

Mercury Analysis (Incl. All Spikes/QC Blanks . . . . . . . . . . . . . . . 46 

PredeterminationReport 

. . . . . . . . . . . . . . . . . . . . . . . . . 47

Analyte 

RCRA ANALYTICAL DATA SUMMARY 

PUREX Tank U3 

SAMPLE LOCATION: TANK U3 

SAMPLE ID# BOHX43 

Dangerous Waste 

Designation Threshold 

m L 

RCRA Sample 

Results 

m L 

Cadmium 1.0 0.24 U 

Chromium 5.0 0.70 B 

Lead 5.0 2.9 N 

Barium 100.0 0.44 B 

Silver 5.0 0.59 U 

Arsenic 5.0 0.11 U 

Selenium 1.0 0.13 (U) 

Mercury 0.2 0.05 U 

H H12.5 11.30 

Total Organic Carbon (TOC) 100,000 (IOwt% based 

upon designation limits 

for tri-butyl 

phosphate) 

48.9 

Benzene 0.5 undetect U 

Carbon Tetrachloride 0.5 undetect U 

Chlorobenzene 100 undetect U 

Chloroform 6.0 undetect U 

1,2-Dichloroethane 0.5 undetect U 

1,1 Dichloroethylene 0.7 undetect U 

2-Butanone 200 undetect U 

Tetrachloroethylene 0.7 undetect U 

Trichloroethylene 0.5 undetect 

Vinyl Chloride 0.2 undetect LUJ 

uetinitions: 

U = compound not detected 

B = compound was found in the blank 

N = interference present in matrix

PROCESS SCREENING DATA

06%17/96 MOS 10:45 FAX 373 3176 S LAB ---- --- 

.4on, Jun )7, 1996 10:44 AM • Pag• 

Parameter 

Alpha in Liquid Samples' 




Caustic Ratio 

Cadmium-ICP-Acid Dil. 


Ce/Pr-144 GEA Rel % Count Err- 


Co-60 GEA Rel. SQ Count Error 

Color of Sample 

Chromium-ICP-Acid Dil. 





Dose Rate in mrad/hour 

DSO Exotherm using Mettler 


Eu-154 GEA Rel % .Counting Err 


Eu-155 GEA Rel % Counting -Err 


Nb-94 GEA R ql % Counting Error 

Nitrate by IC-Dionex IOQ 

Organic Vol Present/sampleprep 

lead-ICP-Acid Dil. 

pH Direct 

Pu-239/240 by TP,U-SPEC Resin 

Pu239 Relative % Count Error 

Pu-236 Tracer % Recovery 


Ra-226 GEA Rel,% Counting Err 

Received Sample Yet? 


Ru/Rh-106 GEA Ref. % Count Err 

Amt of Sam/Present sample prep 

Specific Gravity 

Tot. Organic Carbon by Coul. 

Uranium by Phosphorescence 

U-Phosphorescence Inst. Error 

Volume % Solids 

SAMPLE INQUIRY•~ 

Company Name: PUREX Programs Westinghouse Hanford ComProject Code: U3 

Sample ID: P3706 Sample a: S96P000081 

Rep Result Unit Date Analyst 

---------------------------------------------------°----- 

0 4.33E-04 uCi/:,,,L 06/13/96 akl 

0 5.34E+00 % Ct. Error 06/13/96 akl 

0 5.24E-02 uCi/mL 06/13/96 akl 

0 3.64E-01 % Ct. Error 06113/96 akl 

0 2.42e-2 lbs NaOH/gal06/13/96 dgg 

0 3.87e-02 ug/mL 06/13/96 big 

0 < 6.882e-04 uCi/,;;L - 06/12/96 krm 

0 r./a % Ct. Error 06/12/96 krm 

0

06717/56 MOO 10:47 FAX 373 3175 

Sample ID: P3707 

Darameter 

S LAS 

;on, Jun 17, 1996 10:44 AM Pag 

S41PLE INQUIRY 

;ompany Name:. PUREX Programs Westinghouse Hanford ComProiect Code: U3 Group ='r .. . 

Alpha in Liquid Samples 


3eta.in Liquid Samples 

?eta Liq..- Rel. % Count Error 

Caustic Ratio 

;admium-ICP-Acid Dil. 





Color of Sample 

Chromium-ICP-Acid Dil. 





Dose Rate in mrad/hour 

DSC Exotherm using Mettler 







Nitrate by IC-Dionex 100 

Organic Vol Present/sampleprep 

Lead-ICP-Acid Dil. 

pH-Direct 

Pu-239/240 by TRU-SPEC Resin 

Pu239 Relative % Count Error 

Pu-236 Tracer % Recovery 


Ra-226.GEA Rel % Counting Err 

Received Sample Yet? 



Amt of'Sam/Present sample prep 

Specific Gravity 

Tot, Organic Carbon by Coul. - 

Uranium by Phosphorescence 

U-Phosphorescence Inst.'Error 

Volume % Solids 

Rep Result Unit 

Sample : S96P000082 

Date Analyst 

5.56E-04 uCi/mL 06/13/96 akl 

4.73E+00 % Ct. Error 06/13/96 akl 

6.85E-02 uCi/mL . 06/13/96 akl 

3.20E-01 % Ct. Error 06/13/96 akl 

2.52e-2 lbs NaOH/gal06/13/96 dgg 

4.74e-02 ug/mL 06/13/96 big 

< 7.245e-04 uCi/mL 06/12/96 krm 

n/a % Ct. Error 06/12/96 krm 

< 4.637e-05.-uCi/mL • 06/12/96 krm 

n/a % Ct. Error 06/12/96 krm 

yellow ' '06/12/96 smf 

5.83e-01 ug/mL 06/13/96 big 

< 5.786e-05 uCi/mL 06/12/96 krm 

n/a. % Ct. Error 06/12/96 krm . 

1.960e-02 uCi/ml 06/12/96 krm 

1.64 % Ct. Error 06/12/96 krm 

9 mrad/hour. 06/12/96 smf 

0. Joules/g 06/12/96 adp 

X6/17/98 110Y 03:46 FAX 373 3178 

S LkB 

)a, Jun 7,r 1996 . `8 43 AM - p Pig {L 

4 S f. ^\ x e ^T 41 ; 

SAMPLE INQUIRY 

, - e ♦. .^ x^t`-j ^ a ;y sk '^-.^. .,^,ea{1 t -^ a` c f. t *\ .4`y 'Y a't"i 4 "• f r4- 't .,r 

, 'a^2, t t . . r:. t!':t. ;t } 3.r\:'^-Eaì^ 

^^^.^• ^ 'r ''_^ ^1- ^••-^ >^4. ^.- ti 'lh ^^•T^r a".i c-se•^^.vr. ,'rC ^'^ 1 ri-i ^ t' _ ^.. 

^mpany Name PUREX Programs Westiinghouse Hanford ComPro3ect Code U3 "_ f Group # 96 

`S•S"^' v- 3: rRt"^•••'9'•'+#,a^. •'}^1.,,?^"•Gw^.^•F ^4-+^ ^'^3'^•ti^ ^S^6i+C"•"Z+ti"T•kn ^'. .I\'•i. ^°yr'^Y•.•^'hr^ =+U,.. t'`l Cr s^'S "t^ YL is 

^ rr-''^f..^`^^r^`yû- ^ °'v'S'°'°".c" ,tca 'C' } 3 `°' z „q,l 7 '^ ..^ .r ^ x '_.. rte i.,, .w x t 

• 1 _ Y „ A 

• ` l i^ ^ f.' , •L Y x-• § • { ^ ':lam a.F •. —> „ 

\ 

y5 

. 

J 

5

X ON 08:46 FAX 373 3176 

S LAB 

,an, Jun 17, , 2996'. , 8:44 AM Pag 

SAMPLE INQUIRY -1Z 

:4G-, 

ompany Name .^' PUREX. Programs Westinghouse Hinf6rd.,C6mPro'je6t Code, U3 ,Group 

Pt 

96 

ample ID: 3 amp 

------------- 

arameter Rep R esult 

Unjt 

e, S96P00008, 

Date Analyst 

itrite . by IC -* Dionek 160 -6. 1 '. 2'OeO3 ug/mL 06/15/96 jif 

H- by Pot.-Titr , ation.. 0 < 125 ug/rnL 06/15/96 rdm 

14 Direct o 11 •.53 pH 06/15/96 rdm 

0 

j 

f 11 

QVUZ 

9

CHAIN OF CUSTODY




R00-96-0035 

Record of oispositia, mo. 

Rev. 1 

PROJECT TITLE/SAF #: PUREX Vessels' Flush Solutions/96-016 NCR NO.: N/A 







0 SPOSITION OF SAMPLES: The 4/17/96 date on the Chain of Custody was incorect. The 



narrative. 


