GHS Classification Guidance for the Japanese Government

GHS Classification Guidance for the Japanese Government GHS Classification Guidance for the Japanese Government

04.06.2013 Views

Classification result” shall be “Not classified”, and “Desensitized Explosives” shall indicated forClassification Grounds”. Test data under the “Explosives Control Law” or the “Fire Defense Law, Class 5 Dangerous Goods” both of which adopted test methods of the UN (although partially), may be used for classification after comparison with GHS test methods and close examination. (4) Data availability The performance of explosives depends on their composition, and data regarding explosive performance of each substance are limited. (5) Comparison with conventional classification systems Divisions 1.1-1.6 described above follow the definition of Divisions of UNRTDG 2.1.1.4. (6) Sources of information for classification results under conventional systems The UNRTDG list of dangerous goods (adopted into Annex 1: Dangerous Goods Regulations) includes the following substance. ●Unstable explosives: explosive substances and articles, whose transportation is prohibited. The following explosives shown in 1979, the Ministry of Transportation Notice No. 549, “Notice to settle Transportation Standards and the like of Dangerous Goods by Ship”, Article 5 (1), are deemed as unstable explosives. (a)AMMONIUM BROMATE (b)AMMONIUM BROMATE SOLUTION (c)AMMONIUM CHLORATE (d)AMMONIUM CHLORATE SOLUTION (e)AMMONIUM CHLORITE (f)AMMONIUM NITRATE (excluding those listed in Annex 1) (g)AMMONIUM NITRITE (h)Mixture of INORGANIC NITROUS ACID and AMMONIUM SALT (i)SILVER PICRATE, WETTED with not less than 30% water, by mass (j)CYCLOTRIMETHYLENETRINITRAMINE(CYCLONITE, RDX), WETTED with less than 15% water, by mass (k)DIAZODINITROPHENOL, WETTED with less than 40% water, or mixture of alcohol and water, by mass (l)DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with less than 25% non-volatile, water-insoluble phlegmatizer, by mass (m)GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with less than 30% 36

water, by mass (n)GUANYLNITROSAMINOGUANYLTETRAZENE, WETTED with less than 30% water, or mixture of alcohol and water, by mass (o)LEAD AZIDE, WETTED with less than 20% water, or mixture of alcohol and water, by mass (p)LEAD STYPHNATE, WETTED with less than 20% water, or mixture of alcohol and water, by mass (q)MANNITOL HEXANITRATE, WETTED with less than 40% water, or mixture of alcohol and water, by mass (r)MERCURY FULMINATE, WETTED with less than 20% water, or mixture of alcohol and water, by mass (s)NITROGLYCERIN, DESENSITIZED with less than 40% non-volatile water-insoluble phlegmatizer, by mass (t)PENTAERYTHRITETETRANITRATE, WETTED with less than 25% water, by mass, DESENSITIZED with less than 15% phlegmatizer, by mass (u)POWDER CAKE, WETTED with less than 17% alcohol, less than 25% water, by mass (v)CYCLOTETRAMETHYLENETETRANITRAMINE, WETTED with less than 15% water, by mass (w)CYCLOTRIMETHYLENETRINITRAMINE AND CYCLOTETRAMETHYLENETETRANITRAMINE MIXTURE, WETTED with less than 15% water, by mass Division 1.1 =UNRTDG1.1 UNNo. Substance name 0004 AMMONIUM PICRATE dry or wetted with less than 10% water, by mass 0028 BLACK POWDER (GUNPOWDER),COMPRESSED or BLACK POWDER(GUNPOWDER), IN PELLETS 0072 CYCLOTRIMETHYLENETRINITRAMINE(CYCLONITE; HEXOGEN; RDX), WETTED with not less than 15% water, by mass 0074 DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass 0075 DIETHYLENEGLYCOL DINITRATE,DESENSITIZED with not less than 25% non-volatile, water-insoluble phlegmatizer,by mass 0076 DINITROPHENOL, dry or wetted with less than 15% water, by mass 0077 DINITROPHENOLATES, alkali metals,dry or wetted with less than 15% water, by mass 0078 DINITRORESORCINOL, dry or wetted with less than 15% water, by mass 0079 HEXANITRODIPHENYLAMINE (DIPICRYLAMINE; HEXYL) 37

“<strong>Classification</strong> result” shall be “Not classified”, and “Desensitized Explosives” shall<br />

indicated <strong>for</strong> “<strong>Classification</strong> Grounds”.<br />

Test data under <strong>the</strong> “Explosives Control Law” or <strong>the</strong> “Fire Defense Law, Class 5<br />

Dangerous Goods” both of which adopted test methods of <strong>the</strong> UN (although partially),<br />

may be used <strong>for</strong> classification after comparison with <strong>GHS</strong> test methods and close<br />

examination.<br />

(4) Data availability<br />

The per<strong>for</strong>mance of explosives depends on <strong>the</strong>ir composition, and data regarding explosive<br />

per<strong>for</strong>mance of each substance are limited.<br />

(5) Comparison with conventional classification systems<br />

Divisions 1.1-1.6 described above follow <strong>the</strong> definition of Divisions of UNRTDG 2.1.1.4.<br />

(6) Sources of in<strong>for</strong>mation <strong>for</strong> classification results under conventional systems<br />

The UNRTDG list of dangerous goods (adopted into Annex 1: Dangerous Goods Regulations)<br />

includes <strong>the</strong> following substance.<br />

●Unstable explosives: explosive substances and articles, whose transportation is prohibited.<br />

The following explosives shown in 1979, <strong>the</strong> Ministry of Transportation Notice No. 549,<br />

“Notice to settle Transportation Standards and <strong>the</strong> like of Dangerous Goods by Ship”, Article 5 (1),<br />

are deemed as unstable explosives.<br />

(a)AMMONIUM BROMATE<br />

(b)AMMONIUM BROMATE SOLUTION<br />

(c)AMMONIUM CHLORATE<br />

(d)AMMONIUM CHLORATE SOLUTION<br />

(e)AMMONIUM CHLORITE<br />

(f)AMMONIUM NITRATE (excluding those listed in Annex 1)<br />

(g)AMMONIUM NITRITE<br />

(h)Mixture of INORGANIC NITROUS ACID and AMMONIUM SALT<br />

(i)SILVER PICRATE, WETTED with not less than 30% water, by mass<br />

(j)CYCLOTRIMETHYLENETRINITRAMINE(CYCLONITE, RDX), WETTED with less than<br />

15% water, by mass<br />

(k)DIAZODINITROPHENOL, WETTED with less than 40% water, or mixture of alcohol and<br />

water, by mass<br />

(l)DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with less than 25% non-volatile,<br />

water-insoluble phlegmatizer, by mass<br />

(m)GUANYLNITROSAMINOGUANYLIDENE HYDRAZINE, WETTED with less than 30%<br />

36

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