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ÇAĞRILI KONUŞMALAR / KEYNOTES Invited Speeches ... - TPJD

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Petrographic Examination of the Southeast Anatolian Asphaltite Occurrences<br />

and Their Utilisation<br />

Selami Toprak 1 , Orhan Kavak 2<br />

1 General Directorate of Mineral Research and Exploration, Ankara<br />

2 Dicle University, Faculty of Engineering, Department of Mining Engineering, Diyarbakır<br />

Asphaltite is a form of natural organic material, which is solid, hard, black, black-brownish colored,<br />

and of petroleum source (Kavak, 2011). Its fusion temperature is about 200-315°C. It is soluble in<br />

Carbon Disulfide. It is also defined as a solid petroleum based mine formed with metamorphism.<br />

Liquid and semi liquid component of heavy petroleum solidifies in a suitable environment (as<br />

fracture, void etc.) and settles with effects of migration controlled with hydrostatic pressure,<br />

gas pressure, capillarity, gravitation and heat. Mobile asphalt passes through various fractures<br />

and cracks up to surface. There are various forms of asphaltites in nature and it is mostly<br />

observed in Sirnak region in Turkey and settled within fault and fracture cavities. In spite of high<br />

sulphure, ash and volatile matter content, asphaltite is utilized as heating fuel and even has<br />

been known as “coal”. It is possible to produce a great deal of material from asphaltite and also<br />

used in production of paint, varnish, car-tires, electric insulation, battery preservation, expanded<br />

natural rubber, floor tiles and waterproof cables. Asphaltite has recently taken lots of attentions<br />

to be counted as a source for production synthetic crude oil. But the production of synthetic<br />

oil from asphaltites has never set in application due to being assumed as small reserves and<br />

being consumed immensely. Asphaltite term is used synonymously with many names. These are;<br />

migrabitumen, natural solid petroleum bitumen, pitch and tar. Since it includes about 20% of<br />

liquid products, like petroleum, it takes interests economically as well. In this study, totally about<br />

30 samples were taken from the twelve known individual asphaltite veins in South East Anatolia,<br />

the biggest reserves, Avgamasya and Harbol occurrences were taken into considerations with<br />

detail. Rmax reflection values of asphaltitic material were measured and the organic as well<br />

as inorganic ingredients of them were scrutinized. In the study, Rmax values of Seridahli,<br />

Avgamasya, Milli and Segürük samples display much higher values (>0.35%) than the others.<br />

With this result, it is assumed that the high Rmax showing regions have witnessed higher paleo-<br />

thermometric heat values (> 1000 C). The region’s occurrences were ones found to display less<br />

solution in Carbon Disulphide (Orhun, 1969). Furthermore, it is estimated that the occurrences<br />

associated mainly with Cudi units have undergone much more severe actions. These occurrences<br />

comprising of more than 35% mineral matter (ash) content, and are called as “pyrobitumens”<br />

as well (Lebküchner, 1969). The asphaltites comprise considerably high amount of pyrite (>7%)<br />

and, resultantly, sulphure content, this cause to produce environmental concerns when used as<br />

fuel. Getting rid of the micron sized pyrites from the material seems costly due to high grinding<br />

costs. Although they contain of low amount of nickel, molybdenum, vanadium and uranium, it is<br />

possible to produce them with acid leaching before they are used as fuels (Seferinoğlu vd., 1982).<br />

It is advised that such studies to be continued in applications, and the material, to be leached<br />

before they are used as fuel raw material.<br />

Keywords: Asphaltite, Petrography of asphaltites, Mineral matter content of asphaltites,<br />

Environmentally responsive utilization of Southeast Anatolian asphaltite<br />

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