S.M.Steeie July 9 1996 

SDLA Project Coordinator (Print/Sign Ras) Date 

C.N.Villalobos L 

711 i 

Technical Representative (Print/Sign Nm*) Date 

9



DATE: August 7, 1996 LABORATORY: Quanterra 

ROD-96-0044 

Record of Disposi tion No. 

PROJECT TITLE/SAF #: 96-016 NCR NO.: N/A 

SAMPLE IDENTIFICATION NUMBERS: BOHX42 and BOHX43 


The chain of custody (COC) that was sent with the samples incorrectly listed the sampling 

date as 4117/96. The sample collection date, as verified by the field samplers log book data 

entries, was 6117196. The incorrect listing on the COC of the sampling date has resulted in the 

laborato ry noting that sample holding times had been missed and the result data sheet 

showing a sampling date of 4117/96. 


This ROD is to se rve as documentation from WHC that the sampling date of 4/17/96, as listed 

on the COC, is incorrect and that the correct sampling date is 6117/96. The WHC customer has 

asked that the result data repo rt, the original and priority re-run, be corrected to show the 

sampling date of 6117/96. The case narrative is to be re-written to repo rt the data results using 

the correct sampling date (6/17196). 


/ 

/^ 

(//^ }' 

Sharon Steele lc,^/ .^,1 ^r/t-^ Z" 

sS. /^! • t^ 

SDLA Project C-oordinator (Print/Sig Name) Date 

?11-S/%li 

C N. Villalobos 

Technical Representative (Print/sign Name) Date


Company CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST Q 

er 

100204 

t 

ollector HULSE, KARL, aM•cuseyucel°r VIL.LALOBOS, CARMEN Tcl.Nw 3734753 MEIN 56-19 FAX 

AF Number 96-016°pk Origin 

Ywxh..e orrerKLrieee/e 

uÊ 

"Jed7'uk Pl1REX Vessels Flush Solutions L I IaCIKe1N Tt. 

W /! c -A/ cos 

' ppd To (LA) Quanterra Mefb" of swru W EM of la{Iui/Alr VIII Nc 

Gov. 

Proloc•1 RCRA Dais Twemmu d PRIORITY Ofhbk !"perly Nw 

Sample Na. IA-L ID • Dek Time Narrype C••laleAr S•nple Andyde Penervadve 

WIIX42 L 4/17/9161400 (1) 20 P 

BOIIX42 L 4117196 1400 (1) 1000 ao 

ACTIVITY SCAN (1,41, Specific) 

^V•l. b N°r 

ICP Md4kTAL(6010)pbn • Led 974212 Aw (70601 Scknê°(77401 Meraay(N70) 

,7 S" 73 Ceo1N{C 

B0IIX42 L 4/17196 1400 (1) 40 aOr a7(M) J °/a Nw 

DOl IX42 L 4/177761400 (p 40 " 

801IX42 L 0171% 1400 (1) 40 ape 

I IX42 L 017,96 1400 (p 40 i0y 

0011X43 L 0171% 1400 (() 20 P 

801(X43 L 0171% U00 (1) 1000 to 

TOC ( 900) 

VGA (5240) 

VOA (1240) 

ACTIVITY SCAN (Lob Specifw) 

ICPMakTAL(6010)pk. • L.d(7421) &A 

k(70601UW%km(7740IMsr(7470) r 

O.CM 

/r'OCn?i. 2.^ uJY. Coda{C 

`(J 

U J7i COW N 4C 

r/ 

r 

Coo1N4C 

^'O r, •F Na 

eN BMW L ,4171% 1400 (J) 40 aOt W OW) 

(OJ°(i Nmt 

DOlIX43 L 017196 1400 (1) 40 so$ 

TOC(9060) 

(70 103% Cool to 4C 

•V 1101(X43 LF. 

L 4117/96 1400 (1) 40 toe 

VOA (1240) 

to a CootN4eC 

V0A (U40) 

lIX43 L 4117196 1400 (1) 40 We 

OSS uka A LEIIAZ6011A EMAEKS MS Yes Oi 

SP ^Tww-W 6UC1'IONS^ 

►LtaB lw•em xarlea. (;0//X42 TCP 7y e1..l+ IA. a•h/e 

e.w w'n (_v ove 9 f). etbnt' H' wRmry 

23'0^1. TM 7s Ve•s w// s• ^!e 7'>

3&,V; 

l e r a Cwx c^ 


Record 

QU 41Y..r 6 

q 

.1 ? 

&C 1,-oU-L-0 Qluanterra 

EaYbunam d 

5c vk:. 

Y--.^ 

11 On"7l 

mom mom 

moon 

q NorNforird F6mme6N 

q St7n krsanf q POlsonB _ ihtknown ReWrn To Genf q DispoSe/BY ^. OMU+n'S Fa —__ MWWU Ao dun a rnmNNhsl 

DISTRiSUT)ON: WMTE - Stays with #w Sample; CANARY - RBWm®d b Chart! wWr Roport PINK • Field CapY 

C 

Ubemeyhe a "SSmdYSwW"wS lot~ 

6:26-?6l 40 ?:.j j

RAD SCREENING DATA

Sat, Jun 22, I996 6:47 PM 




Sample #: S96P000086 • Sample ID: 



Alpha in Liquid Samples. 



Am-241 GEA Ref. % Count Error 




















CS -134 GEA Rel. % Count Error 





Europium-154.by GEA 


Furopium-155 by GEA 



H9-203 GEA Rel % Counting Err 


I-131 GEA Rel % Counting Err 












BOHX42 

0 < 1.224e-04 

0 n/a 

0 4.21E-07 

0 1.21E+02 

0 < 1.622e-04 

0 n/a 

0 < 4.138e-05 

0 n/a 

0 < 1.69E-06 

0 5.00E+02 

0 < 3.275e-04 

0 n/a 

0 < 6.584e-05 

0 n/a 

0 < 4.668e=04 

0 n/a 

0 < 2.177e-04 

0 n/a 

0 < 2.360e-05 

0 n/a 

0 < 1.493e-05 

0 n/a 

0 < 2.394e-OS 

0 n/a 

0 < 2.19le-05 

0 n/a 

0 < 6.04le-05 

0 n/a - 

0 < 9.094e-05 

0 n/a 

0 < 7.154e-05 

0 n/a 

0 < 6.082e-05 

0 n/a 

0 < 1.92le-05 

0 n/a 

0 < 2.436e-05 

0 n/a 

0 < 9.284e-04 

0 n/a 

0 < 2.457e-05 

0 n/a 

0 < 1.656e-05 

0 n/a 

0 < 2.041e4S 

0 n/a 

0 < 1.476e-04 

0 n/a 

0 < 5.683e-05 

UCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi /mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi /mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

I Ct. Error 

uC1/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

% Ct. Error 

uCi/mL 

06/18/96 eal 

06/18/96 eal 

06/19/96 dgg 

06119/96 dgg 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/19/96 dgg 

06/19/96 dgg 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96" eat 

06/18/96 eal 

06/18/96 eal 

06/18/96 eat 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

06/18/96 eal 

/3, 

Pag

Sat, Jun 22, 1996 . 6:47 PM Pag 


Company Name: PUREX Programs Westinghouse Hanford Company Protect Code: U3 Group 1: 96 

Parameter 

------------------------------- 

Rep. Result Unit %Rgcov Date Analyst 

Sample #: S96P000086 Sample ID: BOHX42 [Contfnue"d] 



0 n/a % Ct. Error 

0

Sat, Jun 22, 1996 6:47 PM Pa9 




-------------------------------------------- -------------------------------------------- 

Sample #: S96P000087 Sample I0: BOHX43 [Continued) 


