Tellurite And Fluorotellurite Glasses For Active And Passive
Tellurite And Fluorotellurite Glasses For Active And Passive Tellurite And Fluorotellurite Glasses For Active And Passive
1. Introduction; MDO 3 distance systems operate at 1.3 and 1.55 µm using InGaAsP sources, where losses and pulse dispersion are lowered. 1.55 µm operation can incorporate all optical amplifiers; erbium doped fibre amplifiers (EDFAs), with erbium (III) - Er +3 , doped into the silica glass [2]. These are fast, and the signal no longer has to be transduced to electronics for amplification (hence all optical). EDFAs can transmit data at 2.4 Gbit.s -1 over a distance of 21,000 km [8], with efficiencies around 50,000 Gbit.km.s -1 [9], without the need for a repeater, and performance of these devices has since increased further due to wavelength division multiplexing (WDM) [6]. WDM currently allows the simultaneous transmission of around 100 different wavelengths along one fibre, to increase signal capacity, and is at present limited by the flatness of gain of the EDFA. 1.2. The role of novel glass compositions Novel glass compositions made from constituents other than SiO2, such as fluorides, chalcogenides, and heavy-metal oxides, are more optically flexible than silica, having a wide range of transparent windows, linear and non-linear refractive indices, and lower phonon energies, for more efficient rare-earth luminescence [10]. This lower phonon energy than silica, results in substantially increased rare-earth lifetimes in the glass host (and possibly shifted and broadened emission bands), as de-population of excited states is statistically less likely by non-radiative processes. Rare-earth solubility is often higher in novel glass hosts [11]. These are important considerations for developing the next generation of low loss broadband, flat gain fibre amplifiers.
1. Introduction; MDO 4 Infrared transmission is useful for spectroscopic sensing of chemicals / organic groups, whose fundamental absorption bands occur in the mid-IR region. Bandwidth, and hence information carrying capacity is maximaised at zero dispersion (d 2 n/dλ 2 =0, occurring at 1.3 µm for silica, and at longer wavelengths for infrared transmitting materials), and intrinsic scattering losses fall with increasing wavelength [10]. A high linear refractive index generally results in higher non-linearity than silica, with the possibility for use in high-speed switching and high power delivery devices. Glasses with an induced second-order non-linearity can be used for second harmonic generation. The third-order non-linearity can be utilised in devices to boost the transmitted signal with solitons, and the bandwidth increased with all-optical processing [12]. Raman amplification is another way of amplifying the signal carried by the fibre, and is an intrinsic non-linear property of the material. Novel glasses have been shown to exhibit Raman gain much higher than silica [13]. 1.3. Aims and objectives of this study The glasses studied here, tellurite and fluorotellurite (TeO2-based), exhibit many of the desirable properties listed in section 1.2, and therefore show potential in a number of devices and applications. However, there is not much published work to date, particularly on fluorotellurite glasses. Useful properties include transmission from the visible (400 nm) to the mid-IR (6 µm) [11], high refractive index (≈ 2, compared to ≈ 1.5 of silica [14]), large non-linearity (non-linear refractive index two orders of magnitude greater than silica [12]), with broad, long erbium (III) lifetimes [15], and Raman gain around 30
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1. Introduction; MDO 3<br />
distance systems operate at 1.3 and 1.55 µm using InGaAsP sources, where losses and<br />
pulse dispersion are lowered. 1.55 µm operation can incorporate all optical amplifiers;<br />
erbium doped fibre amplifiers (EDFAs), with erbium (III) - Er +3 , doped into the silica<br />
glass [2]. These are fast, and the signal no longer has to be transduced to electronics for<br />
amplification (hence all optical). EDFAs can transmit data at 2.4 Gbit.s -1 over a distance<br />
of 21,000 km [8], with efficiencies around 50,000 Gbit.km.s -1 [9], without the need for a<br />
repeater, and performance of these devices has since increased further due to wavelength<br />
division multiplexing (WDM) [6]. WDM currently allows the simultaneous transmission<br />
of around 100 different wavelengths along one fibre, to increase signal capacity, and is at<br />
present limited by the flatness of gain of the EDFA.<br />
1.2. The role of novel glass compositions<br />
Novel glass compositions made from constituents other than SiO2, such as fluorides,<br />
chalcogenides, and heavy-metal oxides, are more optically flexible than silica, having a<br />
wide range of transparent windows, linear and non-linear refractive indices, and lower<br />
phonon energies, for more efficient rare-earth luminescence [10]. This lower phonon<br />
energy than silica, results in substantially increased rare-earth lifetimes in the glass host<br />
(and possibly shifted and broadened emission bands), as de-population of excited states is<br />
statistically less likely by non-radiative processes. Rare-earth solubility is often higher in<br />
novel glass hosts [11]. These are important considerations for developing the next<br />
generation of low loss broadband, flat gain fibre amplifiers.