PS-PLLA - Www2.che.nthu.edu.tw

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PS128LLA106 diblock copolymer: Lamellar morphology Epitaxy-induced Morphology Phase-separated Morphology 500nm Area > 150μm 2 ! PLLA(200) PLLA(110) 500nm
Mechanisms 1.Homogeneous mixture of solvent and polymer PS PLLA Polymer-crystallizable solvent solution Crystalline substrate Glass-slide 2.Directional crystallization of crystallizable solvent T m, solvent 1 2 L+ 5 6 Liquid + L+ 0 0.5 1 Weight fraction of block copolymer 3.Directional eutectic solidification for strongly segregated PS-PLLA T m, PLLA block T e T C, PLLA block T ODT : Crystalline substrate : PS-PLLA 4.Isothermal crystallization Ho, R.-M. et al. Macromolecules 2006, 39, 7071.
Page 1 and 2: Block Copolymer Thin Films
Page 3 and 4: Thickness Effect while t is small f
Page 6 and 7: Phase diagram of thin film morpholo
Page 9 and 10: Surface Tension @
Page 11 and 12: Grain boundary problem for thicker
Page 13 and 14: Electric field-Induced Orientation
Page 15 and 16: Shear-induced Orientation PS-PEP Cy
Page 17: Grephoepitaxy-induced Orientation C
Page 21 and 22: Evaporation-induced Orientation Spi
Page 23 and 24: FESEM micrographs of hydrolyzed PS-
Page 25 and 26: Tunable dimensions of nanostructure
Page 27 and 28: Spin-coated PS-PLLA thin films Perp
Page 29 and 30: Definition of Solvent Solvent Molar
Page 31 and 32: Evaporation Rate Effect Selective s
Page 33 and 34: Solution Casting Neutral solvent Cr
Page 35 and 36: Molecular Weight Effect Selective S
Page 37 and 38: Tg Effect Side view image of FESEM
Page 39 and 40: Substrate Effect Glass slide Carbon
Page 41 and 42: Proposed Mechanism Segregation stre
Page 43 and 44: Nanopatterning for Lamellar Nanostr
Page 45 and 46: Crystallizable solvent T max =150 o
Page 47 and 48: Strongly Segregated PS-PLLA Quench
Page 49 and 50: Crystallization-Induced Orientation
Page 51: Lattice Matching PLLA -PCL 0.514 nm
Page 56 and 57: Methods for Nanopatterning Photoli
Page 58 and 59: Soft Lithography Whitesides, G. M.
Page 60 and 61: Scanning Probe Lithography Atomic f
Page 62 and 63: Advantages and Disadvantages Electr
Page 64 and 65: Nanopatterning from Degradable BCPs
Page 66 and 67: Nanopatterning from Degradable BCPs
Page 68 and 69: Synthetic routes of PS-PLLA block c
Page 70: Nanotemplate (i.e., Nanoreactor) A
Page 73 and 74: Pore-filling for Nanotemplates Capi
Page 75 and 76: TEM : Air-block releasing Nanoporou
Page 77 and 78: TEM : directed capillary force (met
Page 79 and 80: Confocal Microscopy Observation CdS
Page 81 and 82: Double-length-Scale Patterns (a) Co
Page 83 and 84: FESEM images of CNTs grown from PS/
Page 85 and 86: Lighting DTC Phosphor (CRT) Ni on D
Page 87 and 88: Pore-filling for Sirolimus Capillar
Page 89 and 90: Accumulative Accumulative release r
Page 91 and 92: Nanoscale Spatial Effect PY/CM thin
Page 93: Chain Alignment Mechanism Solventan

PS-PLLA - Www2.che.nthu.edu.tw

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