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Tellurite And Fluorotellurite Glasses For Active And Passive

Tellurite And Fluorotellurite Glasses For Active And Passive

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6. Optical properties; MDO 208<br />

Table (6.7) summarises the positions (P), half-widths (W), and areas (A) of these bands.<br />

Table (6.7): Positions (P), half-widths (W), and areas (A) of OH bands for glasses of the<br />

series (90-x)TeO2-10Na2O-xZnF2, mol. %, for 5 ≤ x ≤ 30 mol. % (glasses MOF001, 004<br />

to 008).<br />

Glass x ZnF2 / mol. % Weak OH Free OH<br />

MOF<br />

P /<br />

ID<br />

cm -1<br />

W /<br />

cm -1<br />

A /<br />

(cm -1 ) 2<br />

P /<br />

cm -1<br />

W /<br />

cm -1<br />

A /<br />

(cm -1 ) 2<br />

004 30 2929 317 11 3325 326 6<br />

001 25 2919 301 16 3309 284 7<br />

005 20 2910 267 7 3335 319 4<br />

006 15 2927 324 9 3343 226 3<br />

007 10 2947 400 23 3324 232 5<br />

008 5 2924 406 58 3274 273 15<br />

Table (6.8) and fig. (6.35) summarise the areas of these bands.<br />

Table (6.8): Percentage of OH groups for glasses of the series (90-x)TeO2-10Na2OxZnF2,<br />

mol. %, for 5 ≤ x ≤ 30 mol. % (glasses MOF001, 004 to 008).<br />

Glass MOF x ZnF2 / Weak Free<br />

ID mol. % OH / % OH / %<br />

004 30 62 38<br />

001 25 71 29<br />

005 20 63 37<br />

006 15 74 26<br />

007 10 82 18<br />

008 5 79 21

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