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Copyright@United Nations, 2011. All rights reserved. TABLE OF CONTENTS VOLUME II ANNEX: MODEL REGULATIONS ON THE TRANSPORT OF DANGEROUS GOODS......... 1 (cont'd) Part 4. PACKING AND TANK PROVISIONS ...................................................................... 3 Chapter 4.1 - Use of packagings, including intermediate bulk containers (IBCs) and large packagings ...................................................................... 5 4.1.1 General provisions for the packing of dangerous goods in packagings, including IBCs and large packagings . .............................. 5 4.1.2 Additional general provisions for the use of IBCs .......................................... 10 4.1.3 General provisions concerning packing instructions....................................... 10 4.1.4 List of packing instructions ...................................................................... 14 4.1.5 Special packing provisions for goods of Class 1............................................. 90 4.1.6 Special packing provisions for goods of Class 2............................................. 92 4.1.7 Special packing provisions for organic peroxides (Division 5.2) and self-reactive substances of Division 4.1 .............................................. 94 4.1.8 Special packing provisions for infectious substances of Category A (Division 6.2, UN 2814 and UN 2900) ........................................................ 96 4.1.9 Special packing provisions for Class 7............................................................ 96 Chapter 4.2 - Use of portable tanks and multiple-element gas containers (MEGCs)............ 101 - iii - Page 4.2.1 General provisions for the use of portable tanks for the transport of substances of Class 1 and Classes 3 to 9................................................ 101 4.2.2 General provisions for the use of portable tanks for the transport of non-refrigerated liquefied gases............................................................. 106 4.2.3 General provisions for the use of portable tanks for the transport of refrigerated liquefied gases .................................................................... 107 4.2.4 General provisions for the use of multiple-element gas containers (MEGCs) ............................................................................................ 108 4.2.5 Portable tank instructions and special provisions............................................ 109 4.2.6 Transitional measures ...................................................................... 125 Chapter 4.3 - Use of bulk containers ................................................................................ 127 4.3.1 General provisions ...................................................................................... 127 4.3.2 Additional provisions applicable to bulk goods of Divisions 4.2, 4.3, 5.1, 6.2 and Classes 7 and 8 ................................................................... 129 Part 5. CONSIGNMENT PROCEDURES ................................................................................ 131 Chapter 5.1 - General provisions ...................................................................................... 133 5.1.1 Application and general provisions ................................................................. 133 5.1.2 Use of overpacks ...................................................................................... 133 5.1.3 Empty packagings ...................................................................................... 133 5.1.4 Mixed packing ...................................................................................... 133 5.1.5 General provisions for class 7 ...................................................................... 134
Copyright@United Nations, 2011. All rights reserved. TABLE OF CONTENTS (cont'd) VOLUME II Chapter 5.2 - Marking and labelling ................................................................................... 139 - iv - Page 5.2.1 Marking .................................................................................................. 139 5.2.2 Labelling .................................................................................................. 142 Chapter 5.3 - Placarding and marking of cargo transport units............................................. 151 5.3.1 Placarding .................................................................................................. 151 5.3.2 Marking ........................................................................................................ 153 Chapter 5.4 - Documentation ............................................................................................... 155 5.4.1 Dangerous goods transport information .......................................................... 155 5.4.2 Container/vehicle packing certificate .............................................................. 161 5.4.3 Emergency response information .................................................................... 162 5.4.4 Retention of dangerous goods transport information ...................................... 162 Chapter 5.5 - Special provisions ......................................................................................... 165 5.5.1 (Deleted) ........................................................................................................ 165 5.5.2 Special provisions applicable to fumigated cargo transport units (UN 3359) ....................................................................................................... 165 5.5.3 Special provisions applicable to packages and cargo transport units containing substances presenting a risk of asphyxiation when used for cooling or conditioning purposes (such as dry ice (UN 1845) or nitrogen, refrigerated liquid (UN 1977) or argon, refrigerated liquid (UN 1951)) ................................................................................................... 167 Part 6. REQUIREMENTS FOR THE CONSTRUCTION AND TESTING OF PACKAGINGS, INTERMEDIATE BULK CONTAINERS (IBCs), LARGE PACKAGINGS, PORTABLE TANKS, MULTIPLE-ELEMENT GAS CONTAINERS (MEGCs) AND BULK CONTAINERS ............................................................................................ 171 Chapter 6.1 - Requirements for the construction and testing of packagings (other than for Division 6.2 substances)..................................................... 173 6.1.1 General ........................................................................................................ 173 6.1.2 Code for designating types of packagings....................................................... 174 6.1.3 Marking ........................................................................................................ 176 6.1.4 Requirements for packagings ...................................................................... 179 6.1.5 Test requirements for packagings.................................................................... 190 Chapter 6.2 - Requirements for the construction and testing of pressure receptacles, aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas. ....................... 197 6.2.1 General requirements ................................................................................... 197 6.2.2 Requirements for UN pressure receptacles...................................................... 202 6.2.3 Requirements for non-UN pressure receptacles .............................................. 218 6.2.4 Requirements for aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas ...................................................................... 219
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CHAPTER 1.4 SECURITY PROVISIONS Int
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Copyright@United Nations, 2011. All
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1.5.1 Scope and application Copyrig
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1.5.2.4 For occupational exposures
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2.0.0 Responsibilities CHAPTER 2.0
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2.0.4 Transport of samples Copyrigh
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CHAPTER 2.1 CLASS 1 - EXPLOSIVES In
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(e) Division 1.5 Very insensitive s
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NOTE 1: Articles of compatibility g
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2.1.3.6 Exclusion from Class 1 Copy
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2.2.1 Definitions and general provi
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2.2.3 Mixtures of gases Copyright@U
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2.3.2.6 Hazard grouping based on fl
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2.4.2.2.3.3 For solids which may ca
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SELF-REACTIVE SUBSTANCE Concentrati
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Figure 2.4.1: FLOW CHART SCHEME FOR
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2.4.3 Division 4.2 - Substances lia
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2.4.4.3 Assignment of packing group
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CHAPTER 2.5 CLASS 5 - OXIDIZING SUB
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2.5.2.3.1.2 The classification test