Beta in Liquid Samples 0 6.44 E-02 uCi/mL -wAa* ti SS.xto*A 06/19/96 dgg 

Beta Liq.- Rel. % Count Error 0 2.07E-01 % Ct. Error 06/19/96 dgg 



Bismuth-214 by GEA 0 < 1.136e-04 uCi/mL 06/18/96 eat 


Cadmium-109 by GEA 0 < 1.228e-03 uCi/mL 06/18/96 eal 

Cd-109 GEA Rel % Counting Err 0 , n/a % Ct. Error 06/18/96 eal 




Co-56 GEA Ref. % Count Error 0 n/•a _ % Ct. Error 06/18196 eal 

Cobalt-57 by GEA 0 < 4.042e-O^5 uCi/mL 06/18/96 eal 

Co-57 GEA Rel. % Count Error 0 n/a N Ct. Error 06/18/96 eal 

Cobalt-60 by GEA 0 < 2.87le-05 uCi/mL 06/18/96 eal 


Cesium-134 by GEA 0 < 4.758e-05 uCi/mL 06/18/96 eal 

Cs-134 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eat 

Cesium-137 by GEA 0 7•13,c%o\ 06/18/96 eal 

Cs-137 GEA Rel. % Count Error 0 1.50 % Ct. Error 06/18/96 eal 



Europium-154 by GEA 0 < 5. 834e-OS uCi/mL 06/ 18/96 eal 

Eu-154 GEA Rel % Counting Err 0 n/a • •• % Ct. Error 06/18/96 eat 



Mercury-203 by GEA 0 < 6.201e-05 uCi/mL 06/18/96 eal 

Hg-203 GEA Rel % Counting Err 0 n/a;: % Ct. Error 06/18/96 eal 

Iodine-131 by GEA 0 < 7.454e-OS uCi/mL 06/18/96 eal 

I-131 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 


K-40 GEA Rel: % Count Error 0 n/a % Ct. Error 06/18/96 eal 


Na-22 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18 / 96-eal 

Sodium-24 by GEA 0 < 1.982e- 05 uCi /mL 06/ 18/96 eal 

Na-24 GEA Rel. % Count Error 0 n/a % Ct. Error 06/18/96 eat 

Niobium-94 by GEA 0 < 2.27le-05 uCi/mL 06/18/96 eal 

Nb-94 GEA Rel % Counting Error 0 n/a % Ct. Error 06/18/96 eal 

Neptunium-237 by GEA 0 < 3.743e-04 uCi/mL 06/18/96 eal. 


Neptunium-239 by GEA 0 < 1.577e-04. uCi/mL 06/18/96 eal 

Np-239 GEA Rel % Counting Err 0 n/a- % Ct. Error 06/18/96 eal 

Protactinium-233 by GEA 0 < 1.389e-04; uCi/mL 06/18/96 eal 

Pa-233 GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Protactinium-234m by GEA 0 < 5.306e-05 6Ci/mL 06/18/96 eal 

Pa-234m GEA Rel % Counting Err 0 n/a % Ct. Error 06/18/96 eal 

Lead-212 by GEA 0 < 1.164e-04 uC1/mL 06/18/96 eal 


Lead-214 by GEA 0 < 3.021e-04 uCi/mL 06/ 18/96 eal 

^s

'Sat, Jun 22, 1996 6:47 PM 


Company Name: PUREX Programs Westinghouse Hanford Company Project Code: U3 Group +1: 96 

Parameter Rep Result % --tt Unit 

te--------- 

%Recov Date Analyst, 

Sample f: S96P000087 Sample ID: BOHX43 [Contini 

Pb-214 GEA Rel % Counting Err 0 n/a % Ct. Error 

06/18/96 eat 


0 < 5.575e-01 uCi/mL 

06/18/96 eal 

Pu-239 GEA Rel % Counting Err 0 n/a % Ct. Error 

06/18/96 eal 


0 < 1.290e-03 uCi/mL 

06/18/96 eal 


06/18/96 eal 


0 < 1.278e-03 uCi/mL 

06/18/96 eal 


06/18/96 eal 


0 < 6.930e-05 uCi/mL 

06/18/96 eal 

Ru-103 GEA Rel % Count Error 0 n/a % Ct. Error 

eal 


0 < 9.13le-04 uCi/mL 

eal 

Ru/Rh-106 GEA Rel. % Count Err 0 n/a % Ct. Error 

eal 


0 < 8.•328e-05 uCi/mL 

eal 

Se-75 GEA Rel. % Count Error 0 n/a % Ct. Error 

eal 


0 < 1.033e-04 uCi/mL 

eal 

Sn-113 GEA Rel % Counting Err 0 n/a % Ct. Error 

eal 


0 < 6.957e-05 uCi/mL 

eal 

Sr-85 GEA Rel. % Count Error 0 n/a % Ct. Error 

eat 


0 < 3.910e-03 uCi/mL 

eal 


eal 


0' < 1.781e-04 uCi/mL 

eal 

Th-229 GEA Ref % Counting Err 0 n/a % Ct. Error 

eal 


0 < 2.527e-03 uCi/mL 

eal 


eal 


0 < 8.152e=04 uCi/mL 

eal 

T1-208 GEA Rel % Counting Err 0 n/a % Ct. Error 

eal 

Uranium/Thorium-233 by GEA 0 < 4.68le-02 uCi/mL 

eal 

U/Th-233 GEA Rel % Count Err 0 n/a % Ct. Error 

eal 


0 < 7.793e-05 OCi/mL 

eal 

U-235 GEA Rel % Counting Err 0 n/a % Ct. Error 

eal 


0 < 1.484e-05 uCi/mL 

eal 

• Y-88 GEA Rel. % Count Error 0 n/a % Ct. Error 

eal 


0 < 5.770e-05 uCi/mL 

eal 

Zr/Nb-95 GEA Rel % Count. Err 0 n/a % Ct. Error 

eal 

Pag

0 


137I5 Rider Trail North 

Earth City, Missouri 63045 

314 298.8566 Telephone 

314 298.8757 Fax 


P.O. Box 1970 


July 12, 1996 










rAuanferra 

Environmental 

Se i'ti 

On June 25, 1996, two (2) liquid samples were received by Quanterra, Richland and transferred 

to Quanterra, St. Louis for chemical analysis. Upon receipt, the samples were given the 

following laboratory ID numbers to correspond with the specific client ID's: 

St Louis rD WHC ID Richland TD Matrix Date of Receipt 

11452-001 BOHX42 60632401 Liquid 6/25/96 

11452-002 BOHX43 60632402 Liquid 6/25/96 




Analyses requested: pH by EPA method 9040. TOC by EPA method 9060. VOA by EPA 

method 8240. TAL ICP Metals by EPA method 6010. Arsenic by EPA 

method 7060. Lead by EPA method 7421. Selenium by EPA method 

7740. Mercury by EPA method 7470.

a 


July 12, 1996 


SDG: W01056 

Page 2 

III. Quality Control 

Arlit 

%oa 

Environmennl 

Smicrs 


Matrix Spike and Matrix Spike Duplicate and/or Sample Duplicate analyses were performed per 

the protocol for each analyte. pH analysis uses only Sample Duplicate for matrix QC. 

IV. Definitions 

The following codes are used to denote laboratory quality control samples and can be found in 

the data summary section of this report: 



V. Comments 



samples out of holding time. Per ROD-96-0044, the samples true sampling date is 6/17/96 and 

the samples were not out of holding time. This ROD supercedes ROD-96-0035. 

General Rcp.Qrting 

The results are reported in mg/L for the TOC analysis and mg/kg or ug/kg for all other analyses 

due to sample matrix. The Density of both samples was determined to be 1.00 g/ml. This value 

can be used to convert each result to the desired units. 

Volatiles 

There are no comments or nonconformances associated with this analysis. 

l8


July 12, 1996 

Project Number: 5 19.13 6 

SDG: W01056 

Page 3 

Quanterra 

ZM, V„aMM► 

Sim= 

^' GSa1S 

The matrix spike recovery in sample 11452-001 was outside the 80-120%a limit for lead 

(137.5%) with an Relative Percent Difference for the Manix Spike/Matrix Spike Difference of 

39.4%. The associated data for lead was flagged with an "N". 

Percent solids was not determined for the samples in SDG W01056, Due to software 

configuration, the CLP forms list solid sample result uni ts as " dry weight" and % solids as " 

100 ". The results on the forms are actually mg/Kg as is and are not corrected for percent 

solids. The figure of 100 was used as percent solids for calculation purposes only and does not 

represent measured solids content of the samples. 

Wet_ hemis 

The Relative Percent Difference could not be calculated for the TOC analysis due to the.sample 

concentrations being below the detection limit. 

I certify that this data package is in compliance with the SOW, both technica lly and for 

completeness, for other than the conditions detailed above. Release of the data contained in this 

hard copy data package has been authorized by the Laborato ry Manager or a designee, as 

verified by the fo llowing signature. 


