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Tellurite And Fluorotellurite Glasses For Active And Passive

Tellurite And Fluorotellurite Glasses For Active And Passive

Tellurite And Fluorotellurite Glasses For Active And Passive

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1. Introduction; MDO 6<br />

1.4. Thesis structure<br />

A literature review (chapter 2) will follow this introductory section, outlining tellurite and<br />

fluorotellurite glass research most relevant to the compositions studied here. Background<br />

to glass formation, and optical loss mechanisms will also be discussed. Chapters 3 to 8,<br />

inclusively, individually containing experimental, results, discussion, and summary<br />

sections based on the work undertaken. Chapter 3 will detail the glass batching and<br />

melting procedures used, with a tabulated list of all compositions studied. Chapter 4<br />

looks at the characteristic temperatures of these glasses, obtained by differential thermal<br />

analysis (DTA). Crystal structure of batch materials, products of melting, and devitrified<br />

glasses were then examined, using X-ray diffraction (XRD), presented in chapter 5. The<br />

infrared spectra and refractive indices of a number of compositions are then evaluated in<br />

chapter 6, by FTIR- spectroscopy, and ellipsometry respectively. Chapter 7 shows some<br />

of the surface properties of the tellurite and fluorotellurite glasses: X-ray photoelectron<br />

spectroscopy (XPS), chemical and environmental durability, and ion-exchange. Finally<br />

chapter 8 presents the optical fibre drawing process, viscosity-temperature behaviour,<br />

defects in the fibres, and fibre loss, measured by cut-back. The conclusions chapter (9)<br />

summarises the main points from chapters 3 to 8 inclusive, and the thesis ends with future<br />

work (chapter 10). References will be listed at the end of each chapter.

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