GHS Classification Guidance for the Japanese Government

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R39 Danger of very serious irreversible effects. R39/23 Toxic: danger of very serious irreversible effects through inhalation. R39/24 Toxic: danger of very serious irreversible effects in contact with skin. R39/25 Toxic: danger of very serious irreversible effects if swallowed. R39/23/24 R39/23/25 R39/24/25 R39/23/24/25 R39/26 R39/27 Toxic: danger of very serious irreversible effects through inhalation and in contact with skin. Toxic: danger of very serious irreversible effects through inhalation and if swallowed. Toxic: danger of very serious irreversible effects in contact with skin and if swallowed. Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Very toxic: danger of very serious irreversible effects through inhalation. Very toxic: danger of very serious irreversible effects in contact with skin. R39/28 Very toxic: danger of very serious irreversible effects if swallowed. R40 Limited evidence of a carcinogenic effect R41 Risk of serious damage to eyes. R42 May cause sensitization by inhalation. R42/43 May cause sensitization by inhalation and skin contact. R43 May cause sensitization by skin contact. R45 May cause cancer. R46 May cause heritable genetic damage. R48 Danger of serious damage to health by prolonged exposure. 216
R48/20 R48/21 R48/22 R48/20/21 R48/20/22 R48/21/22 R48/20/21/22 R48/23 R48/24 R48/25 R48/23/24 R48/23/25 R48/24/25 Harmful: danger of serious damage to health by prolonged exposure through inhalation. Harmful: danger of serious damage to health by prolonged exposure in contact with skin. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin. Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Toxic: danger of serious damage to health by prolonged exposure through inhalation. Toxic: danger of serious damage to health by prolonged exposure in contact with skin. Toxic: danger of serious damage to health by prolonged exposure if swallowed. Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin. Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. R49 May cause cancer by inhalation. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in <strong>the</strong> aquatic environment. R51 Toxic to aquatic organisms. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in <strong>the</strong> aquatic environment. 217
Page 1:
GHS Classification Guidance for the
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2-3-12 Substances and mixtures whic
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Japanese judgments and consideratio
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(2) Points to remember when describ
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① ② Information Gathering Class
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Part2. Physical Hazards Guidance 2-
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described in the next section is of
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Information in the book can be sear
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(8) International Chemical Safety C
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guidelines can be compared with GHS
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“Liquids” are defined as substa
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When a substance does not contain c
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Table 2-2 Filled examples of "Not a
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oxygen balance = -1600 [2x +(y/2) -
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GHS classification 8)Self-reactive
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The “Dangerous Goods Regulations,
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4.2 4.3 5.1(I) 5.1(II) 5.1(III) 6.1
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Table 2-5 Filled examples of “Cla
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explosion hazard: (i) combustion of
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water, by mass (n)GUANYLNITROSAMINO
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substance 0224 BARIUM AZIDE, dry or
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1337 NITROSTARCH, WETTED with not l
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(4) Data availability Physical prop
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flame distance (ignition distance)
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Nitrogen trifluoride C і = 1.6 Nit
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2-3-5 Gases Under Pressure (1)Defin
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2-3-6 Flammable Liquids (1)Definiti
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Category 3 =UNRTDG3 III Category 4
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Table 2.7.1: Criteria for flammable
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2-3-8 Self-reactive Substances and
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2.8.2.3 Criteria for temperature co
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3225 There is no article with a spe
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classified according to it. If not,
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classified”. Reference: UN GHS se
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Table 2.11.1: Criteria for self-hea
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than 30% water of crystallization 1
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transport, the same chemical is to
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138: Water-reactive substances - em
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orohydrides, alkyl compounds, etc.)
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2-3-13 Oxidizing Liquids (1)Definit
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2-1-14 Oxidizing Solids (1)Definiti
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(Example of category 3)2067 AMMONIU
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this class, according to the follow
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The flow chart of 2.15.2.2 is exact
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2-3-16 Corrosive to Metals (1)Defin
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Note: In GHS, it is defined that if
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1-1) Organization National Institut
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URL http://www.ecetoc.org/publicati
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List 2: Useful information sources
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http://www.cdc.gov/niosh/npg/npgdrt
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3-1-3 Management of information in
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Relation between concentration(ppm)
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follows: Category 1 (100 ppmV), Cat
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(ii) the appropriate conversion val
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UNRTDG Class 6.1 is not sub-categor
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possible” unless the obvious conc
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whereas the reference value is set
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3-2-2 Skin Corrosion/Irritation (1)
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Table 3.2.2 Skin irritation categor
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possible, and to classify the subst
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and scaling persist to the end of 1
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【GHS 2 nd revised edition】 Figu
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[Note for the above figure] (a) Cla
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B) Classification criteria in GHS (
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(4)Guidance for classification and
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G) Strategy of testing and evaluati
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2c Structure activity Skin corrosiv
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done in parallel. This stage should
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criteria given below:” a) If ther
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[Decision Criteria 1]: In the cases
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substance shall be classified in Ca
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The classification is based on any
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7) Data from various kinds of tests
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Table 3-8 Test data as the basis of
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Category 1B. Mutagens classified a
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c)Exceptionally, strong positive re
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3-2-6 Carcinogenicity (1)Definition
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The principles of GHS classificatio
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B) Substance for which GHS classifi
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metabolic system, a cautious invest
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hazard warning for pregnant women a
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OECD414 Prenatal development toxici
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D) Decision logic and classificatio
Page 170 and 171: e considered to be sufficient. (Sub
Page 172 and 173: No. Test guideline Limit dose 414 P
Page 174 and 175: 3-2-8 Specific Target Organ Toxicit
Page 176 and 177: specifically for these effects as d
Page 178 and 179: existing MSDSs. A literature search
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Page 182 and 183: g) When the affected organ can be i
Page 184 and 185: 3-2-9 Specific Target Organ Toxicit
Page 186 and 187: Table 3-16: Guidance value ranges f
Page 188 and 189: (c) Any consistent and significant
Page 190 and 191: has received some degree of approva
Page 192 and 193: As for the classification of specif
Page 194 and 195: formed in the mouth, which then may
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Page 200 and 201: (1)Sources for test data for Hazard
Page 202 and 203: List 2: Useful information sources
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Page 206 and 207: 4-2 Classification of Hazardous to
Page 208 and 209: water solubility, and which are not
Page 210 and 211: Tests shall be conducted by using f
Page 212 and 213: e categorized based on chronic aqua
Page 214 and 215: endpoint. When it is not clear whet
Page 216 and 217: that the relevant information sourc
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Page 222: R52 Harmful to aquatic organisms. R
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GHS Classification Guidance for the Japanese Government

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