Tellurite And Fluorotellurite Glasses For Active And Passive
Tellurite And Fluorotellurite Glasses For Active And Passive Tellurite And Fluorotellurite Glasses For Active And Passive
6. Optical properties; MDO 207 Absorption coefficient / cm -1 0.06 FTIR data 0.05 Gaussian fit Weak OH (2947 cm 0.04 0.03 -1 ) Free OH (3324 cm -1 4.0 3.8 3.6 3.4 3.2 3.0 2.8 Baseline: y=[875/x]^4+0.431 Chi^2 = 2.9932E-6 R^2 = 0.9856 ) y0 0 ±0 xc1 2946.91761 ±2.12554 w1 A1 400.39325 23.42574 ±3.73518 ±0.22293 xc2 3324.31284 ±3.00352 w2 231.94867 ±5.34024 A2 5.16635 ±0.20654 0.02 0.01 0.00 Wavelength / µm 2600 2800 3000 3200 3400 0 3600 Wavenumber / cm -1 Fig. (6.33): Gaussian deconvolution of the OH bands for glass MOF007 (80TeO2- 10Na2O-10ZnF2 mol. %). Absorption coefficient / cm -1 0.16 0.14 0.12 0.10 0.08 0.06 0.04 0.02 FTIR data Gaussian fit Weak OH (2924 cm -1 ) Free OH (3274 cm -1 ) Wavelength / µm 4.0 3.8 3.6 3.4 3.2 3.0 2.8 0.00 0 2400 2600 2800 3000 3200 3400 3600 Wavenumber / cm -1 Baseline: [1240/x]^4+0.52 Chi^2 = 0.00002 R^2 = 0.98872 y0 0 ±0 xc1 2923.5899 ±3.9576 w1 406.04562 ±5.26077 A1 57.63908 ±1.01847 xc2 3273.534 ±5.26013 w2 272.93229 ±7.16477 A2 15.01855 ±0.98824 Fig. (6.34): Gaussian deconvolution of the OH bands for glass MOF008 (85TeO2- 10Na2O-5ZnF2 mol. %). 60 50 40 30 20 10 160 140 120 100 80 60 40 20 Loss / dB.m -1 Loss / dB.m -1
6. Optical properties; MDO 208 Table (6.7) summarises the positions (P), half-widths (W), and areas (A) of these bands. Table (6.7): Positions (P), half-widths (W), and areas (A) of OH bands for glasses of the series (90-x)TeO2-10Na2O-xZnF2, mol. %, for 5 ≤ x ≤ 30 mol. % (glasses MOF001, 004 to 008). Glass x ZnF2 / mol. % Weak OH Free OH MOF P / ID cm -1 W / cm -1 A / (cm -1 ) 2 P / cm -1 W / cm -1 A / (cm -1 ) 2 004 30 2929 317 11 3325 326 6 001 25 2919 301 16 3309 284 7 005 20 2910 267 7 3335 319 4 006 15 2927 324 9 3343 226 3 007 10 2947 400 23 3324 232 5 008 5 2924 406 58 3274 273 15 Table (6.8) and fig. (6.35) summarise the areas of these bands. Table (6.8): Percentage of OH groups for glasses of the series (90-x)TeO2-10Na2OxZnF2, mol. %, for 5 ≤ x ≤ 30 mol. % (glasses MOF001, 004 to 008). Glass MOF x ZnF2 / Weak Free ID mol. % OH / % OH / % 004 30 62 38 001 25 71 29 005 20 63 37 006 15 74 26 007 10 82 18 008 5 79 21
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6. Optical properties; MDO 207<br />
Absorption coefficient / cm -1<br />
0.06<br />
FTIR data<br />
0.05<br />
Gaussian fit<br />
Weak OH (2947 cm<br />
0.04<br />
0.03<br />
-1 )<br />
Free OH (3324 cm -1 4.0 3.8 3.6 3.4 3.2 3.0 2.8<br />
Baseline: y=[875/x]^4+0.431<br />
Chi^2 = 2.9932E-6<br />
R^2 = 0.9856<br />
)<br />
y0 0 ±0<br />
xc1 2946.91761 ±2.12554<br />
w1<br />
A1<br />
400.39325<br />
23.42574<br />
±3.73518<br />
±0.22293<br />
xc2 3324.31284 ±3.00352<br />
w2 231.94867 ±5.34024<br />
A2 5.16635 ±0.20654<br />
0.02<br />
0.01<br />
0.00<br />
Wavelength / µm<br />
2600 2800 3000 3200 3400<br />
0<br />
3600<br />
Wavenumber / cm -1<br />
Fig. (6.33): Gaussian deconvolution of the OH bands for glass MOF007 (80TeO2-<br />
10Na2O-10ZnF2 mol. %).<br />
Absorption coefficient / cm -1<br />
0.16<br />
0.14<br />
0.12<br />
0.10<br />
0.08<br />
0.06<br />
0.04<br />
0.02<br />
FTIR data<br />
Gaussian fit<br />
Weak OH (2924 cm -1 )<br />
Free OH (3274 cm -1 )<br />
Wavelength / µm<br />
4.0 3.8 3.6 3.4 3.2 3.0 2.8<br />
0.00<br />
0<br />
2400 2600 2800 3000 3200 3400 3600<br />
Wavenumber / cm -1<br />
Baseline: [1240/x]^4+0.52<br />
Chi^2 = 0.00002<br />
R^2 = 0.98872<br />
y0 0 ±0<br />
xc1 2923.5899 ±3.9576<br />
w1 406.04562 ±5.26077<br />
A1 57.63908 ±1.01847<br />
xc2 3273.534 ±5.26013<br />
w2 272.93229 ±7.16477<br />
A2 15.01855 ±0.98824<br />
Fig. (6.34): Gaussian deconvolution of the OH bands for glass MOF008 (85TeO2-<br />
10Na2O-5ZnF2 mol. %).<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
160<br />
140<br />
120<br />
100<br />
80<br />
60<br />
40<br />
20<br />
Loss / dB.m -1<br />
Loss / dB.m -1