Quanterra Environmental Services, Inc. 

s:\UgdmW 31p^csSVbby'^^'s\3uNordVynu3036,xut 

^9

DATA ANALYSIS

METALS

EL 

Quenterro-Rtchland 


P.O. Box 1970 


210oanterra 

Envbvnmentaf 

Serticty 


Category: ICAP Metals - Sample Data : 06/17/96 


Receipt Date . 06/25/96 

Matrix: LIQUID Report Date 08/15/96 

Client 1 0 : 80HK42 Ouanterra ID 11452.001 

Blank Sample 

Anatyte . CAS Number Name 

Alumnus -- ---_- 7429-90-5 QCBLK105316-1 

Antimony 7440-36-0 OCOLK105316-1 

Barium 7440-39-3 QCBLK105316-1 

Beryllium 7440-41-7 QCBLK105316-1 

Cadmitm 7440-43.9 OCOLK105316-1 

Calcium 7440-70.2 QCBLK105316-1 

Chromium 7440-47-3 OCBLK105316-1 

Cobalt 7440-48-4 QCBLK105316-1 

Copper 7140-50.8 QCBLK105316-1 

Iron 7439-89-6 OCBLK105316-1 

Magnesium 7439-95.4 OCBLK105316.1 

Manganese 7439-96-5 GCBLK105316-1 

Mickel 7440-02.0 OCOLKI05316-1 

Potassium 7440-09.7 OCOLK105316-1 

Silver 7440-Z2-4 OCBLK105316-1 

Sodium 7440-23-5 OCOLK105316-1 

Vanadium 7440.62-2 QCBLX105316-1 

Zinc 7440.66.6 QCSLK105316.1 


Date Date Result Unit Oust. Limit Dilution 

27/96 06/27/96 5.3 MG/KG U 20.0 1 

27/96 06/27/96 3.5 MG/KG U 6.0 1 

27/96 06/27/96 0.21 MG/KG 8 20.0 1 

27/96 06/27196 0.05 MG/KG U 0.50 1 

27/96 06/27/96 0.24 MG/KG U 0.50 1 

27/96' 06/27/96 185 MG/KG B 500 1 

27/96 06/27/96 0.41 MG/KG U 1.0 1 

27/96 06/27/96 0.48 MG/KG U 5.0 1 

27/96 06/27/96 0.56 MG/KG U 2.5 1 

27/96 06/27/96 2.6 MG/KG B 10.0 1 

27/96 06/27/96 20.9 MG/KG 8 500 1 

27196 06/27/96 0.12 MG/KG U 1.S 1 

27/96 06/27/96 0.91 MG/KG U 4.0 1 

27/96 06/27/96 182 MG/KG U 500 1 

27/96 06/27/96 0.59 MG/KG U 1.0 1 

27/96 06/27/96 13.4 MG/KG B 500 1 

27/96 06/27/96 0.57 MG/KG U 5.0 1 

27/96 06/27/96 0.65 MG/KG U 2.0 1 

- a^

Category: 

Method: 

Matrix: 

client ID: 

ICAP Metals 

EPA 6010 

LIQUID 

808X42 

ouanterra-Richland 


P.O. Box 1970 



- 

- 

uanterra 

Farimnmenral 

'ors 

I Semple Date : 06/17/96 



ouenterra ID : 11452-OOIMS 


Analyte CAS Number Name Date Date Result Unit Oual. Limit Dilution 

Aluminum 7429-90-5 QCBLK105316-1 06/27196 06/27/96 %REC i 

Antimony 7440-36.0 QCBLK105316 . 1 06/27/96 06/27/96 102 %REC 1 

Barium 7440-39.3 QCBLK105316-1 06/27/96 06127196 98 %REC 1 

Beryltium 7440.41-7 QCBLK105316-1 06/27/96 06/27/96 103 %REC 1 

Cadmium 7440.43-9 QCBLK105316-1 06/27/96 06/27/96 102 %REC 1 

Chromium 7440-47.3 QCBLK105316-1 06/27/96 06/27/96 98 %REC 1 


Copper 7440-50.8 QCBLK105316-1 06/27/96 06/27/96 102 %REC 

1 

Iron 7439-89-6 QCBLK105316-1 06/27/96 06/27/96 100 %REC - 

1 

Manganese 7439.96.5 QCBLK105316 . 1 06/27196 06/27/96 97 %REC 1 


Silver 7440-22-4 OCOLK105316-1 06/27/96 06/27/96 93 %REC 1 

Vanadium 7440-62.2 QCBLK105316-1 06/27/96 06/27/96 96 %REC 1 

Zinc 7440.66-6 OCBLK105316-1 06/27/96 06/27/96 102 %REC 1

k 




Client 10: BOHX42 

Anatyte 

CAS Number 

Blank Sample 

Name 

Ouanterra-Richland 


P.O. Box 1970 

Richland, W 99352 


Prep. 

Date 

Analyses 

Date Result Unit 

,iivanterra 

£n,ironmrmal 

Semces 

Semple Date : 06/17196 



Ouanterra 10 : 11452-OOlMSD 

Detection 

Oual. Limit Dilution 

Aluminum 7429-90-5 QCBLK105 16-1 06/2 /96 06/27/96 99 %REC 1 

Antimony 7440-36-0 QCBLK105316 . 1 06/27/96 06/27/96 103 %REC 1 

Barium 7440-39.3 OCBLK105316-1 06/27/96 06/27196 97 %REC 1 

Beryllium 7440-41-7 QCBLK105316-1 06/27/96 06/27/96 101 %REC 1 

Cadmium 7440-43.9 QCBLK105316 . 1 06/27196 06/27/96 100 %REC 1 

Chromium 7440-47.3 QCBLK105316-1 06/27/96 06/27/96 96 %REC 1 


Copper 7440-50-8 QCBLK105316-1 06/27/96 06/27/96 102 %REC 1 

Iron 7439-89-6 QCBLK105316-1 06/27/96 06/27/96 99 %REC 1 

Manganese 7439-96.5 QCBLK105316 . 1 06/27/96 06/27/96 97 %REC 1 


Silver 7440-22.4 QCBLK105316 . 1 06/27196 06/27/96 94 %REC 1 

Vanadium 7440-62.2 QCBLK105316-1 06/27/96 06/27/96 96 %REC 1 

Zinc 7440-66-6 QCBLK105316 . 1 06/27/96 06/27196 102 %REC 1

^%ivanterra 

Emironmenra/ 

Quanterra-Richland Services 


P.O. Box 1970, 



Category : ICAP Metals Sample Date : 06/17/96 



Matrix: -LIQUID Report Date : 08/15/96 

Client ID: BOHX43 .. Quenterre ID : 11452-002 


Anelyte CAS Number Name Date Date Result Unit Qual. Limit Dilution 

Alumiraam 7429-90-5 QCBLK105316-1 06/27/96 06/27/96 5.3 MG/KG U 20.0 1 

Antimony 7440-36-0 QCBLK105316-1 06/27/96 06/27/96 3.5 MG/KG U 6.0 1 

sariva 7440-39-3 QCBLK105316 . 1 06/27/96 06127/96 0.44 MG/KG B 20.0 1 

Beryllium 7440-41-7 QCBLX105316-1 06/27/96 06/27/96 0.05 MG/KG U 0.50 1 

Cadniva 7440-43.9 QCBLK105316-1 06/27/96 06/27/96 0.24 MG/KG U 0.50 1 

Calcium 7440-70.2 QCBLK105316-1 06/27196 06/27/96 602 MG/KG 500 1 

Chromium 7440-47.3 QCBLK105316-1 06/27/96 06/27/96 0.70 MG/KG B 1.0 1 

Cobalt 7440-48-4 QCBLK105316-1 06/27/96 06/27/96 0.48 MG/KG U 5.0 1 

Copper 7440-50.8 QCBLK105316-1 06/27/96 06/27/96 2.5 MG/KG 2.5 1 

Iran 7439-89-6 QCBLK105316-1 06/27/96 06/27/96 20.7 MG/KG 10.0 1 

Magnesium 7439.95-4 QCBLK105316-1 06/27/96 06/27/96 42.2 MG/KG B Soo i 

Manganese 7439-96-5 QCBLK105316-1 06/27/96 06/27/96 0.68 MG/KG B 1.5 1 

Nickel 7440-02-0 OCOLK105316-1 06/27/96 06/27/96 1.1 MG/KG B 4.0 1 

Potassium 7440-09.7 OCOLK105316-1 06/27/96 06/27/96 182 MG/KG U 500 1 

Silver 7440-22-4 QCBLK105316-1 06/27/96 06/27/96 0.59 MG/KG U 1.0 1 

Sodium 7440-23-5 QCBLK105316-1 06/27/96 06/27/96 2490 MG/KG 500 1 

Vanadium 7440-62-2 QCBLK105316-1 06/27/96 06/27/96 0.57 MG/KG U 5.0 1 

Zinc 7440-66-6 QCBLX105316-1 06/27/96 06/27/96 1.9 MG/KG B 2.0 1 

o5 .




Client 10: NA 


Blank Sample 

Name 



P.O. Box 1970 

Richland, UA 99352 


Prep. 

