GHS Classification Guidance for the Japanese Government

GHS Classification Guidance for the Japanese Government GHS Classification Guidance for the Japanese Government

04.06.2013 Views

The classification criteria refer to kinematic viscosity. The conversion formula between dynamic viscosity and kinematic viscosity is indicated below. Dynamic viscosity (mPa・s) / Density (g/cm 3 ) = Kinematic viscosity (mm 2 /s) (4)Guidance for classification and judgment A) Background of this item and points to be noted As for background of this item, refer to Part 1, Introduction. In classification, take the following points into account. * Unless a description that definitely denies hazards or recognizes extremely low hazards is available in List 1, the determination of “Not classified” should be performed carefully. If there is any question, a given substance should rather be classified in “Classification not possible” due to insufficient information for judgment. * If data are available only for a mixture, the mixture itself is classified, and this shall be stated in "Grounds". B)Regarding classification procedure 1) A substance meeting [Decision Criteria 1a] or [Decision Criteria 1b] shall be placed in Category 1. [Decision Criteria 1a]: A document in List 1 or List 2 contains a description to the effect that human chemical pneumonia was caused by accidental aspiration. (Note) a) Any kinematic viscosity shall not be considered. b) Liquids and solids, not gases, are subject to classification. Since aspiration hazard concerns, not aspiration of substances suspended in gas phase, accidental aspiration of liquids and solids, aerosol/dust/mist substances are judged by referring to the UN GHS second revised edition 3.10.1.6.4 and considering nature of substances, performance of the containers in which the substances are provided (spray can, etc.), etc. (Substances aspirated into respiratory tract/respiratory system while suspended in gas phase are placed in “Not applicable”.). [Decision Criteria 1b]: A substance which is a hydrocarbon and has kinematic viscosity of 20.5 mm 2 /s or less at 40℃. (Note) a) The existence or absence of human evidence shall not be considered. b) Viscosity depends on temperature, and that of liquids generally become smaller as temperature rises. Therefore, as for liquids, the substance with kinematic viscosity of 20.5 mm 2 /s or less at ambient temperature is placed in Category 1. Since, however, 192

the dependence of liquid viscosity on temperature is not linear in most cases, it is preferable to confirm the viscosity of the substance at 40℃ by referring to chemical technology books such as the Chemical Technology Handbook, or to estimate it by using the empirical formula recognized for the substance. The basic data such as the value of viscosity and measuring temperature and their references shall be given in “Grounds”. c) liquids and solids, not gases, are subject to classification. Since aspiration hazard concerns, not aspiration of substances suspended in gas phase, but to accidental aspiration of liquids and solids, aerosol/dust/mist substances are judged by referring to the UN GHS second revised edition 3.10.1.6.4, and considering nature of substances, performance of the containers in which the substances are provided (spray can, etc.), etc. (Substances aspirated into respiratory tract/respiratory system while suspended in gas phase are placed in “Not applicable”.). d) Here, “hydrocarbon” means substances consisting of carbon and hydrogen including nonlinear one, but halogenized hydrocarbon is not included. (General notes regarding kinematic viscosity) (Note 1)In many cases, viscosity is indicated in cgs units(dyn・s/cm 2 = poise(or P)). Use the following conversion formula when appropriate. 1 poise = 0.1Pa・s (Note 2)The classification criteria refer to kinematic viscosity. The conversion formula between dynamic viscosity and kinematic viscosity is indicated below. It should be noted that both of SI unit and CGS unit are used in the formula. Dynamic viscosity (mPa・s) / Density (g/cm 3 ) = Kinematic viscosity (mm 2 /s) 193

The classification criteria refer to kinematic viscosity. The conversion <strong>for</strong>mula between<br />

dynamic viscosity and kinematic viscosity is indicated below.<br />

Dynamic viscosity (mPa・s) / Density (g/cm 3 ) = Kinematic viscosity (mm 2 /s)<br />

(4)<strong>Guidance</strong> <strong>for</strong> classification and judgment<br />

A) Background of this item and points to be noted<br />

As <strong>for</strong> background of this item, refer to Part 1, Introduction.<br />

In classification, take <strong>the</strong> following points into account.<br />

* Unless a description that definitely denies hazards or recognizes extremely low hazards<br />

is available in List 1, <strong>the</strong> determination of “Not classified” should be per<strong>for</strong>med<br />

carefully. If <strong>the</strong>re is any question, a given substance should ra<strong>the</strong>r be classified in<br />

“<strong>Classification</strong> not possible” due to insufficient in<strong>for</strong>mation <strong>for</strong> judgment.<br />

* If data are available only <strong>for</strong> a mixture, <strong>the</strong> mixture itself is classified, and this shall be<br />

stated in "Grounds".<br />

B)Regarding classification procedure<br />

1) A substance meeting [Decision Criteria 1a] or [Decision Criteria 1b] shall be placed in<br />

Category 1.<br />

[Decision Criteria 1a]: A document in List 1 or List 2 contains a description to <strong>the</strong> effect that<br />

human chemical pneumonia was caused by accidental aspiration.<br />

(Note)<br />

a) Any kinematic viscosity shall not be considered.<br />

b) Liquids and solids, not gases, are subject to classification. Since aspiration hazard<br />

concerns, not aspiration of substances suspended in gas phase, accidental aspiration<br />

of liquids and solids, aerosol/dust/mist substances are judged by referring to <strong>the</strong> UN<br />

<strong>GHS</strong> second revised edition 3.10.1.6.4 and considering nature of substances,<br />

per<strong>for</strong>mance of <strong>the</strong> containers in which <strong>the</strong> substances are provided (spray can, etc.),<br />

etc. (Substances aspirated into respiratory tract/respiratory system while suspended in<br />

gas phase are placed in “Not applicable”.).<br />

[Decision Criteria 1b]: A substance which is a hydrocarbon and has kinematic viscosity of<br />

20.5 mm 2 /s or less at 40℃.<br />

(Note)<br />

a) The existence or absence of human evidence shall not be considered.<br />

b) Viscosity depends on temperature, and that of liquids generally become smaller as<br />

temperature rises. There<strong>for</strong>e, as <strong>for</strong> liquids, <strong>the</strong> substance with kinematic viscosity of<br />

20.5 mm 2 /s or less at ambient temperature is placed in Category 1. Since, however,<br />

192

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