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OFR 151.pdf - CRC LEME

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climates. For example, grass species utilising the C4 photosynthesis pathway are most<br />

numerous in regions where summers are hot and wet. Their relative abundance declines in<br />

regions where mean annual temperatures and/or summer rainfall are relatively reduced<br />

(Hattersley 1983, 1987). Connin et al. (1998) have used δ 13 C variation in herbivore tooth<br />

enamel to evaluate patterns of C4 plant abundance, and therefore infer trends in summer<br />

rainfall, in the southwestern United States.<br />

3. Minerals<br />

A number of minerals form under highly specific conditions and these (or their casts) can<br />

provide direct or indirect information on past climates.<br />

An example is glendonite, which provide unequivocal evidence of seasonal freezing of<br />

seawater in the Eromanga Basin during the Early Cretaceous (Frakes et al. 1995). Gibson et<br />

al. (2000) have used a spike in kaolinite-dominated mineral assemblages to infer intensified<br />

weathering due to increased precipitation and temperatures on the north-east Atlantic coast of<br />

the United States during the Late Paleocene. Other widely used environmental indicators<br />

include evaporite minerals that form onshore only under arid and semi-arid conditions, e.g.<br />

anhydrite, gypsum and halite (cf. Bowler 1976). These are at the dry end of a spectrum of<br />

mineral indicators whose wet end are lignites and coal (Rees et al. 1999). Between these end<br />

members are clays such as illite, which indicate weathering under temperate conditions, and<br />

smectite, which indicates weathering under warm and semi-arid conditions. Uranium-lead<br />

dating of zircons has been used to provenance sands reworked into Quaternary sand dunes<br />

(Pell et al. 1997) and the same technique can be applied to pre-Quaternary contexts (B.<br />

Pillans pers. comm.).<br />

4. Palaeosols<br />

Fossil soils (palaeosols, paleosols) developed across former landsurfaces are indirect<br />

evidence of past climates and climatic change (Catt et al. 2000). Recent reviews of the<br />

terminology and taxonomy of palaeosols include Nettleton et al. (2000) and Reuter (2000).<br />

In Australia, considerable attention has been paid to the local conditions under which major<br />

cementing minerals in duricrust are transported by, and precipitated from, circulating<br />

groundwater. Examples are iron/aluminium sesquioxides (ferricrete), secondary silica<br />

(silcrete) and carbonates (calcrete) (Arakel 1991, Bourman 1993, Anand 1997).<br />

These and related studies indicate: (1) Ferricrete is best developed under climates with a<br />

seasonally variable rainfall (Milnes et al. 1985, Butt 1981, cited in Clarke 1994). (2) Silcrete<br />

requires acid-weathering conditions within the soil but otherwise cannot be linked to specific<br />

environmental conditions (Milnes and Twidale 1983). (3) Gibbsite, one of the major minerals<br />

found in bauxite, implies mean annual temperatures were above 22 ° C, unless drainage and<br />

parent rock characteristics were unusually favourable (references in: Price et al. 1997, Price<br />

1998, Taylor 1998). (4) Calcrete may form under sub-humid to semi-arid climates although<br />

one form (pedogenic calcrete) preferentially occurs in winter rainfall regions such as<br />

southwestern Western Australia whilst the other form (groundwater calcrete) preferentially<br />

occurs in regions receiving summer rainfall. (5) Saprolite can develop under almost any<br />

humid climatic regime although rates of 'deep weathering' will vary. More generally,<br />

Christopherson (1997) proposes that heavily weathered soils with distinctive iron and<br />

aluminium oxide horizons (oxisols) reflect seasonal- and non-seasonal wet tropical climates,<br />

respectively. Ekart et al. (1999) have used palaeosol carbonates to estimate atmospheric<br />

ρCO2 levels over the past 400 million years.<br />

51

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