Date 

Analyses 

Date 

Aluminum 7429-90-5 OCSLK10 316-1 06/27/96 06/27/96 

Antimony 7440-36-0 OCOLK105316-1 06/27/96 06/27/96 

Barium 7440-39-3 QCSLK105316-1 06/27/96 06/27/96 

Beryllium 7440.41-7 QCBLK105316-1 06/27/96 06/27/96 

Cadniva 7440-43-9 QCBLX105316-1 06/27/96 06/27/96 

Calcium 7440-70-2 QCBLK105316-1 06/27/96 06/27/96 

Chromium 7440-47-3 QCBLK105316-1 06/27/96 06/27/96 

Cobalt 7440-48-4 QCBLK105316-1 06/27/96 06/27/96 

Copper 7440.50-8 QCBLK105316-1 06/27/96 06/27/96 

Iron 7439-89-6 QCDLK105316-1 06/27/96 06/27/96 

Magnesium 7439-95-4 OCBLK105316-1 06/27/96 06/27/96 

Manganese 7439.96.5 OCOLK105316-1 06/27/96 06/27/96 

Nickel 7440-02.0 QCSLK105316 . 1 06/27/96 06/27/96 

Potassium 7440-09.7 QCBLK105316-1 06/27/96 06/27/96 

Silver 7440-22-4 OCBLK105316-1 06/27/96 06/27/96 

Sodium 7440.23-5 OCOLK105316-1 06/27/96 06/27/96 

Vanadium 7440-62-2 OCOLK105316-1 06/27196 06/27/96 

Zinc 7440-66-6 QCBLK105316-1 06/27/96 06/27/96 

riivanterra 

Envkonmenra/ 

Services 

Sample Date t NA 

Receipt Data : MA 



Detection 

Result Unit Qual. Limit - Dilution 

3.5 MG/KG U 

-0.13 MG/XG B 

0.05 NG/KG U 

0.24 MG/KG U 

2.1 MG/KG U 

0.41 MG/KG U 

0.48 MG/KG U 

0.56 MG/KG U 

2.4 MG/KG B 

-14.8 MG/KG it 

0.12 MG/KG U 

0.91 MG/KG U 

182 MG/KG U 

0.59 MG/KG U 

-11.4 MG/KG B 

-0.87 MG/KG B 

0.65 MG/KG U 

0.50 1 

0.50 1 

500 1 

1.0 1 

5.0 1 

2.5 1 

10.0 1 

500 1 

1.5 1 

4.0 1 

S00 1 

1.0 1 

S00 1 

5.0 1 

2.0 1 

a?6.

.i 

q 




Client ID: NA 



P.O. Box 1970 



i banterra 

S711MDo2Wra1 

Services 

Sample Data NA 

Receipt Date : MA 


Quanterra ID : QCLCSIOS316-1 

Blank Sartple Prep. Analyses Detection 

Analyte CAS Number Name Date Date Result Unit Ouat. Limit Dilution 

Aluminum 7429-90-5 OCBLK105 16 . 1 06/27/96 06/21/96 76 XREC 1 

1 

Antimony 7440-36-0 OCBLX105316 . 1 06/27/96 06/27/96 128 %REC 

Barium 7440-39-3 QCSLK105316-1 06/27/96 06/27/96 93 %REC 1 

Beryllium 7440-41-7 QCBLK105316 . 1 06/27/96 06/27/96 96 %REC 1 

Cadmium 7440-43-9 QCBLK105316-1 06/27/96 06/27/96 98 XREC 1 

Calcium 7440-70-2 QCBLK105316-1 06/27/96 06/27/96 103 %REC 

1 

Chromium 7440.47-3 QCBLK105316-1 06/27/96 06/27/96 95 %REC i 

Cobalt 7440-48-4 QCBLK105316-1 06/27/96 06/27/96 98 %REC 1 

Copper 7440-50-8 QCSLK105316-1 06127/96 06127/96 96 %REC i 

Iron 7439-89-6 QCBLK105316-1 06/27/96 06/27/96 92 %REC 1 

Magnesium 7439-95-4 QCBLK105316-1 06/27/96 06/27/96 93 %REC 1 

Manganese 7439-96.5 QCBLK105316-1 06/27/96 06/27/96 95 %REC 1 

Nickel 7440-02-0 OCOLK105316-1 06/27/96 06/27/96 97 %REC 1 

Potassium 7440-09-7 QCBLK105316 . 1 06/27/96 06/27/96 94 %REC 1 

Silver 7440-22-4 QCBLK105316-1 06/27/96 06/27/96 106 %REC 

Sodium 7440-23-5 OCOLK105316 . 1 06/27/96 06/27/96 97 %REC 1 

Vanadium 7440-62-2 GCBLK105316-1 06/27/96 06/27/96 91 %REC 1 

Zinc 7440-66-6 OCBLK105316 . 1 06/27/96 06/27/96 98 %REC 1 

a

s 

firAuanterra 

EalfronnwB 


di 

Vestirghouse Hanford Company 

P.O. Box 1970: 

Richland, VA 99352 


Category: Arsenic Sample Date 06/17/96 



Receipt Date : 06/25196 

Report Date . 08/15/96 

Client Ouanterra Blank Sampte Prep. Analyses Detection 

ID ID Analyte CAS Nueber Name Date Date Result Unit Oust. Limit Dit. 

BOHR42 11452-001 Arsenic 7440-39-2 QCBLKI -1 06/27/96 6/ / b 0.11MG/KG U i.0 1 

BDHX42 11452.00lMS Arsenic 7440-38-2 QCBLK105321-1 G6/27/96 06/28/96 92 %REC i 

BOHX42 - 11452-OOlMSD Arsenic 7440-38-2 QCBLK105321-1 06/27/96 06/28/96 97 %REC 1 

BOHX43 11452-002 Arsenic 7440-38-2 QCBLK105321-1 06/27/96 06/28196 0.11 MG/KG U 1.0 1 

NA QCLCS105321-1 Arsenic 7440-38-2 QCBLK105321-1 06/27/96 06/28/96 105 %REC 20 

NA OCBLK105321-1 Arsenic 7440-38-2 QCBLK105321-1 06/27/96 06/28/96 0.11 MG/KG U 1.0 1 

i

106anterra 

Envlronmrmal 

ouanterra • Richland Services 

Vestinghouse Hanford Company 

P.O. Box 1970 

Richland, W 99352 

Category: Lead 



Proi Kt7 

519.136 

Semple Date 06/17/96 


Report Data : 08/15/96 

Client Ouanterra Blank Saapla Prep. Analysts Detection 

10 10 Analyte CAS Number Name Date Date Result Unit Oust. Limit Dil. 

B NX4 Lead 7439-92-1 OCBLKI / 7/96 06/ / b 0.16 MG/KG BN o.30 1 

BOHX42 111452-00IMS Lead 7439.92-1 QCBLK105321 . 1 06/27/96 06/27196 138 %REC N i 

BOHX42 11452-OOINSD Lead 7439-92-1 QCBLK105321-1 06127/96 06/27/96 92 %REC 1 

BOHX43 11452-002 Lead 7439-92-1 OCOLK105321-1 06/27/96 06/27/96 2.9 MG/KG H 0.30 1 

NA QCLCS105321-1 Lead 7439-92.1 QCBLK105321-1 06/27/96 06/27196 103 %REC 10 

NA QCBLK105321-1 Lead 7439-92-1 QCBLK105321-1 06127/96 06/27/96 0.12 MG/KG U 0.30 1

Category: Selenium 

Method: EPA 7000 Series 




P.O. Box 1970 


Project: 519.136 , 

>riiaanterra 

Environmental 

Services 


Receipt Data : 06/25/96 


Ctient Ouanterrs Blank Sample Prep. Analyses Detection 

ID ID Analyts CAS Nurber Nerve Date Date r . Result Unit Oual. Limit Dil. 

BOHX42 il452- 001 Selenium T782-49-2 OCBLK7 1-1 06/27/96 06/28/96 .1 MG/KG U 

BOHX42 11452-OOIKS Selenium 7782-49-2 GCBLK105321-1 06/27/96 06/28/96 109 %REC 1 

BOHX42 1 452-001MSD Selenium 7782-49-2 QCBLK105321 . 1 06/27/96 06/28/96 100 %REC 1 

BDHX43 11452-002 Selenium 7782-49-2 QCBLK105321-1^ 06/27/96 06/28/96 0.13 MG/KG U 0.50 1 

NA OCLCS105321-1 Setentum 7782-49.2 OCOLK105321-1 06/27/96 06/28/96 95 XREC 20 

NA OCBLK105321-1 Selenium 7782-49-2 QCBLK105321-1 06/27196 06/28/96 0.13 MG/KG U 0.50 1 

0 

C.:. 30 .

I 




iiivanferra 

Eminonmenral 

Quanterra-Richtand Services 

Westinghouse Hanford Cortpany 

P.O. Box 1970 



Sample Data 06/17/96 



Ctient Quanterra Stank Semple Prep. Analyses Detection 

.ID ID Analyte CAS Number Name Date Date Result Unit gust. Limit Dil. 

