ÇAĞRILI KONUŞMALAR / KEYNOTES Invited Speeches ... - TPJD

Prediction of Temperature Change of Hydrocarbon Gases Using A Two-
Parameter Z-Factor Correlation Under Isenthalpic Flash Conditions
Cansu Uğur 1 , Şenol Yamanlar 2
1 BVG Shipping and Trading Lmd, İstanbul
2 İstanbul Technical Universİty, Faculty of Mines, Department of Petroleum and Natural Gas
Engineering, İstanbul
Isenthalpic expansion processes of real gases through restrictions are usually accompanied
by a temperature change of the gas phase. This phenomena is known as the Joule-Thomson
cooling (or heating). The temperature change depends on the initial and final pressures and
initial temperature as well as the composition of the gas phase. Natural gases cool down at
moderate pressures upon expansion in downhole perforations or in surface chokes whereas gas
condensates may heat up when expanded at elevated reservoir pressures and temperatures.
The direction and the magnitude of the temperature change may be predicted by using an
isenthalpic flash calculation procedure. The constant enthalpy expansion of a real gas may result
with condensation of a liquid phase due to the lowered gas temperature. In such processes,
simultaneous solution of mass and enthalpy balance equations is required. If there is no
liquid condensation after the expansion, the enthalpy balance equation should be solved for
downstream temperature given up and downstream pressures and upstream temperature.
An equation of state or a two-parameter z-factor correlation can be used to model the PVT
behavior of the single phase natural gas in constant enthalpy flash calculations. Two-parameter z
factor correlations are simpler to code and reduce computational time. However their accuracy
in energetic computations is not well understood. In this paper, predictive capability of Abu
Kassem-Dranchuk z-factor correlation is studied when used in calculating temperature changes
during a constant enthalpy flash process. The results are compared to Peng-Robinson equation
of state and to a leading reference thermodynamic fluid properties program results.
Keywords: Natural gas, hydrocarbon, enthalpy, expansion, temperature change, z-factor,
equation of state
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