GHS Classification Guidance for the Japanese Government
GHS Classification Guidance for the Japanese Government GHS Classification Guidance for the Japanese Government
classified”. For the grounds for judgment, see “water solubility” and “reactivity” fields, which are common in the classification entry forms. If the value of aqueous solubility is indicated there or if descriptions such as “water soluble” or “insoluble” are present, it shall be classified as “Not classified”. If a substance is water-reactive, a statement such as “react vigorously with water” is to be entered in the “reactivity” field. 76
2-3-13 Oxidizing Liquids (1)Definitions Definitions of oxidizing liquids in UN GHS are as follows, and they are adopted in this guidance. 【GHS 2 nd revised edition】(2.13.1) An oxidizing liquid is a liquid which, while in itself not necessarily combustible, may, generally by yielding oxygen, cause, or contribute to, the combustion of other material. (2)Classification criteria in GHS 【GHS 2 nd revised edition】 (2.13.2) An oxidizing liquid is classified in one of the three categories for this class using test O.2 in Part I II, sub-section 34.4.2 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, according to the following table: Table 2.13.1: Criteria for oxidizing liquids Category Criteria 1 Any substance or mixture which, in the 1:1 mixture, by mass, of substance (or mixture) and cellulose tested, spontaneously ignites; or the mean pressure rise time of a 1:1 mixture, by mass, of substance and cellulose is less than that of a 1:1 mixture, by mass, of 50% perchloric acid and cellulose; 2 Any substance or mixture which, in the 1:1 mixture, by mass, of substance (or mixture) and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 40% aqueous sodium chlorate solution and cellulose; and the criteria for Category 1 are not met; 3 Any substance or mixture which, in the 1:1 mixture, by mass, of substance (or mixture) and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 65% aqueous nitric acid and cellulose; and the criteria for Categories 1 and 2 are not met. (3) Guidance for Classification A) Judgment of Not applicable 1) Substances of gases and solids shall be judged as “Not applicable”. 2) Organic substances which do not contain oxygen, fluorine, or chlorine or which contain any of these elements that are bound to carbon or hydrogen only shall be judged “Not 77
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2-3-13 Oxidizing Liquids<br />
(1)Definitions<br />
Definitions of oxidizing liquids in UN <strong>GHS</strong> are as follows, and <strong>the</strong>y are adopted in this<br />
guidance.<br />
【<strong>GHS</strong> 2 nd revised edition】(2.13.1)<br />
An oxidizing liquid is a liquid which, while in itself not necessarily combustible, may,<br />
generally by yielding oxygen, cause, or contribute to, <strong>the</strong> combustion of o<strong>the</strong>r material.<br />
(2)<strong>Classification</strong> criteria in <strong>GHS</strong><br />
【<strong>GHS</strong> 2 nd revised edition】 (2.13.2)<br />
An oxidizing liquid is classified in one of <strong>the</strong> three categories <strong>for</strong> this class using test O.2 in<br />
Part I II, sub-section 34.4.2 of <strong>the</strong> UN Recommendations on <strong>the</strong> Transport of Dangerous Goods,<br />
Manual of Tests and Criteria, according to <strong>the</strong> following table:<br />
Table 2.13.1: Criteria <strong>for</strong> oxidizing liquids<br />
Category Criteria<br />
1 Any substance or mixture which, in <strong>the</strong> 1:1 mixture, by mass, of substance<br />
(or mixture) and cellulose tested, spontaneously ignites; or <strong>the</strong> mean<br />
pressure rise time of a 1:1 mixture, by mass, of substance and cellulose is<br />
less than that of a 1:1 mixture, by mass, of 50% perchloric acid and<br />
cellulose;<br />
2 Any substance or mixture which, in <strong>the</strong> 1:1 mixture, by mass, of substance<br />
(or mixture) and cellulose tested, exhibits a mean pressure rise time less<br />
than or equal to <strong>the</strong> mean pressure rise time of a 1:1 mixture, by mass, of<br />
40% aqueous sodium chlorate solution and cellulose; and <strong>the</strong> criteria <strong>for</strong><br />
Category 1 are not met;<br />
3 Any substance or mixture which, in <strong>the</strong> 1:1 mixture, by mass, of substance<br />
(or mixture) and cellulose tested, exhibits a mean pressure rise time less<br />
than or equal to <strong>the</strong> mean pressure rise time of a 1:1 mixture, by mass, of<br />
65% aqueous nitric acid and cellulose; and <strong>the</strong> criteria <strong>for</strong> Categories 1 and<br />
2 are not met.<br />
(3) <strong>Guidance</strong> <strong>for</strong> <strong>Classification</strong><br />
A) Judgment of Not applicable<br />
1) Substances of gases and solids shall be judged as “Not applicable”.<br />
2) Organic substances which do not contain oxygen, fluorine, or chlorine or which contain<br />
any of <strong>the</strong>se elements that are bound to carbon or hydrogen only shall be judged “Not<br />
77