BOHX42 11452-001 Mercury 7439-97-6 QCSLXI -1 / / / 8/96 0.05 MG/KG U 0.20 1 

BOHX42 11452.00IMS Mercury 7439-97.6 QCBLK105509-1 06/28/96 06/28196 93 XREC 1 

BOHX42 11452-OOINSD Mercury 7439.97.6 OCOLK105509 . 1 06/28/96 06/28/96 96 %REC 1 

BONX43 11452.002 Mercury 7439-97-6 QCBLK105509-1 06/28/96 06/28/96 0.05 MG/KG U 0.20 1 

NA OCLCS105509-1 Mercury 7439.97-6 OCOLK105509-1 06128/96 06128/96 100 %REC 1 

NA QCBLK105509-1 Mercury 7439.97-6 OCBLK105509-1 06/28/96 06128/96 0.05 MG/KG U 0.20 1 

31

WET CHEMISTRY

a 

s; 

Category: pH 



Quanterro-Richland 


P.O. Box 1970 



Qiivanterra 

Environmental 

Senicm 


Receipt ,Date : 06/25196 



IO ID Analyte CAS Nurber Name Date Date Result Unit Dual. Limit Dil. 

BOHX42 11452-001 pH PH QCBLKI 4 -1 06/27/96 06/ / PH 0.10 1 

BOHX42 11452-OOIDUP PH PH QCBLK105343-1 06/27/96 06/27/96 6.53 PH 0.10 1 

80HX43 11452-002 PH PH QCBLK105343-1 06/27196 06/27/96 11.30 PH 0.10 1 

NA QCBLK105343-1 PH PH QCBLX105343.1 06/27/96 06/27/96 5.50 PH 0.10 1


Westinghouse Hanford Cortpany 

P.O. Box 1970 


îivanterra 

Emironmmnl 

Services 

Project- . S19.136 

Category : Total Organic Carbon Sample Date : 06/17/96 

Method: EPA 9060 Receipt Date : 06/2S/96 

Matrix: LI QU ID Report Date : 08/15/96 

Client Duanterra Blank Sample Prep. Analyses Detection 

ID 10 Anslyte CAS Nur6er Nam Na Data Date Result Unit Oual. Limit Dil. 

e HX4 2 114S2-001 Total Organic C TOC OCSLKI -1 06/27/96 06/27/96 MG/L U 1.00 

BOHX42 11452-0010UP Total Organic C TOC QCBLK105350-1 06/27/96 06/27/96 1.00 MG/L U 1.00 1 

BOHX42 11452-OOIMS Total Organic C TOC QCBLK105350-1 06/27/96 06/27/96 98 %REC 1 

i 

BOHX43 11452-002 Total Organic C TOC 

OCBLK105350-1 06/27/96 06/27/96 48.9 MG/L 1.00 1 

NA QCBLK105350-1 Total Organic C TOC QCBLK105350-1 06/27/96 06/27/96 1.00 MG/L U 1.00 1 

NA DCLCS105350=1 Total Organic C TOC QCSLK105350-1 06/27/96 06/27/96 98 %REC 1 

SW 

3^

VOLATILE ORGANICS





Blank Sample 

Analyte CAS Number Name 

chloremethane 74-87-3 QCBLK105677.1 

Bromomethane 74.83-9 OCBLK105677-1 

Vinyl Chloride 75-01.4 OCOLK105677-1 

Chloroethane 75-00.3 QCBLK105677-1 

Methylene Chloride 75-09-2 OCOLK105677-1 

Acetone 67-64.1 OCOLK105677.1 

Carbon Disulfide 75-15-0 QCBLK105677.1 

1,1-Dichtoroethene 75-35-4 OCOLK105677-1 

1,1-Dichloroethane 75-34-3 QCSLK105677-1 

1,2-Dichloroethene (total) 540.59-0 QCBLK105677-1 

Chloroform 67.66-3 QCBLK105677-1 

1,2-Dichloroethane 107-06-2 QCBLK105677-1 

2-Butanone (MEK) 78-93-3 OCBLK105677.1 

1,1,1-Trichloroethane 71-55-6 QCBLK105677-1 

Carbon Tetrachloride 56-23-5 QCBLK105677.1 

Bromodichloromethane 75-27-4 OCOLK105677.1 

i t 2-Diehloropropane 78-87-5 QCBLK105677-1 

ets-1,3-Dichloropropene 10061-01-5 QCBLK105677-1 

Trichloroethane 79-01.6 OCOLK105677-1 

Dibromochloromethane 124.48.1 OCBLK105677-1 

1,1,2-Trichloroethane 79-00.5 QCBLK105677-1 

Benzene 71-43-2 QCBLK105677.1 

` trans-1,3-Dichloropropene 10061-02-6 QCBLK105677-1 

f- Bromoform 75.25.2 QCSLK105677-1 

-. 4-Methyt-2-Pentanone (MIRK) 108-10-1 QCBLK105677.1 

• 2-Hexanone 591-78-6 OCELK105677-1 

Tetrachtoroethene 127-18-4 QCBLK105677-1 

1,1,2,2-Tatrachloroethane 79-34.5 QCBLX105677-1 

? Toluene 108.88-3 QCBLK105677-1 

Chlorobenzene 108-90-7 QCBLX105677-1 

EthylBenzene 100.41-4 QCBLK105677-1 

Styrene 100.42-S QCBLK105677.1 

Xylene (total) 1330-20-7 QCSLK105677-1 

Toluene-d8 (SURR) 2037-26.5 OCELK105677-1 

Bromoftuorobenzene (SURR) 460-00.4 OCBLK105677-1 

1,2-Dichloroethane-d4 (SURR) 17070-07-0 QCBLK105677.1 



P.O. Box 1970 

Richland, UA 99352 


Prep. Analyses 

Date Date 

/96 

QPuanterrra 

Environmenral 

Senfces 

Sample Data : 06/17/96 



Ouanterra ID : 11452-001 

Detection 

Result Unit Oual. Limit Dilution 

10 UG/KG U 10 

10 UG/KG U 10 

10 UG/KG U 10 

5 UG/KG U 5 

20 UG/KG U 20 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

20 UG/KG U 20 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U S 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U S 

20 UG/KG U 20 

20 UG/KG U 20 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U 5 

5 UG/KG U S 

5 UG/KG U 5 

5 UG/KG U S 

S UG/KG U 5 

103 XREC 

101 XREC 

114 XREC

Qiivanterra 

Eavironmmm/ 

• Ouanterra-Richland 


P.O. Box 1970. 

Rtchlend, WA 99352 


Category : Votatiles Supte Date : 06/17/96 

Method: EPA 8240 Receipt Data : 06/25/96 

Matrix: LIOUID Report Date : 08/15/96 

Ctient ID: BOR%42 Ouanterre iD : 11452.00lMS 


AnaLyte CAS Number Name Date Date Result Unit Oust. Limit Dilution 

1,1-D:chloroethere -4 QCBLK10 6 -1 07/01/96 0 /01/96 1 %REC 1 

Trichloroethene 79-01-6 QCBLK105677-1 07/01/96 07/01/96 106 %REC 1 

Benzene 71-43-2 QCBLK105677-1 07/01/96 07/01/96 112 %REC 1 

Toluene 108.68-3 QCBLK105677-1 07/01/96 07/01/96 102 %REC 1 

Chtorobenzene 106-90-7 OCBLK105677 . 1 07/01/96 07/01/96 98 %REC 1 

Totuene-d8 (SURR) 2037-26-5 OCBLK105677-1 07/01/96 07/01/96 104 %REC 1 

Bromofluorobenzene (SURR) 460-00-4 OCBLK105677-1 07/01/96 07/01/96 98 %REC 1 

1,2-Dichloroethane-d4 (SURR) 17070-07-0 OCBLK10S677-1 07/01/96 07/01/96 113 %REC 1 

35^




Client ID: BOHx42 

Ouenterra-Richland 


P.O. Box 1970 



.r/ uanterra 

Bnvbro meonl 

Services 

Semple Date : 06/17/96 


Report Data : 08/15/96 

Quanterra ID : 11452-OOlMSD 

Blank Sample Prep. Analyses . Detection 

Analyte CAS Number Name Date Date Result Unit Qual. Limit Dilution 

"'I ehloroethene -35-4 QCBLKI 5 -1 07/01/96 07/01/96 1 %REC 1 

Trichloroethene 79-01.6 QCBLK105677-1 07/01/96 07/01/96 104 %REC 1 

Benzene 71-43.2 QCBLX105677-1 07/01/96 07/01/96 112 %REC i 

Toluene 108.88-3 QCBLK105677-1 07/01/96 07/01/96 105 %REC 1 

Chlorobenzene 108-90-7 QCBLK105677-1 07/01/96 07/01/96 98 %REC 1 

Toluene-d8 (BURR) 2037.26.5 GCBLK105677 . 1 07/01/96 07/01/96 105 %REC 1 

Bromofluorobenzene (BURR) 460.00.4 QCBLK105677-1 07/01/96 07/01/96 100 %REC 1 

1,2-Dichloroethane-d4 (SURR) 17070-07-0 QCBLK105677-1 07/01/96 07/01/96 114 %REC 1

