GHS Classification Guidance for the Japanese Government

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2.8.2.2 Self-reactive substances and mixtures are classified in one of the seven categories of“Types A to G”for this class,according to the following principles: (a) Any self-reactive substance or mixture which can detonate or deflagrate rapidly, as packaged, will be defined as self-reactive substance TYPE A; (b) Any self-reactive substance or mixture possessing explosive properties and which, as packaged, neither detonates nor deflagrates rapidly, but is liable to undergo a thermal explosion in that package w ill be defined as self-reactive substance TYPE B; (c) Any self-reactive substance or mixture possessing explosive properties when the substance or mixture as packaged cannot detonate or deflagrate rapidly or undergo a thermal explosion will be defined as self-reactive substance TYPE C; (d) Any self-reactive substance or mixture which in laboratory testing: (i) detonates partially, does not deflagrate rapidly and shows no violent effect when heated under confinement; or (ii) does not detonate at all, deflagrates slowly and shows no violent effect when heated under confinement; or (iii) does not detonate or deflagrate at all and shows a medium effect when heated under confinement; will be defined as self-reactive substance TYPE D; (e) Any self-reactive substance or mixture which, in laboratory testing, neither detonates nor deflagrates at all and shows low or no effect when heated under confinement will be defined as self-reactive substance TYPE E; (f) Any self-reactive substance or mixture which, in laboratory testing, neither detonates in the cavitated state nor deflagrates at all and shows only a low or no effect when heated under confinement as w ell as low or no explosive power will be defined as self-reactive substance TYPE F; (g) Any self-reactive substance or mixture which, in laboratory testing, neither detonates in the cavitated state nor deflagrates at all and shows no effect when heated under confinement nor any explosive power, provided that it is thermally stable (self-accelerating decomposition temperature is 60°C to 75°C for a 50 kg package),and,for liquid mixtures, a diluent having a boiling point greater than or equal to 150°C is used for desensitization will be defined as self-reactive substance TYPE G. I f the mixture is not thermally stable or a diluent having a boiling point less than 150°C is used for desensitization, the mixture shall be defined as self-reactive substance TYPE F. NOTE 1: Type G has no hazard communication elements assigned but should be considered for properties belonging to other hazard classes. NOTE 2: Types A to G may not be necessary for all systems. 58
2.8.2.3 Criteria for temperature control Self-reactive substances need to be subjected to temperature control if their self-accelerating decomposition temperature (SADT) is less than or equal to 55℃.Test methods for determining the SADT as well as the derivation of control and emergency temperatures are given in the UN Recommendations for the Transport of Dangerous Goods, Manual of Tests and Criteria, Part II , section 28. The test selected shall be conducted in a manner which is representative, both in size and material, of the package. (3)Guidance for Classification A) Judgment of Not applicable 1)Gas, explosives, organic peroxides, and liquids and solid classified as oxidizing substances shall be “Not applicable”. 2)Substances not containing chemical groups related to explosibility or self-reactivity shall be “Not applicable”. B)Judgment of Not Classified Regarding the substances containing chemical groups related to explosibility or self-reactivity, if data on SADT or exothermic decomposition are obtained from prescribed review documents and the guidance of 2.8.2.1(d)(e) in the UN GHS second revised edition is applicable to the substances, fill in “Classification result” with “Not classified”, and fill in “Classification Grounds and Problems” with “SADT ** °C” (** is filled with a specific value). C) Classification based on TDG Classification etc If the name of a substance is included in TDG classification, the substance shall be classified according to it. Pure substances of some transport-prohibited substances listed in “Notice to settle Transportation Standards and the like of Dangerous Goods by Ship”, Article 5 (1) to (4), based on the Dangerous Goods Regulations, Article 7 (1), belong to the self-reactive substance TYPE A. However, they shall be classified into those containing a required stabilization agent, not into TYPE A. Substances that cannot be classified by the procedure mentioned above shall be classified as “Classification not possible”. (4)Data availability Few measurement data related to the flow chart have been published. Mostly, self-reactive substances are traded and used as prepared chemicals in which diluents and/or stabilizing agents are added to them, rather than as pure substances. Classification into TYPE A to G should be made based on a test for individual prepared chemicals. 59
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GHS Classification Guidance for the
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2-3-12 Substances and mixtures whic
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Japanese judgments and consideratio
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(2) Points to remember when describ
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① ② Information Gathering Class
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Page 21 and 22: guidelines can be compared with GHS
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Page 25 and 26: When a substance does not contain c
Page 27 and 28: Table 2-2 Filled examples of "Not a
Page 29 and 30: oxygen balance = -1600 [2x +(y/2) -
Page 31 and 32: GHS classification 8)Self-reactive
Page 33 and 34: The “Dangerous Goods Regulations,
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Page 37 and 38: Table 2-5 Filled examples of “Cla
Page 39 and 40: explosion hazard: (i) combustion of
Page 41 and 42: water, by mass (n)GUANYLNITROSAMINO
Page 43 and 44: substance 0224 BARIUM AZIDE, dry or
Page 45 and 46: 1337 NITROSTARCH, WETTED with not l
Page 47 and 48: (4) Data availability Physical prop
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Page 51 and 52: Nitrogen trifluoride C і = 1.6 Nit
