Corrigendum - REACH24H Consulting Group

Recommendations

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Copyright@United Nations, 2011. All rights reserved. 7.1.5.3.1.3 The control and emergency temperatures are derived using the table in 7.1.5.3.1.2 from the self-accelerating decomposition temperature (SADT) which is defined as the lowest temperature at which self-accelerating decomposition may occur with a substance in the packaging as used in transport. An SADT shall be determined in order to decide if a substance shall be subjected to temperature control during transport. Provisions for the determination of the SADT are given in 2.4.2.3.4 and 2.5.3.4.2 for self-reactive substances and organic peroxides, respectively. 7.1.5.3.1.4 Control and emergency temperatures, where appropriate, are provided for currently assigned selfreactive substances in 2.4.2.3.2.3 and for currently assigned organic peroxide formulations in 2.5.3.2.4. The actual transport temperature may be lower than the control temperature but shall be selected so as to avoid dangerous separation of phases. 7.1.5.3.2 Transport under temperature control NOTE: Since the circumstances to be taken into account differ for the various modes of transport, only general guidance is provided. 7.1.5.3.2.1 Maintenance of the prescribed temperature is an essential feature of the safe transport of many self-reactive substances and organic peroxides. In general, there shall be: (a) Thorough inspection of the cargo transport unit prior to loading; (b) Instructions to the carrier about the operation of the refrigeration system; (c) Procedures to be followed in the event of loss of control; (d) Regular monitoring of operating temperatures; and (e) Provision of a back-up refrigeration system or spare parts. 7.1.5.3.2.2 Any control and temperature sensing devices in the refrigeration system shall be readily accessible and all electrical connections weather-proof. The temperature of air space within the cargo transport unit shall be measured by two independent sensors and the output shall be recorded so that temperature changes are readily detectable. The temperature shall be checked every four to six hours and logged. When substances having a control temperature of less than +25 °C are carried, the cargo transport unit shall be equipped with visible and audible alarms, powered independently of the refrigeration system, set to operate at or below the control temperature. 7.1.5.3.2.3 If during transport the control temperature is exceeded, an alert procedure shall be initiated involving any necessary repairs to the refrigeration equipment or an increase in the cooling capacity (e.g. by adding liquid or solid refrigerants). The temperature shall also be checked frequently and preparations made for implementation of the emergency procedures. If the emergency temperature is reached, the emergency procedures shall be initiated. 7.1.5.3.2.4 The suitability of a particular means of temperature control for transport depends on a number of factors. Factors to be considered include: (a) The control temperature(s) of the substance(s) to be transported; (b) The difference between the control temperature and the anticipated ambient temperature conditions; (c) The effectiveness of the thermal insulation; (d) The duration of transport; and (e) Allowance of a safety margin for delays. - 360 -
Copyright@United Nations, 2011. All rights reserved. 7.1.5.3.2.5 Suitable methods for preventing the control temperature being exceeded are, in order of increasing control capability: (a) Thermal insulation; provided that the initial temperature of the organic peroxide(s) is sufficiently below the control temperature; (b) Thermal insulation with coolant system; provided that: (i) An adequate quantity of coolant (e.g. liquid nitrogen or solid carbon dioxide), allowing a reasonable margin for delay, is carried; (ii) Liquid oxygen or air is not used as coolant; (iii) There is a uniform cooling effect even when most of the coolant has been consumed; and (iv) The need to ventilate the unit before entering is clearly indicated by a warning on the door(s) of the unit; (c) Single mechanical refrigeration; provided that for organic peroxides with a flash point lower than the sum of the emergency temperature plus 5 °C explosion-proof electrical fittings are used within the cooling compartment to prevent ignition of flammable vapours from the organic peroxides; (d) Combined mechanical refrigeration system with coolant system; provided that: (i) The two systems are independent of one another; (ii) The provisions in (b) and (c) are complied with; (e) Dual mechanical refrigeration system; provided that: (i) Apart from the integral power supply unit, the two systems are independent of one another; (ii) Each system alone is capable of maintaining adequate temperature control; and (iii) For organic peroxides with a flash point lower than the sum of the emergency temperature plus 5 °C explosion-proof electrical fittings are used within the cooling compartment to prevent ignition of flammable vapours from the organic peroxides. 7.1.6 Special provisions applicable to the transport of substances stabilized by temperature control (other than self-reactive substances and organic peroxides) 7.1.6.1 These provisions apply to the transport of substances for which: (a) The proper shipping name contains the word “STABILIZED”; and (b) The SADT (see 7.1.5.3.1.3) as presented for transport in the package, IBC or tank is 50 °C or lower. When chemical inhibition is not used to stabilize a reactive substance which may generate dangerous amounts of heat and gas, or vapour, under normal transport conditions, these substances need to be transported under temperature control. These provisions do not apply to substances which are stabilized by the addition of chemical inhibitors such that the SADT is greater than 50 °C. NOTE: Some substances which are transported under temperature control are prohibited from transport by certain modes. - 361 -
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Recommendations on the Transport of
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16. 4.1.4.1, P802 (1) After 4B, ins
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Copyright@United Nations, 2011. All
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Recommendations on the TRANSPORT OF
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2.8 Appearance at normal transport
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4.9 Does the substance have oxidizi
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CHAPTER 1.1 GENERAL PROVISIONS Intr
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1.2.1 Definitions CHAPTER 1.2 DEFIN
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Consignee means any person, organiz
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Open cryogenic receptacle means a t
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Remanufactured packagings include:
