GHS Classification Guidance for the Japanese Government

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0113 GUANYL-NITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass 0114 GUANYL-NITROSAMINOGUANYLTETRAZENE(TETRAZENE), WETTED with not less than 30% water, or mixture of alcohol and water, by mass 0118 HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass 0129 LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0130 LEAD STYPHNATE (LEAD TRINITRORESORCINATE), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0133 MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40% water, or mixture of alcohol and water, by mass 0143 NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile waterinsoluble phlegmatizer, by mass 0146 NITROSTARCH, dry or wetted with less than 20% water, by mass 0147 NITRO UREA 0150 PENTAERYTHRITE TETRANITRATE(PENTAERYTHRITOL TETRANITRATE; PETN, wetted with not less than 25% water, by mass, or desensitized with not less than 15% phlegmatizer, by mass 0151 PENTOLITE, dry or wetted with less than 15% water, by mass 0153 TRINITROANILINE (PICRAMIDE) 0154 TRINITROPHENOL (PICRIC ACID), dry or wetted with less than 30% water, by mass 0155 TRINITROCHLOROBENZENE(PICRYL CHLORIDE) 0207 TETRANITROANILINE 0208 TRINITROPHENYLMETHYLNITRAMINE(TETRYL) 0209 TRINITROTOLUENE (TNT), dry or wetted with less than 30% water, by mass 0213 TRINITROANISOLE 0214 TRINITROBENZENE, dry or wetted with less than 30% water, by mass 0215 TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass 0216 TRINITRO-m-CRESOL 0217 TRINITRONAPHTHALENE 0218 TRINITROPHENETOLE 0219 TRINITRORESORCINOL (STYPHNICACID), dry or wetted with less than 20% water, or mixture of alcohol and water, by mass 0220 UREA NITRATE, dry or wetted with less than 20% water, by mass 0222 AMMONIUM NITRATE with more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added 38
substance 0224 BARIUM AZIDE, dry or wetted with less than 50% water, by mass 0226 CYCLOTETRAMETHYLENETETRANITRAMINE(HMX; OCTOGEN),WETTED with not less than 15% water,by mass 0266 OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass 0282 NITROGUANIDINE (PICRITE), dry or wetted with less than 20% water, by mass 0340 NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass 0341 NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass 0385 5-NITROBENZOTRIAZOL 0386 TRINITROBENZENESULPHONIC ACID 0387 TRINITROFLUORENONE 0390 TRITONAL 0392 HEXANITROSTILBENE 0393 HEXOTONAL 0394 TRINITRORESORCINOL (STYPHNICACID), WETTED with not less than 20% water, or mixture of alcohol and water, by mass 0402 AMMONIUM PERCHLORATE 0483 CYCLOTRIMETHYLENETRINITRAMINE(CYCLONITE; HEXOGEN;RDX), DESENSITIZED 0484 CYCLOTETRAMETHYLENETETRANITRAMINE(HMX; OCTOGEN), DESENSITIZED 0489 DINITROGLYCOLURIL (DINGU) 0490 NITROTRIAZOLONE (NTO) 0496 OCTONAL 0504 1H-TETRAZOLE Division 1.2 =UNRTDG1.2 At present, only articles have UN numbers, but substances may be included in accordance with the definition. Division 1.3 =UNRTDG1.3 0161 POWDER, SMOKELESS 0234 SODIUM DINITRO-o-CRESOLATE, dry or wetted with less than 15% water, by mass 39
Page 1: GHS Classification Guidance for the
Page 4 and 5: 2-3-12 Substances and mixtures whic
Page 6 and 7: Japanese judgments and consideratio
Page 8 and 9: (2) Points to remember when describ
Page 10 and 11: ① ② Information Gathering Class
Page 13 and 14: Part2. Physical Hazards Guidance 2-
Page 15 and 16: described in the next section is of
Page 17 and 18: Information in the book can be sear
Page 19 and 20: (8) International Chemical Safety C
Page 21 and 22: guidelines can be compared with GHS
Page 23 and 24: “Liquids” are defined as substa
Page 25 and 26: When a substance does not contain c
Page 27 and 28: Table 2-2 Filled examples of "Not a
Page 29 and 30: oxygen balance = -1600 [2x +(y/2) -
Page 31 and 32: GHS classification 8)Self-reactive
Page 33 and 34: The “Dangerous Goods Regulations,
Page 35 and 36: 4.2 4.3 5.1(I) 5.1(II) 5.1(III) 6.1
Page 37 and 38: Table 2-5 Filled examples of “Cla
Page 39 and 40: explosion hazard: (i) combustion of
Page 41: water, by mass (n)GUANYLNITROSAMINO
Page 45 and 46: 1337 NITROSTARCH, WETTED with not l
Page 47 and 48: (4) Data availability Physical prop
Page 49 and 50: flame distance (ignition distance)
Page 51 and 52: Nitrogen trifluoride C і = 1.6 Nit
Page 53 and 54: 2-3-5 Gases Under Pressure (1)Defin
Page 55 and 56: 2-3-6 Flammable Liquids (1)Definiti
Page 57 and 58: Category 3 =UNRTDG3 III Category 4
Page 59 and 60: Table 2.7.1: Criteria for flammable
Page 61 and 62: 2-3-8 Self-reactive Substances and
Page 63 and 64: 2.8.2.3 Criteria for temperature co
Page 65 and 66: 3225 There is no article with a spe
Page 67 and 68: classified according to it. If not,
Page 69 and 70: classified”. Reference: UN GHS se
Page 71 and 72: Table 2.11.1: Criteria for self-hea
Page 73 and 74: than 30% water of crystallization 1
Page 75 and 76: transport, the same chemical is to
Page 77 and 78: 138: Water-reactive substances - em
Page 79 and 80: orohydrides, alkyl compounds, etc.)
