PS-PLLA - Www2.che.nthu.edu.tw

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Scanning Probe Lithography Atomic force microscope tip as a “pen” A solid-state substrate as “paper” Molecules with a chemical affinity for the solid-state substrate as “ink” Transport of the molecules from the AFM tip to the solid substrate Mirkin, C. A. et. al. Science, 1999, 283, 661
Why Degradable Block Copolymers ? Polyesters: degradable characteristics for mesoporous materials Substrate Bio-degradation Chemical degradation Zalusky, A. S.; Olayo-Valles, R.; Taylor, C.; Hillmyer, M. A. J. Am. Chem. Soc. 2001, 123, 1519. Degradable blocks Non-degradable blocks Height profile Substrate Topographic nanopattern Nanopatterned template
Page 1 and 2:
Block Copolymer Thin Films
Page 3 and 4:
Thickness Effect while t is small f
Page 6 and 7:
Phase diagram of thin film morpholo
Page 9 and 10: Surface Tension @
Page 11 and 12: Grain boundary problem for thicker
Page 13 and 14: Electric field-Induced Orientation
Page 15 and 16: Shear-induced Orientation PS-PEP Cy
Page 17: Grephoepitaxy-induced Orientation C
Page 21 and 22: Evaporation-induced Orientation Spi
Page 23 and 24: FESEM micrographs of hydrolyzed PS-
Page 25 and 26: Tunable dimensions of nanostructure
Page 27 and 28: Spin-coated PS-PLLA thin films Perp
Page 29 and 30: Definition of Solvent Solvent Molar
Page 31 and 32: Evaporation Rate Effect Selective s
Page 33 and 34: Solution Casting Neutral solvent Cr
Page 35 and 36: Molecular Weight Effect Selective S
Page 37 and 38: Tg Effect Side view image of FESEM
Page 39 and 40: Substrate Effect Glass slide Carbon
Page 41 and 42: Proposed Mechanism Segregation stre
Page 43 and 44: Nanopatterning for Lamellar Nanostr
Page 45 and 46: Crystallizable solvent T max =150 o
Page 47 and 48: Strongly Segregated PS-PLLA Quench
Page 49 and 50: Crystallization-Induced Orientation
Page 51 and 52: Lattice Matching PLLA -PCL 0.514 nm
Page 53 and 54: Mechanisms 1.Homogeneous mixture of
Page 56 and 57: Methods for Nanopatterning Photoli
Page 58 and 59: Soft Lithography Whitesides, G. M.
Page 62 and 63: Advantages and Disadvantages Electr
Page 64 and 65: Nanopatterning from Degradable BCPs
Page 66 and 67: Nanopatterning from Degradable BCPs
Page 68 and 69: Synthetic routes of PS-PLLA block c
Page 70: Nanotemplate (i.e., Nanoreactor) A
Page 73 and 74: Pore-filling for Nanotemplates Capi
Page 75 and 76: TEM : Air-block releasing Nanoporou
Page 77 and 78: TEM : directed capillary force (met
Page 79 and 80: Confocal Microscopy Observation CdS
Page 81 and 82: Double-length-Scale Patterns (a) Co
Page 83 and 84: FESEM images of CNTs grown from PS/
Page 85 and 86: Lighting DTC Phosphor (CRT) Ni on D
Page 87 and 88: Pore-filling for Sirolimus Capillar
Page 89 and 90: Accumulative Accumulative release r
Page 91 and 92: Nanoscale Spatial Effect PY/CM thin
Page 93: Chain Alignment Mechanism Solventan
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