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Clarifying examples for certain def
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The decimal multiples and sub-multi
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CHAPTER 1.4 SECURITY PROVISIONS Int
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1.5.1 Scope and application Copyrig
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1.5.2.4 For occupational exposures
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2.0.0 Responsibilities CHAPTER 2.0
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2.0.4 Transport of samples Copyrigh
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CHAPTER 2.1 CLASS 1 - EXPLOSIVES In
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(e) Division 1.5 Very insensitive s
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NOTE 1: Articles of compatibility g
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2.2.1 Definitions and general provi
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2.2.3 Mixtures of gases Copyright@U
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2.3.2.6 Hazard grouping based on fl
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SELF-REACTIVE SUBSTANCE Concentrati
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Figure 2.4.1: FLOW CHART SCHEME FOR
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2.4.3 Division 4.2 - Substances lia
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2.4.4.3 Assignment of packing group
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CHAPTER 2.5 CLASS 5 - OXIDIZING SUB
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2.5.2.3.1.2 The classification test
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Notes on 2.5.3.2.4: 1) Diluent type
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Exit E Box 11 Figure 2.5.1: FLOW CH
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CHAPTER 2.6 CLASS 6 - TOXIC AND INF
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2.6.2.2.4.2 The criteria for inhala
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(a) Classify the formulation accord
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INDICATIVE EXAMPLES OF INFECTIOUS S
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2.6.3.2.3.7 Except for: Copyright@U
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CHAPTER 2.7 CLASS 7 - RADIOACTIVE M
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Gold (79) Radionuclide (atomic numb
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Radionuclide (atomic number) A1 A2
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Osmium (76) Radionuclide (atomic nu
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2.7.2.2.4 For mixtures of radionucl
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(b) SCO-II: A solid object on which
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2.7.2.3.3.8 For specimens which com
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For mixtures of radionuclides whose
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2.8.1 Definition CHAPTER 2.8 CLASS
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CHAPTER 2.9 CLASS 9 - MISCELLANEOUS
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Other substances or articles presen
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NOTE 1: The organisms fish, crustac
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2.9.3.4.2 The approach for classifi
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2.9.3.4.4.2 Dilution 2.9.3.4.4.2.1
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2.9.3.4.5.3 When applying the addit
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2.9.4 Lithium batteries Copyright@U
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3.1.1 Scope and general provisions
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3.1.2.8 Generic or “not otherwise
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UN No. Name and description Copyrig
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UN No. Name and description Class o
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P200 PACKING INSTRUCTION (cont'd) P
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P207 PACKING INSTRUCTION P207 This
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IBC520 PACKING INSTRUCTION IBC520 T
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IBC620 PACKING INSTRUCTION IBC620 T
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equirements. Copyright@United Natio
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4.2.1.9.6 Portable tanks shall not
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4.2.1.13.9 For insulated portable t
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(b) When leaking; (c) When damaged
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4.2.4.4 The periodic testing and in
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T23 PORTABLE TANK INSTRUCTION T23 T
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T50 PORTABLE TANK INSTRUCTION T50 T
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T50 PORTABLE TANK INSTRUCTION (cont
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4.2.5.3 Portable tank special provi
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(c) Substances shall not be allowed
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4.3.1 General provisions Copyright@
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4.3.1.16 Before a flexible bulk con
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5.1.1 Application and general provi
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5.2.1 Marking Copyright@United Nati
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5.2.1.6 Special marking provisions
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.2.7 The following table indicat
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6.1.4.2.6 Maximum capacity of drum:
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6.1.4.8 Plastics drums and jerrican
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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6.1.5.5 Internal pressure (hydrauli
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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6.2.1.5.2 On an adequate sample of
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ISO 4706:2008 Gas cylinders - Refil
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6.2.2.4 Periodic inspection and tes
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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Marking shall be applied in the seq
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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(b) A liquid tight closure at the e
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6.7.2.12.2.3 Minimum required rate
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(d) Missing or loose bolts or nuts
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