GHS Classification Guidance for the Japanese Government
GHS Classification Guidance for the Japanese Government GHS Classification Guidance for the Japanese Government
“Classification result” shall be “Not classified”, and “Desensitized Explosives” shall indicated for “Classification Grounds”. Test data under the “Explosives Control Law” or the “Fire Defense Law, Class 5 Dangerous Goods” both of which adopted test methods of the UN (although partially), may be used for classification after comparison with GHS test methods and close examination. (4) Data availability The performance of explosives depends on their composition, and data regarding explosive performance of each substance are limited. (5) Comparison with conventional classification systems Divisions 1.1-1.6 described above follow the definition of Divisions of UNRTDG 2.1.1.4. (6) Sources of information for classification results under conventional systems The UNRTDG list of dangerous goods (adopted into Annex 1: Dangerous Goods Regulations) includes the following substance. ●Unstable explosives: explosive substances and articles, whose transportation is prohibited. The following explosives shown in 1979, the Ministry of Transportation Notice No. 549, “Notice to settle Transportation Standards and the like of Dangerous Goods by Ship”, Article 5 (1), are deemed as unstable explosives. (a)AMMONIUM BROMATE (b)AMMONIUM BROMATE SOLUTION (c)AMMONIUM CHLORATE (d)AMMONIUM CHLORATE SOLUTION (e)AMMONIUM CHLORITE (f)AMMONIUM NITRATE (excluding those listed in Annex 1) (g)AMMONIUM NITRITE (h)Mixture of INORGANIC NITROUS ACID and AMMONIUM SALT (i)SILVER PICRATE, WETTED with not less than 30% water, by mass (j)CYCLOTRIMETHYLENETRINITRAMINE(CYCLONITE, RDX), WETTED with less than 15% water, by mass (k)DIAZODINITROPHENOL, WETTED with less than 40% water, or mixture of alcohol and water, by mass (l)DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with less than 25% non-volatile, water-insoluble phlegmatizer, by mass (m)GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with less than 30% 36
water, by mass (n)GUANYLNITROSAMINOGUANYLTETRAZENE, WETTED with less than 30% water, or mixture of alcohol and water, by mass (o)LEAD AZIDE, WETTED with less than 20% water, or mixture of alcohol and water, by mass (p)LEAD STYPHNATE, WETTED with less than 20% water, or mixture of alcohol and water, by mass (q)MANNITOL HEXANITRATE, WETTED with less than 40% water, or mixture of alcohol and water, by mass (r)MERCURY FULMINATE, WETTED with less than 20% water, or mixture of alcohol and water, by mass (s)NITROGLYCERIN, DESENSITIZED with less than 40% non-volatile water-insoluble phlegmatizer, by mass (t)PENTAERYTHRITETETRANITRATE, WETTED with less than 25% water, by mass, DESENSITIZED with less than 15% phlegmatizer, by mass (u)POWDER CAKE, WETTED with less than 17% alcohol, less than 25% water, by mass (v)CYCLOTETRAMETHYLENETETRANITRAMINE, WETTED with less than 15% water, by mass (w)CYCLOTRIMETHYLENETRINITRAMINE AND CYCLOTETRAMETHYLENETETRANITRAMINE MIXTURE, WETTED with less than 15% water, by mass Division 1.1 =UNRTDG1.1 UNNo. Substance name 0004 AMMONIUM PICRATE dry or wetted with less than 10% water, by mass 0028 BLACK POWDER (GUNPOWDER),COMPRESSED or BLACK POWDER(GUNPOWDER), IN PELLETS 0072 CYCLOTRIMETHYLENETRINITRAMINE(CYCLONITE; HEXOGEN; RDX), WETTED with not less than 15% water, by mass 0074 DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass 0075 DIETHYLENEGLYCOL DINITRATE,DESENSITIZED with not less than 25% non-volatile, water-insoluble phlegmatizer,by mass 0076 DINITROPHENOL, dry or wetted with less than 15% water, by mass 0077 DINITROPHENOLATES, alkali metals,dry or wetted with less than 15% water, by mass 0078 DINITRORESORCINOL, dry or wetted with less than 15% water, by mass 0079 HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL) 37
- Page 1: GHS Classification Guidance for the
- Page 4 and 5: 2-3-12 Substances and mixtures whic
- Page 6 and 7: Japanese judgments and consideratio
- Page 8 and 9: (2) Points to remember when describ
- Page 10 and 11: ① ② Information Gathering Class
- Page 13 and 14: Part2. Physical Hazards Guidance 2-
- Page 15 and 16: described in the next section is of
