semmelweis university 2 0 1 2 / 2 0 1 3

SEMMELWEIS UNIVERSITY / FACULTY OF PHARMACY
418
QUANTITATIVE ANALYTICAL CHEMISTRY
Second Semester
Lectures (2 hours per week) Practicals (5 hours per week)
Topic Task
Titration curves in oxidimetry. Titrat- Introduction Safety and order in the laboratory
ions with permanganate solution. Practical and theoretical requirements in
the semester
The schedule during the semester
Redox titrations (permanganometry)
Permanga- Standardization of » 0.1N potassium
nometry permanganate solution
Titrations with chromate and Permanga- Determination of the total iron content by
cerium (IV). Bromatometry I. nometry Zimmermann-Reinhardt method
Permanganometric determination of
bromide ions (Winkler’s method)
Bromatometry II. Reactions with Chromatometry Determination of Mohr salt with
periodate and their analytical use. chromatometric titration
Bromatometry Bromatometric determination of arsenic
(III) (from As2O3) or antimony (III)
compounds (in form of “tartar emetic”:
antymonyl tartarate)
Determination of azophene
Iodometric titrations and other TEST I.
reductometric methods. Bromatometry Bromatometric determination of ascorbic
Cerimetry acid (Vitamin C) in tablets (e.g..Vit C,
Rutascorbin, Béres C)
Cerimetric determination of amidazophene
Sampling and preparatory processes Iodometry Standardization of » 0.01N sodium
in analytical chemistry. thiosulfate solution
Determination of phenol in water / acetyl
salicylic acid content in tablets (e.g.
Aspirin, Kalmopyrin, Istopyrin,…) by
Koppeschaar’s method
Interactions between electromagnetic Iodometry Iodometric determination of copper (II)-ions
radiations and materials. Emission Determination of mannitol by Malaprade’s
spectroscopy. reaction with periodate
Flame emission photometry, atomic Iodometry Determination of iodide by Winkler’s method
absorption spectrophotometry. ICP–ES
and ICP–MS possibilities.
Molecular absorption spectroscopy in Optional TEST II.
UV-VIS region as well as in IR. measurements* One selection from “Other determinations”
Possibilities of spectrophotometric Instrumental Computer aided learning of modern
method(s) in complex systems. analysis instrumental analytical methods
(HPLC; GC; UV-Vis Spectrophotometry)
Separation methods in analytical Optional From “Potentiometric determinations”
chemistry. measurements* From “Other determinations”
Distillation, extraction and their Spectrophoto- Spectrophotometric determination of iron
possibilities. metry content in multivitamin tablets