PS-PLLA - Www2.che.nthu.edu.tw

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Drug-Eluting Stent for Atherosclerosis ■ Sirolimus: immunosupressive agent with anti- inflammation and antiproliferation characteristics ■ Metallic stent: prevent vascular recoil ■ Local delivery for the sustained release of drug Stent implantation during percutaneous transluminal coronary angioplasty (PTCA) Mixture of drug and polymer coated on the stent for drug-eluting control SIBS
Pore-filling for Sirolimus Capillary force driven from the tunable wetting property of aqueous solution for the templates Ho, R.-M. et al. Macromolecules 2007, 40, 2621. nanoscale releasing Ho, R.-M. et al. ACS Nano, 2009, 3, 2260. Water → enhance the surface tension for the deposition of the <strong>PS</strong> template Ethanol → wet the <strong>PS</strong> template for the driven capillary force
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Block Copolymer Thin Films
Page 3 and 4:
Thickness Effect while t is small f
Page 6 and 7:
Phase diagram of thin film morpholo
Page 9 and 10:
Surface Tension @
Page 11 and 12:
Grain boundary problem for thicker
Page 13 and 14:
Electric field-Induced Orientation
Page 15 and 16:
Shear-induced Orientation PS-PEP Cy
Page 17:
Grephoepitaxy-induced Orientation C
Page 21 and 22:
Evaporation-induced Orientation Spi
Page 23 and 24:
FESEM micrographs of hydrolyzed PS-
Page 25 and 26:
Tunable dimensions of nanostructure
Page 27 and 28:
Spin-coated PS-PLLA thin films Perp
Page 29 and 30:
Definition of Solvent Solvent Molar
Page 31 and 32:
Evaporation Rate Effect Selective s
Page 33 and 34:
Solution Casting Neutral solvent Cr
Page 35 and 36: Molecular Weight Effect Selective S
Page 37 and 38: Tg Effect Side view image of FESEM
Page 39 and 40: Substrate Effect Glass slide Carbon
Page 41 and 42: Proposed Mechanism Segregation stre
Page 43 and 44: Nanopatterning for Lamellar Nanostr
Page 45 and 46: Crystallizable solvent T max =150 o
Page 47 and 48: Strongly Segregated PS-PLLA Quench
Page 49 and 50: Crystallization-Induced Orientation
Page 51 and 52: Lattice Matching PLLA -PCL 0.514 nm
Page 53 and 54: Mechanisms 1.Homogeneous mixture of
Page 56 and 57: Methods for Nanopatterning Photoli
Page 58 and 59: Soft Lithography Whitesides, G. M.
Page 60 and 61: Scanning Probe Lithography Atomic f
Page 62 and 63: Advantages and Disadvantages Electr
Page 64 and 65: Nanopatterning from Degradable BCPs
Page 66 and 67: Nanopatterning from Degradable BCPs
Page 68 and 69: Synthetic routes of PS-PLLA block c
Page 70: Nanotemplate (i.e., Nanoreactor) A
Page 73 and 74: Pore-filling for Nanotemplates Capi
Page 75 and 76: TEM : Air-block releasing Nanoporou
Page 77 and 78: TEM : directed capillary force (met
Page 79 and 80: Confocal Microscopy Observation CdS
Page 81 and 82: Double-length-Scale Patterns (a) Co
Page 83 and 84: FESEM images of CNTs grown from PS/
Page 85: Lighting DTC Phosphor (CRT) Ni on D
Page 89 and 90: Accumulative Accumulative release r
Page 91 and 92: Nanoscale Spatial Effect PY/CM thin
Page 93: Chain Alignment Mechanism Solventan
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