I 


Vestinghouse Hanford Company 

P.O. Box 1970 

Richland, VA 99352 

^%ivanterra 

Emfrunmental 

S `lm 


Category: Volatiles Sample Date : 06/17/96 

Method: EPA 8240 Receipt Date : 06/25/96 

Matrix: LIQUID Report Dote 08/15/96 

Client ID: BOHX43 Quanterra 1D 11452.002 

Stam Sample Prep. Analyses Detection 

Analyte CAS Nurber Name Date Date Result Unit Ouat. Limit Dilution 

Chloromethane 74.87-3 QCBLX10 6 -1 07/01/96 07/01/96 10 UG/KG U 10 1 

Bromomethane 74-83-9 OCOLK105677.1 07101/96 07/01/96 10 UG/KG U 10 1 

Vinyl Chloride 75-01-4 OCOLK105677-1 07/01/96 07/01/96 10 UG/KG U 10 1 

Chloroethane 75-00-3 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG U 10 1 

Methylene Chloride 75-09-2 QCBLK105677.1 07/01/96 07/01/96 5 UG/KG U S 1 

Acetone 67-64-1 QCBLK105677-1 07/01/96 07/01/96 49 UG/KG 20 1 

Carbon Disulfide 75-15-0 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,1-Dichloroethene 75-35-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,1-Dichtoroethane 75-34.3 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,2-Dichloroethene (total) 540-59.0 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Chloroform 67-66-3 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,2-Dichtoroethane 107-06.2 OCOLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

2-Butanone (MEK) 78.93-3 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG U 20 1 

1,1,1-Trichtoroethane 71-55.6 QCBLKlOS677.1 07/01/96 07/01/96 5 UG/KG U 5 1 

Carbon Tetrachloride 56-23.5 OCOLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Bromodichtoromethene 7S-27-4 GCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,2-Dichloropropane 78.87-5 QCBLK105677.1 07101/96 07/01/96 5 UG/KG U 5 1 

cis-1,3-Dichloropropene 10061.01.5 OCOLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Trichlorcethen* 79-01.6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Dibromochloromethane 124-48-1 QCBLKIOS677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,1,2-Trichloroethane 79.00-5 OCOLK105677.1 07/01/96 07/01/96 5 UG/KG U 5 1 

Benzene 71-43-2 QCBLK105677.1 07/01/96 07/01/96 5 UG/KG U 5 1 

trans- 1 ,3-Dichtoropropene 10061.02-6 QCBLX105677. 1 07/01/96 07/01/96 5 UG/KG U 5 1 

Bromoform 75.25.2 QCBLKIOS677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

4-Methyl-2-Pentanone (MIRK) 108-10-1 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG U 20 1 

2-Hexanone 591-78.6 QCBLK105677. 1 07/01/96 07/01/96 20 UG/KG U 20 1 

Tetrachloroethene 127-18-4 OCBLKI05677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,1,2,2-Tetrachloroethene 79-34-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Toluene 108.88-3 QCBLK105677. 1 07/01/96 07/01/96 5 UG/KG U 5 1 

Chlorobenzene 108-90-7 QCSLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

EthylBenzene 100-41-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Styrene 100-42-5 GCBLK105677 . 1 07/01/96 07/01/96 5 UG/KG U 5 1 

Xytene (total) 1330-20-7 OCBLK105677-1 07/01/96 07101/96 5 UG/KG U S 1 

Unknown TIC-2 QCBLK105677-1 07/01/96 07/01/96 25 UG/KG J 1 

Toluene-d8 (BURR) 2037-26.5 QCBLK1056TT-1 07/01/96 07/01/96 102 %REC 1 

Bromofluorobenzene (SURR) 460-00-4 QCBLK105677-1 07/01/96 07/01/96 100 %REC 1 

1,2-Dichloroethene-d4 (SURR) 17070-07-0 QCBLK105677-1 07/01/96 07/01/96 111 %REC 1

s 



Matrix: LIGUID 

Client ID: MA 


Blank Searle 

Rome 



P.O. Box 1970 



Prep. 

Data 

Analyses 

Date Result Unit Oual. 

rAuanterra 

Emironmenta/ 

Services 

Semple Date : RA 

Receipt Date : MA 


Guanterra ID : QCBLK105677.1 

Detection 


Ch oromethane 74-87-3 QCBLK1056TT-1 07/01/96 0 /01/96 10 UG/KG U 10 1 

Bromomethana 74.83-9 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG U 10 1 

Vinyl Chloride 75-01-4 QCBLK105677-1 07101/96 07/01/96 10 UG/KG U 10 1 

Chloroethane 75-00.3 QCBLK105677-1 07/01/96 07/01/96 10 UG/KG U 10 1 

Methylene Chloride 75-09-2 QCBLX105677.1 07/01/96 07/01/96 5 UG/KG U 5 1 

Acetone 67-64.1 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG U 20 1 

Carbon Disulfide 75.15-0 QCBLX105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,1-Dichloroethene 75-35-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,1-Dichloroethane 75-34-3 GCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,2-Dichloroethena (total) 540-59-0 GCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Chloroform 67-66-3 QCBLX105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,2-Dichloroethane 107-06-2 QCBLK105677. 1 07/01/96 07/01/96 5 UG/KG U 5 1 

2-Butanone (MEK) 78-93-3 QCBLK105677-1 07/01/96 07/01/96 20 UG/KG U 20 1 

1,1,1-Trichloroethane 71-55-6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Carbon Tetrachloride 56-23-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Bromodichloromethane 75-27-4 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,2-Dichloropropane 78.87.5 GCBLK105677-1 07101/96 07/01/96 5 UG/KG U 5 1 

cis-1,3-Dichloropropene 10061-01-5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Trichloroethene 79-01-6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Dibromochloromethane 

1,1,2-Trichloroethane 

Benzene 

124-48-1 

79-00-5 

71-434 

QCBLK105677-1 

QCBLK105677-1 

QCBLK105677-1 

07/01/96 

07/01/96 

07/01/96 

07101/96 

07/01/96 

07/01/96 

5 

5 

5 

UG/KG 

UG/KG 

UG/KG 

U 

U 

U 

5 

5 

5 

1 

1 

1 

trans-1,3-Dichloropropene 10061-02-6 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Srcmoform 75-25-2 OCBLK105677.1 07/01/96 07/01/96 5 UG/KG U 5 1 

4-Methyl-2-Pentanone (MIBK) 108 . 10-1 OCOLK105677-1 07/01/96 07/01/96 20- UG/KG U 20 1 

2-Hexanone 591-78-6 QCBLK105677 . 1 07/01/96 07/01/96 20 UG/KG U 20 1 

Tetrachloroethene 127-18-4 OCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

1,1,2,2-Tetrach Loroethane 79-34.5 OCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Toluene 108.88-3 OCOLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Chlorobenzene 108-90-7 OCOLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

EthyiDenzene 100.41.4 GCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Styrene 100-42.5 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

XyLena (total) 1330-20-7 QCBLK105677-1 07/01/96 07/01/96 5 UG/KG U 5 1 

Toluene-d8 (BURR) 2037-26-5 QCBLK105677-1 07/01/96 07101/96 102 %REC 1 

Bromofluorobenzene (BURR) 460-00-4 QCBLK105677-1 07/01/96 07/01/96 99 %REC 1 

1,2-Dichloroethane-d4 (BURR) 17070-07-0 GCBLK105677-1 07/01/96 07/01/96 106 %REC 1

Quanterra 

Emironmenral 

Ouanterra-Richtand Senias 


P.O. Box 1970 


Project: $19.136 

Category: Yolatiles Sample Date:NA 

Method: EPA 8240 Receipt Date : NA 

Matrix: LIQUID Report Date : OB/1/96 

Client 10: NA Ouenterra 1D : OCLCS105677.1 

Blank Sample 

Analyte CAS Number Name 

1,1-D chlorocthene -35-4 aC8LK10 6 -1 

Triehloroethene 79-01-6 QCBLK105677-1 

Benzene 71-43-2 QCBLX105677-1 

Toluene 108-88-3 QCBLK105677-1 

Chlorobenzene 108-90-7 OCOLK105677.1 

Toluene-d8 (SURR) 2037-26-5 QCBLK105677.1 

Bromofluorobenzene (SURR) 460-00-4 QCBLK105677-1 

1,2-Dichloroethane-d4 (SURR) 17070-07-0 QCBLK105677-1 


Data Date Result Unit Quist. Limit Dilution 

01/ 07/01/96 14 %REC 1 

01/96 07/01/96 103 %REC 1 

01/96 07/01/96 110 %REC 1 

01/96 07/01/96 102 %REC 1 

01/96 07/01/96 96 %REC 1 

01/96 07/01/96 104 %REC 1 

01/96 07/01/96 100 %REC t 

01/96 07/01/96 114 %REC 1




ROD-96-0039 


PROJECT TITLEISAF #: PURER Vessels' Flush Solutions/96-016 NCR NO.: N/A 






within the three business day priority data turnaround requirement. 