Page 53 and 54: 2-3-5 Gases Under Pressure (1)Defin
Page 55 and 56: 2-3-6 Flammable Liquids (1)Definiti
Page 57 and 58: Category 3 =UNRTDG3 III Category 4
Page 59 and 60: Table 2.7.1: Criteria for flammable
Page 61: 2-3-8 Self-reactive Substances and
Page 65 and 66: 3225 There is no article with a spe
Page 67 and 68: classified according to it. If not,
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Page 71 and 72: Table 2.11.1: Criteria for self-hea
Page 73 and 74: than 30% water of crystallization 1
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Page 77 and 78: 138: Water-reactive substances - em
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Page 81 and 82: 2-3-13 Oxidizing Liquids (1)Definit
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Page 85 and 86: (Example of category 3)2067 AMMONIU
Page 87 and 88: this class, according to the follow
Page 89 and 90: The flow chart of 2.15.2.2 is exact
Page 91 and 92: 2-3-16 Corrosive to Metals (1)Defin
Page 93: Note: In GHS, it is defined that if
Page 96 and 97: 1-1) Organization National Institut
Page 98 and 99: URL http://www.ecetoc.org/publicati
Page 100 and 101: List 2: Useful information sources
Page 102 and 103: http://www.cdc.gov/niosh/npg/npgdrt
Page 104 and 105: 3-1-3 Management of information in
Page 106 and 107: Relation between concentration(ppm)
Page 108 and 109: follows: Category 1 (100 ppmV), Cat
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UNRTDG Class 6.1 is not sub-categor
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possible” unless the obvious conc
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whereas the reference value is set
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3-2-2 Skin Corrosion/Irritation (1)
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Table 3.2.2 Skin irritation categor
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possible, and to classify the subst
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and scaling persist to the end of 1
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【GHS 2 nd revised edition】 Figu
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[Note for the above figure] (a) Cla
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B) Classification criteria in GHS (
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(4)Guidance for classification and
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G) Strategy of testing and evaluati
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2c Structure activity Skin corrosiv
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done in parallel. This stage should
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criteria given below:” a) If ther
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[Decision Criteria 1]: In the cases
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substance shall be classified in Ca
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The classification is based on any
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7) Data from various kinds of tests
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Table 3-8 Test data as the basis of
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Category 1B. Mutagens classified a
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c)Exceptionally, strong positive re
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3-2-6 Carcinogenicity (1)Definition
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The principles of GHS classificatio
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B) Substance for which GHS classifi
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metabolic system, a cautious invest
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hazard warning for pregnant women a
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OECD414 Prenatal development toxici
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D) Decision logic and classificatio
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e considered to be sufficient. (Sub
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No. Test guideline Limit dose 414 P
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3-2-8 Specific Target Organ Toxicit
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specifically for these effects as d
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existing MSDSs. A literature search
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* Unless a description that definit
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g) When the affected organ can be i
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3-2-9 Specific Target Organ Toxicit
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Table 3-16: Guidance value ranges f
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(c) Any consistent and significant
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has received some degree of approva
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As for the classification of specif
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formed in the mouth, which then may
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The classification criteria refer t
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194
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(1)Sources for test data for Hazard
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List 2: Useful information sources
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3-3)EU classification When classif
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4-2 Classification of Hazardous to
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water solubility, and which are not
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Tests shall be conducted by using f
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e categorized based on chronic aqua
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endpoint. When it is not clear whet
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that the relevant information sourc
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214
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R39 Danger of very serious irrevers
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R52 Harmful to aquatic organisms. R
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GHS Classification Guidance for the Japanese Government

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