- Page 17 and 18: Information in the book can be sear
- Page 19 and 20: (8) International Chemical Safety C
- Page 21 and 22: guidelines can be compared with GHS
- Page 23 and 24: “Liquids” are defined as substa
- Page 25 and 26: When a substance does not contain c
- Page 27 and 28: Table 2-2 Filled examples of "Not a
- Page 29 and 30: oxygen balance = -1600 [2x +(y/2) -
- Page 31 and 32: GHS classification 8)Self-reactive
- Page 33 and 34: The “Dangerous Goods Regulations,
- Page 35 and 36: 4.2 4.3 5.1(I) 5.1(II) 5.1(III) 6.1
- Page 37 and 38: Table 2-5 Filled examples of “Cla
- Page 39: explosion hazard: (i) combustion of
- Page 43 and 44: substance 0224 BARIUM AZIDE, dry or
- Page 45 and 46: 1337 NITROSTARCH, WETTED with not l
- Page 47 and 48: (4) Data availability Physical prop
- Page 49 and 50: flame distance (ignition distance)
- Page 51 and 52: Nitrogen trifluoride C і = 1.6 Nit
- Page 53 and 54: 2-3-5 Gases Under Pressure (1)Defin
- Page 55 and 56: 2-3-6 Flammable Liquids (1)Definiti
- Page 57 and 58: Category 3 =UNRTDG3 III Category 4
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- Page 63 and 64: 2.8.2.3 Criteria for temperature co
- Page 65 and 66: 3225 There is no article with a spe
- Page 67 and 68: classified according to it. If not,
- Page 69 and 70: classified”. Reference: UN GHS se
- Page 71 and 72: Table 2.11.1: Criteria for self-hea
- Page 73 and 74: than 30% water of crystallization 1
- Page 75 and 76: transport, the same chemical is to
- Page 77 and 78: 138: Water-reactive substances - em
- Page 79 and 80: orohydrides, alkyl compounds, etc.)
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- Page 85 and 86: (Example of category 3)2067 AMMONIU
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“<strong>Classification</strong> result” shall be “Not classified”, and “Desensitized Explosives” shall<br />
indicated <strong>for</strong> “<strong>Classification</strong> Grounds”.<br />
Test data under <strong>the</strong> “Explosives Control Law” or <strong>the</strong> “Fire Defense Law, Class 5<br />
Dangerous Goods” both of which adopted test methods of <strong>the</strong> UN (although partially),<br />
may be used <strong>for</strong> classification after comparison with <strong>GHS</strong> test methods and close<br />
examination.<br />
(4) Data availability<br />
The per<strong>for</strong>mance of explosives depends on <strong>the</strong>ir composition, and data regarding explosive<br />
per<strong>for</strong>mance of each substance are limited.<br />
(5) Comparison with conventional classification systems<br />
Divisions 1.1-1.6 described above follow <strong>the</strong> definition of Divisions of UNRTDG 2.1.1.4.<br />
(6) Sources of in<strong>for</strong>mation <strong>for</strong> classification results under conventional systems<br />
The UNRTDG list of dangerous goods (adopted into Annex 1: Dangerous Goods Regulations)<br />
includes <strong>the</strong> following substance.<br />
●Unstable explosives: explosive substances and articles, whose transportation is prohibited.<br />
The following explosives shown in 1979, <strong>the</strong> Ministry of Transportation Notice No. 549,<br />
“Notice to settle Transportation Standards and <strong>the</strong> like of Dangerous Goods by Ship”, Article 5 (1),<br />
are deemed as unstable explosives.<br />
(a)AMMONIUM BROMATE<br />
(b)AMMONIUM BROMATE SOLUTION<br />
(c)AMMONIUM CHLORATE<br />
(d)AMMONIUM CHLORATE SOLUTION<br />
(e)AMMONIUM CHLORITE<br />
(f)AMMONIUM NITRATE (excluding those listed in Annex 1)<br />
(g)AMMONIUM NITRITE<br />
(h)Mixture of INORGANIC NITROUS ACID and AMMONIUM SALT<br />
(i)SILVER PICRATE, WETTED with not less than 30% water, by mass<br />
(j)CYCLOTRIMETHYLENETRINITRAMINE(CYCLONITE, RDX), WETTED with less than<br />
15% water, by mass<br />
(k)DIAZODINITROPHENOL, WETTED with less than 40% water, or mixture of alcohol and<br />
water, by mass<br />
(l)DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with less than 25% non-volatile,<br />
water-insoluble phlegmatizer, by mass<br />
(m)GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with less than 30%<br />
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