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Isotopic and Geochemical Records of the Middle Eocene Climatic Changes in<br />

Central Anatolia, Turkey<br />

Faruk Ocakoğlu 1 , Sanem Açıkalın 1 , İsmail Ömer Yılmaz 2 , Celal Erayık 1<br />

1 Eskişehir Osmangazi University, Department of Geology Engineering, Eskişehir<br />

2 Middle East Technical University, Department of Geology Engineering, Ankara<br />

A 150 m thick lacustrine succession crops out in vicinity of Orhaniye and Güvenç villages in<br />

the 20 km north of Ankara (central Turkey). It is made of generally rhythmically bedded shalelimestone<br />

alternations. High resolution sedimentological logging and isotopic and geochemical<br />

investigation of the samples collected enabled the understanding of climatic and limnological<br />

conditions prevailed during the deposition of succession. Spectral analysis of bed thickness<br />

displayed statistically significant hidden cyclicities at 8.2 m and 16.1 m that would correspond<br />

precession and obliquity Milankovitch bands respectively. This finding, together with the<br />

previously published benthic foraminifera biozone data of overlying marine unit showed that the<br />

target lacustrine unit would have been deposited within 430 ka between 44.53 Ma and 44.1 Ma.<br />

Evaluation of the δ13C and δ18O concentrations indicates relatively high correlation between<br />

them. Carbonate intervals have higher δ18O (>-3 permil) and δ13C compared to shale levels.<br />

An overall negative shift in δ18O up in the section is typical. Proxy elements of Co, V, Ni, Mn<br />

and Zn, characteristic of reducing conditions are enriched in shale levels and more scarce in<br />

carbonates. The upper half of the section is evidently poor in these elements compared to lower<br />

half. Indicators of the weathering intensity in source area, the Na 2 O/Al 2 O3, Na 2 O/TiO 2 and Na 2 O/<br />

K 2 O ratios are generally higher in carbonate intervals. Similarly, the upper part of the section<br />

has lower elemental ratios that may explain more humid and warm climate conditions. δ13C<br />

isotope stratigraphy having a positive shift (5.6 permil) in the lower part and then a negative<br />

shift towards up may support this interpretation. These briefly explained preliminary data proves<br />

that during the deposition of the Güvenç lacustrine sediments in the Middle Eocene climatic<br />

optimum, astronomic forcing may have been prime driver. Probably for this reason, δ18O<br />

stratigraphy of the area has very parallels with the previously published global pattern of this<br />

time. In this scheme, carbonate intervals of the Güvenç succession may have been formed during<br />

cold and dry periods while the shale intervals represent warm and hot period when the lake level<br />

and weathering intensity were higher.<br />

Keywords: Lacustrine, Lutetien, Eocene climatic optimum, stable isotopes, geochemistry<br />

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