October 15, 2012 - City of Laredo

October 15, 2012 - City of Laredo October 15, 2012 - City of Laredo

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Material Safety i)ata Sheet , Shell SPIRAXB I ,EAR OIL SAE 80W-90 1 MSDS# 864020L i Version 13.0 Effective Date 07/03/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 i I i other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, 1 Additional Advjce : sand or other suitable material and dispose of properly. Local authorities should be advised if significant spillages 1 cannot be contained. 7. HANDLING AN^ STORAGE General ~recaqtions : Use local exhaust ventilation if there is risk of inhalation of I ; I i vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine 1 appropriate controls for safe handling, storage and disposal of ~ this material. ~ Handling 1 : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety Storage i ! : footwear should be worn and proper handling equipment should be used. Keep container tightly closed and in a cool, well-ventilated i place. Use properly labelled and closeable containers. Storage Temperature: 0 - 50 "C / 32 - 122 O F ~ecommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional lnfqrmation : Polyethylene containers should not be exposed to high I temperatures because of possible risk of distortion. i 8. EXPOSURE CO dTROLS/PERSONAL PROTECTION Oil mist, Occupational Exposure Limits Oil mist, STEL(Mist.) l mineral I i I I I I I Exposure ~ofrols : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls I ! i based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne I i Personal Protective Equipment i : concentrations to be generated. Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory ~fotection : No respiratory protection is ordinarily required under normal I I conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of Print Date 1 111 0/20/11 1 Type TWA(lulisi.) ppm I mg/m3 1 Notation 1 5 mg/m3 MSDS-US

Material Safety $ata Sheet I i Shell SPIRAXB I- EAR OIL SAE 80W-90 I MSDS# 864020L i Version 13.0 ~ 1 Effective Date 07/03/2008 According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 : Typical 400 mm2ls at 40 "C I 104 OF : > 1 (estimated value(s)) : Data not available i Stability 1 : Stable. Conditions to Atoid : Extremes of temperature and d~rect sunlight. Materials to Avo,id : Strong oxidising agents. Hazardous Decqmposiltion : Hazardous decomposition products are not expected to form Products during normal storage. Basis for Asse4;sment Acute Oral ~ox/icit~ Acute Dermal loxicity Acute Inhalation Toxic:ity Skin lrritation / Eye lrritation i Respiratory lrrltation Sensitisation Repeated Dos 1 Toxicity Mutagenicity I ~arcino~eniciti~ : Information given is based on data on the components and the toxicology of similar products. : Expected to be of low toxicity: LD50 > 5000 mglkg , Rat : Expected to be of low toxicity: LD50 > 5000 mglkg , Rabbit : Low toxicity by inhalation. : Expected to be slightly irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. : Expected to be slightly irritating. : Inhalation of vapours or mists may cause irritation. : Not expected to be a skin sensitiser. : Not expected to be a hazard. : Not considered a mutagenic hazard. : Product contains mineral oils of types shown to be non- carcinogenic in animal skin-painting studies. Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Other components are not known to be associated with carcinogenic effects. Reproductive {~nd Developmenta/l Toxicity : Not expected to be a hazard. Additional lnfqrmation : Used oils may contain harmful impurities that have i I I accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. 12. ECOLOGICAL /INFORIMATION ~ ~cotoxicologic~.l data have not been determined specifically for this product, Information given is based on a kndwledge of the components and the ecotoxicology of similar products. Acute ~oxiciti : Poorly soluble mixture. May cause physical fouling of aquatic I I organisms. Expected to be practically non toxic: LUEUIL50 > 100 mg/l (to aquatic organisms) (LUEL50 expressed as the nominal amount of product required to prepare aqueous test extract). Mineral oil is not expected to cause any chronic I i I 517 Print Date 1 1 I1 0/20/11 MSDS-US

Material Safety $ata Sheet<br />

I<br />

i Shell SPIRAXB I- EAR OIL SAE 80W-90<br />

I MSDS# 864020L<br />

i Version 13.0<br />

~<br />

1 Effective Date 07/03/2008<br />

According to OSHA Hazard Communication Standard, 29 CFR<br />

1910.1200<br />

: Typical 400 mm2ls at 40 "C I 104 OF<br />

: > 1 (estimated value(s))<br />

: Data not available<br />

i<br />

Stability 1 : Stable.<br />

Conditions to Atoid : Extremes <strong>of</strong> temperature and d~rect sunlight.<br />

Materials to Avo,id : Strong oxidising agents.<br />

Hazardous Decqmposiltion : Hazardous decomposition products are not expected to form<br />

Products during normal storage.<br />

Basis for Asse4;sment<br />

Acute Oral ~ox/icit~<br />

Acute Dermal loxicity<br />

Acute Inhalation Toxic:ity<br />

Skin lrritation /<br />

Eye lrritation i<br />

Respiratory lrrltation<br />

Sensitisation<br />

Repeated Dos 1 Toxicity<br />

Mutagenicity I<br />

~arcino~eniciti~<br />

: Information given is based on data on the components and the<br />

toxicology <strong>of</strong> similar products.<br />

: Expected to be <strong>of</strong> low toxicity: LD50 > 5000 mglkg , Rat<br />

: Expected to be <strong>of</strong> low toxicity: LD50 > 5000 mglkg , Rabbit<br />

: Low toxicity by inhalation.<br />

: Expected to be slightly irritating. Prolonged or repeated skin<br />

contact without proper cleaning can clog the pores <strong>of</strong> the skin<br />

resulting in disorders such as oil acne/folliculitis.<br />

: Expected to be slightly irritating.<br />

: Inhalation <strong>of</strong> vapours or mists may cause irritation.<br />

: Not expected to be a skin sensitiser.<br />

: Not expected to be a hazard.<br />

: Not considered a mutagenic hazard.<br />

: Product contains mineral oils <strong>of</strong> types shown to be non-<br />

carcinogenic in animal skin-painting studies. Highly refined<br />

mineral oils are not classified as carcinogenic by the<br />

International Agency for Research on Cancer (IARC). Other<br />

components are not known to be associated with carcinogenic<br />

effects.<br />

Reproductive {~nd<br />

Developmenta/l Toxicity<br />

: Not expected to be a hazard.<br />

Additional lnfqrmation : Used oils may contain harmful impurities that have<br />

i<br />

I I<br />

accumulated during use. The concentration <strong>of</strong> such impurities<br />

will depend on use and they may present risks to health and<br />

the environment on disposal. ALL used oil should be handled<br />

with caution and skin contact avoided as far as possible.<br />

12. ECOLOGICAL /INFORIMATION<br />

~<br />

~cotoxicologic~.l data have not been determined specifically for this product, Information given is<br />

based on a kndwledge <strong>of</strong> the components and the ecotoxicology <strong>of</strong> similar products.<br />

Acute ~oxiciti : Poorly soluble mixture. May cause physical fouling <strong>of</strong> aquatic<br />

I<br />

I<br />

organisms. Expected to be practically non toxic: LUEUIL50 ><br />

100 mg/l (to aquatic organisms) (LUEL50 expressed as the<br />

nominal amount <strong>of</strong> product required to prepare aqueous test<br />

extract). Mineral oil is not expected to cause any chronic<br />

I<br />

i<br />

I 517<br />

Print Date 1 1 I1 0/20/11 MSDS-US

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