semmelweis university 2 0 1 2 / 2 0 1 3

Week Lectures (4 hours per week)
13 Mean activity coefficients. Debye–Hückel theory. The ionic strength.
The mobilities of ions. The measurement of transport numbers.
Conductivities and ion-ion interactions. Diffusion and transport.
The metal ion/metal electrode. The ion (insoluble salt) metal electrode.
Oxidation-reduction electrodes. Liquid junctions and membrane potentials.
14 Kinds of cell. E.m.f. and electrode potentials, the sign convention.
The concentration dependence of the e.m.f. Standard electrode potentials.
Thermodynamic data from cell e.m.f.-s and applications of e.m.f. measurement.
The rate of charge transfer. The current density. Overpotential. Polarography.
PHYSICAL CHEMISTRY
Second Semester
Week Lectures (1 hour per week)
Practicals (4 hours per week)
1 Determination of freezing point depression.
2 Calibration of a thermometer. Determination the temperature of
a phase transition.
3 Studying IR Spectra.
4 Spectrophotometric investigations in the ultraviolet region.
5 Determination of ionization constant of indicators by
spectrophotometric method.
6 Solubility product determination by potentiometric method.
7 Measurement of pH by hydrogen-electrode, measurement of
redox potential.
8 Deadstop titration, determination of ionization constant of
a weak acid.
9 Computer assisted conductimetric titration.
10 Polarography.
11 Studying the kinetics of the hydrolysis.
12 Investigation of stressed decomposition of a medicine.
13 Studying of the surface tension.
14 Supplementary lab.
SEMMELWEIS UNIVERSITY / FACULTY OF PHARMACY
Faculty of
Pharmacy
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