Quanterra can run 


S M Steele ^s2,. July 16 1996 

SDLA Project Coo a'tor - cprinc/sign maw) 3 Date 

C.N.Villalobos 

Technical Representa tive (print/sign Name) Date 

#;I-

09/03/96 14:19 

Quantena Incorporated 

13715 Rider Trail No rth 

Ea rt h City, ,Wirlau rt 63045 

314 298.8566 Telephone 

314 298.8757 Fos 

♦ $. r 11 " 4" 01 01 


P.O. Box 1970 


August 30, 1996 


f;030J 

VUAP%I ERILA RA ++• RICHL-.'^D 

OUJ: UJO 



Date Received by Lab Jane 25, 1996 






i 

â w J 'i 1 ^ L/ , 3 tJ f 

" an terra 

Eni,anr..rnul 

services 

On June 25, I996, two (2) liquid samples were received by Quanterra, Richland and transferred to 

Quanrerra, St. Louis for chemical analysis. On July 16, 1996, additional Mercury analyses were 

requested on these samples. Upon receipr, the samples were given the fo ll 

owing laboratory ID 

numbers to correspond with the specific client ID's: 

St Louis Q WHC ID Richland ID TALC Date of Receipt 

11452-001 BQHX42 60632401 Liquid 6125196 

11452-002 BOHX43 60632402 Liquid 6!25/96 

The results of the original analyses can be found with SDG W01056. This report er,nWns only the 

results for the Mercury reanalysis. 


The analytical results for this report are pi esented by analytical test. Each set of data includes 

sample identification informa tion, analy tical results and the approp riate detection limits. 

Analyses requested: Mercury by EPA method 7470. 

1{3

09uotoutso tio' 9 t a",)L4 3721546 

ot VU.i^rl;l

09/03/96 14:20 V509 3721546 

5 

08/30/96 16:41 '5314 298 8757 QUAYMRRA »»» RICHLAND to 0057030 


August 30, 1996 

Project Number. 519.136 

SDG: W01075 

Page 3 

^t A ^ ^ i^^ U ^,, J ^ s 

Quanitrra 

Ear"Aawrd 

S"'im 

I cer tify that this data package is in compliance with the SOW, both technica lly and for 

completeness, for other than the conditions deta iled above. Release of the data contained in 

this hard copy data package has been authorized by the Laborato ry Manager or a designec, as 

verified by the following signature. 

.ed a ri ndapproved: 

H. P 

ce 

J 


Quanterm Fmvirc=crital Services. Inc. 

e:%14qdMaO1%p ricc4Pabbyda e\hufvTd\h n 191s. ti



Matrix: LIOUID 



P.O. Box 1970 



,iiaanterra 

Environinmul 

Serw'^ 

Sampl• Date 06/17/96 



Client Ouanterra Blank Semple Prep. Analyses Detection 

ID ID Analyte CAS Nudxr Name Date Date Result Unit Owl. Limit Dil. 

BOKX42 11 Mercury 7439-97-6 DCBLK 07/17/96 07117/96 UG/L U 

BOHX42 11452-OOlMS Mercury 7439-974 QCBLK106918-1 - 071 17/96 07/17/96 106 %REC i 

BOHX42 11452-OOIMSD Mercury 7439-97-6 QCBLK106918-1 07/17/96 07/17/96 107 XREC 1 

BOKX43 11452-002 Mercury 7439-97-6 QCBLK106918-1 07/17/96 07/17/96 4.1 UG/L 0.20 1 

NA OCLCS106918.1 Mercury 7439-97-6 QCBLK106918 . 1 07/17/96 07/17/96 110 XREC 1 

NA QCBLK106918-1 Mercury 7439-97-6 QCBLK106915-1 07/17/96 07/17/96 0.10 UG/L U 0.20 1 

1 

JAP

- WESTINGHOUSE HANFORD COMPANY 

GENERATOR & WASTE ACCEPTANCE SERVICES 

Page ^ of ^ 

PREDETERMINATION REPORT - , .... .. . 

REQUEST #: 28230 DATE: Aupust 7 1996 

SUBJECT; I PRODUCT PREDETERM NATION 

TO C armen Villalobos COMPANY WHC 

PHONE" 373-4753 ADDRESS 200 East 

FACD:.TFY IPUREX MSIN I S6-19 

This waste p redetermination is based on the MSDS information for p roductstmate rials li 

sted in the predetermination request and 

was performed according to current state and Federal law (WAC 173-303 and 40 CFR 261). For questions or comments, please 

contact the Generator & Waste Acceptance Services analyst above and reference the request #. Thank you for your interest in 

waste predetermination. 

Item # DfSDS # Productgliaterial 

REGULATED ?...... 

Rags^sitii 

Unused Used Empty 

Product Product. Container fd ^ ' Possible Wdste Cod"_:_ 

Product 

I Lab Analysis PURER Tank U3 FuW Flush Solution N I N I N N NONE 

Comments: B ased on Lab analysis and attached process knowledge from the above waste generator, the "PURBX 

U3 Final Flush Solution" does not designate as a Washington dangerous or extremely hazardous waste. 

rage t or i 

DISCLAIMER .. . 

This predetermination is believed accurate based on the information p rovided. Predeterminations a re performed to assist 

generators in selecting less hazardous p roducts. Since solid waste regulations are subject to constant revision, waste status may.. 

change without notice. Waste designations must be performed on aUwastes by Generator& Waste Acceptance Se rv ices to assure 

proper disposal in the event products are spilled or contained within a waste matrix. . 

l

clay, 

The following should better address concerns for the presence of 

acetone in RCRA Sample BOHX43 collected from the PURER Tank U3 final 

flush solution. Acetone, detected at 0.05 ppm for sample BOHX43, is 

not designated as unused discarded chemical material products or spent 

solvents. 

No unused or spent solvent acetone was discharged into this tank. The 

use of acetone in the PUREX laboratory and other places in the plant was 

eliminated in 1989. However, it is most likely that some residual 

amount remained from that time. It is also possible that acetone is 

present as a degradation product from the organics used in the process, 

and acetone, as a degradation product, would not constitute a spent 

solvent. 

In addition, per EPA's and Ecology's concurrence, any acetone in waste 

solutions, resulting from the past practice of returning analyzed 

sample solutions to the PUREX process, will not carry listed waste 

codes. 

If you have any questions or need additional information, please 

contact me at 373-4753. 

Thank you, 

Carmen Villalobos 

W

9653803 

ATTACHMENT 2 

LETTER FOR TRANSMITTAL TO ECOLOGY AND EPA 

Page 1 of 2

0 

Mr. Michael A. Wilson 

Program Manager 

State of Washington 

Department of Ecology 

1315 W. 4th Avenue 

Kennewick, Washington 99336 

Dear Mr. Wilson: 

TRANSMITTAL OF PLUTONIUM URANIUM EXTRACTION PLANT TANK U3 FLUSH ANALYTICAL 

RESULTS 

Enclosed are laboratory analytical results conducted on the final flush for 

the Plutonium Uranium Extraction (PUREX) Plant Tank U3. These results are 

transmitted in accordance with U.S. Department of Energy, Richland Operations 

Office/Westinghouse Hanford Company agreement with State of Washington 

Department of Ecology and the U. S. Environmental Protection Agency. 

This is the last of the analytical results from vessel flushes as defined in 

Westinghouse Hanford Company Supporting Document WHC-SD-EN-TI-283, Revision 0, 

"Data Quality Objectives for PUREX Deactivation Flushing." 

A copy of the Predetermination Report, designating the final flush solutions 

based on the analytical results, is also included in the enclosure. The final 

flush for this tank was designated as non-dangerous waste. 

If you have any questions, please contact L. D. Romine (376-4747) of my staff. 

Enclosure: 

Predetermination Report 

Sincerely, 

cc: J. K. Bartz, Ecology 

D. L. Duncan, EPA 

D. G. Hamrick, WHC, w/o encl. 

M. N. Jaraysi, Ecology 

R. Jim, YIN, w/o encl. 

G. J. LeBaron, WHC, w/o encl. 

D. Powaukee, NPT, w/o encl. 

J. Wilkinson, CTUIR, w/o encl. 

J. E. Mecca, Director 

Transition Programs Division

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