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- 101 - ORGANIC PEROXIDE Concentrat
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Notes on 2.5.3.2.4: 1) Diluent type
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Exit E Box 11 Figure 2.5.1: FLOW CH
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CHAPTER 2.6 CLASS 6 - TOXIC AND INF
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2.6.2.2.4.2 The criteria for inhala
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(a) Classify the formulation accord
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INDICATIVE EXAMPLES OF INFECTIOUS S
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2.6.3.2.3.7 Except for: Copyright@U
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CHAPTER 2.7 CLASS 7 - RADIOACTIVE M
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Gold (79) Radionuclide (atomic numb
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Radionuclide (atomic number) A1 A2
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Osmium (76) Radionuclide (atomic nu
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2.7.2.2.4 For mixtures of radionucl
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(b) SCO-II: A solid object on which
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2.7.2.3.3.8 For specimens which com
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For mixtures of radionuclides whose
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2.8.1 Definition CHAPTER 2.8 CLASS
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CHAPTER 2.9 CLASS 9 - MISCELLANEOUS
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Other substances or articles presen
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NOTE 1: The organisms fish, crustac
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2.9.3.4.2 The approach for classifi
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2.9.3.4.4.2 Dilution 2.9.3.4.4.2.1
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2.9.3.4.5.3 When applying the addit
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2.9.4 Lithium batteries Copyright@U
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3.1.1 Scope and general provisions
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3.1.2.8 Generic or “not otherwise
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UN No. Name and description Copyrig
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UN No. Name and description Class o
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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Recommendations on the TRANSPORT OF
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Recommendations on the TRANSPORT OF
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P200 PACKING INSTRUCTION (cont'd) P
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P207 PACKING INSTRUCTION P207 This
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P502 PACKING INSTRUCTION P502 The f
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IBC520 PACKING INSTRUCTION IBC520 T
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IBC620 PACKING INSTRUCTION IBC620 T
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equirements. Copyright@United Natio
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4.2.1.9.6 Portable tanks shall not
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4.2.1.13.9 For insulated portable t
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(b) When leaking; (c) When damaged
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4.2.4.4 The periodic testing and in
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T23 PORTABLE TANK INSTRUCTION T23 T
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T50 PORTABLE TANK INSTRUCTION T50 T
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T50 PORTABLE TANK INSTRUCTION (cont
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4.2.5.3 Portable tank special provi
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(c) Substances shall not be allowed
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4.3.1 General provisions Copyright@
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4.3.1.16 Before a flexible bulk con
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5.1.1 Application and general provi
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5.2.1 Marking Copyright@United Nati
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5.2.1.6 Special marking provisions
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.2.7 The following table indicat
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6.1.3.10 Examples of markings for N
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6.1.4.2.6 Maximum capacity of drum:
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6.1.4.8 Plastics drums and jerrican
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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6.1.5.3.2 Special preparation of te
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6.1.5.5 Internal pressure (hydrauli
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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6.2.1.3.4 Individual pressure recep
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6.2.1.5.2 On an adequate sample of
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ISO 4706:2008 Gas cylinders - Refil
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6.2.2.4 Periodic inspection and tes
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6.2.2.5.3 Manufacturer's quality sy
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6.2.2.5.4.8 The application shall i
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pressure receptacle is not the comp
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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6.4.7.9 If the containment system f
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6.4.18 Enhanced water immersion tes
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Marking shall be applied in the seq
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6.5.2.4 Marking of remanufactured c
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6.5.4.4.3 A report of each inspecti
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6.5.6.3 Preparation of IBCs for tes
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6.5.6.5.5 Criteria for passing the
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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6.5.6.14 Test report Copyright@Unit
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6.6.1 General Copyright@United Nati
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6.6.3.2 Examples of the marking 50
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6.6.5.2.2 In the drop tests for liq
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6.6.5.3.4 Drop test 6.6.5.3.4.1 App
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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6.7.2.2.14 The values of yield stre
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6.7.2.4.7 When in the applicable po
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(b) A liquid tight closure at the e
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6.7.2.12.2 The combined delivery ca
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6.7.2.12.2.3 Minimum required rate
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6.7.2.17.5 When portable tanks are
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(d) Missing or loose bolts or nuts
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Figure 6.7.2.20.1: Example of ident
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(b) For steels with no clearly defi
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6.7.3.5 Service equipment Copyright
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where: 0. 82 FA Q = 12. 4 LC - 317
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There shall be no obstruction in an
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(f) Materials (i) Shell material(s)
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6.7.4.8.2 The rated flow capacity m
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6.7.4.14.3 The initial inspection a
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(d) Pressures (i) MAWP (in bar gaug
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6.7.5.3.3 For filling and discharge
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6.7.5.10 MEGC supports, frameworks,
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the inspection and test, the test p
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CHAPTER 6.8 REQUIREMENTS FOR THE DE
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6.8.4.3 Vehicles shall comply with
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6.8.5.3.6.2 Preparation for testing
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8. Characteristics of test contents
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oken, missing or otherwise inoperat
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(c) Inform the appropriate public h
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7.2.1 Application and general provi
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TS-R-1 UN 101 1.5.1.1 102 X 103 1.1
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TS-R-1 UN 667 6.4.10.1 668 6.4.10.2
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