Page 81 and 82: 2-3-13 Oxidizing Liquids (1)Definit
Page 83 and 84: 2-1-14 Oxidizing Solids (1)Definiti
Page 85 and 86: (Example of category 3)2067 AMMONIU
Page 87 and 88: this class, according to the follow
Page 89 and 90: The flow chart of 2.15.2.2 is exact
Page 91 and 92: 2-3-16 Corrosive to Metals (1)Defin
Page 93:
Note: In GHS, it is defined that if
Page 96 and 97:
1-1) Organization National Institut
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URL http://www.ecetoc.org/publicati
Page 100 and 101:
List 2: Useful information sources
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http://www.cdc.gov/niosh/npg/npgdrt
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3-1-3 Management of information in
Page 106 and 107:
Relation between concentration(ppm)
Page 108 and 109:
follows: Category 1 (100 ppmV), Cat
Page 110 and 111:
(ii) the appropriate conversion val
Page 112 and 113:
UNRTDG Class 6.1 is not sub-categor
Page 114 and 115:
possible” unless the obvious conc
Page 116 and 117:
whereas the reference value is set
Page 118 and 119:
3-2-2 Skin Corrosion/Irritation (1)
Page 120 and 121:
Table 3.2.2 Skin irritation categor
Page 122 and 123:
possible, and to classify the subst
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and scaling persist to the end of 1
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【GHS 2 nd revised edition】 Figu
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[Note for the above figure] (a) Cla
Page 130 and 131:
B) Classification criteria in GHS (
Page 132 and 133:
(4)Guidance for classification and
Page 134 and 135:
G) Strategy of testing and evaluati
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2c Structure activity Skin corrosiv
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done in parallel. This stage should
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criteria given below:” a) If ther
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[Decision Criteria 1]: In the cases
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substance shall be classified in Ca
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The classification is based on any
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7) Data from various kinds of tests
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Table 3-8 Test data as the basis of
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Category 1B. Mutagens classified a
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c)Exceptionally, strong positive re
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3-2-6 Carcinogenicity (1)Definition
Page 158 and 159:
The principles of GHS classificatio
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B) Substance for which GHS classifi
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metabolic system, a cautious invest
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hazard warning for pregnant women a
Page 166 and 167:
OECD414 Prenatal development toxici
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D) Decision logic and classificatio
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e considered to be sufficient. (Sub
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No. Test guideline Limit dose 414 P
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3-2-8 Specific Target Organ Toxicit
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specifically for these effects as d
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existing MSDSs. A literature search
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* Unless a description that definit
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g) When the affected organ can be i
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3-2-9 Specific Target Organ Toxicit
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Table 3-16: Guidance value ranges f
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(c) Any consistent and significant
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has received some degree of approva
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As for the classification of specif
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formed in the mouth, which then may
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The classification criteria refer t
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194
Page 200 and 201:
(1)Sources for test data for Hazard
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List 2: Useful information sources
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3-3)EU classification When classif
Page 206 and 207:
4-2 Classification of Hazardous to
Page 208 and 209:
water solubility, and which are not
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Tests shall be conducted by using f
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e categorized based on chronic aqua
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endpoint. When it is not clear whet
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that the relevant information sourc
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214
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R39 Danger of very serious irrevers
Page 222:
R52 Harmful to aquatic organisms. R
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GHS Classification Guidance for the Japanese Government

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