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Copyright@United Nations, 2011. All rights reserved. TABLE OF CONTENTS (cont'd) VOLUME I Chapter 2.3 - Class 3 - Flammable liquids ............................................................................ 77 2.3.1 Definition and general provisions.................................................................... 77 2.3.2 Assignment of packing groups ........................................................................ 78 2.3.3 Determination of flash point............................................................................ 79 2.3.4 Determination of initial boiling point.............................................................. 80 Chapter 2.4 - Class 4 - Flammable solids; substances liable to spontaneous combustion; substances which, in contact with water, emit flammable gases..................... 81 2.4.1 Definitions and general provisions.................................................................. 81 2.4.2 Division 4.1 - Flammable solids, self-reactive substances and solid desensitized explosives .............................................................. 89 2.4.3 Division 4.2 - Substances liable to spontaneous combustion .......................... 93 2.4.4 Division 4.3 - Substances which in contact with water emit flammable gases ......................................................................................... 94 2.4.5 Classification of organometallic substances.................................................... 95 Chapter 2.5 - Class 5 - Oxidizing substances and organic peroxides.................................... 97 2.5.1 Definitions and general provisions.................................................................. 97 2.5.2 Division 5.1 - Oxidizing substances................................................................ 97 2.5.3 Division 5.2 - Organic peroxides..................................................................... 99 Chapter 2.6 - Class 6 - Toxic and infectious substances ....................................................... 117 - 14 - Page 2.6.1 Definitions .................................................................................................... 117 2.6.2 Division 6.1 - Toxic substances....................................................................... 117 2.6.3 Division 6.2 - Infectious substances................................................................ 123 Chapter 2.7 - Class 7 - Radioactive material ......................................................................... 129 2.7.1 Definitions .......................................................................................... 129 2.7.2 Classification ................................................................................................... 130 Chapter 2.8 - Class 8 - Corrosive substances ........................................................................ 159 2.8.1 Definition ....................................................................................................... 159 2.8.2 Assignment of packing groups ........................................................................ 159 Chapter 2.9 - Class 9 - Miscellaneous dangerous substances and articles, including environmentally hazardous substances............................................ 161 2.9.1 Definitions .................................................................................................... 161 2.9.2 Assignment to Class 9 ..................................................................................... 161 2.9.3 Environmentally hazardous substances (aquatic environment)....................... 163 2.9.4 Lithium batteries.............................................................................................. 175
Copyright@United Nations, 2011. All rights reserved. TABLE OF CONTENTS (cont'd) VOLUME I Part 3. DANGEROUS GOODS LIST, SPECIAL PROVISIONS AND EXCEPTIONS ........... 177 Chapter 3.1 - General .......................................................................................................... 179 - 15 - Page 3.1.1 Scope and general provisions .......................................................................... 179 3.1.2 Proper shipping name ...................................................................................... 179 3.1.3 Mixtures or solutions....................................................................................... 181 Chapter 3.2 - Dangerous goods list ....................................................................................... 183 3.2.1 Structure of the dangerous goods list .............................................................. 183 3.2.2 Abbreviations and symbols ............................................................................. 184 Chapter 3.3 - Special provisions applicable to certain articles or substances........................ 297 Chapter 3.4 - Dangerous goods packed in limited quantities ................................................ 323 Chapter 3.5 - Dangerous goods packed in excepted quantities ............................................. 325 3.5.1 Excepted quantities.......................................................................................... 325 3.5.2 Packagings .......................................................................................... 326 3.5.3 Tests for packages .......................................................................................... 326 3.5.4 Marking of packages ....................................................................................... 327 3.5.5 Maximum number of packages in any freight vehicle, railway freight wagon or multimodal freight container............................................. 328 3.5.6 Documentation .......................................................................................... 328 APPENDICES .............................................................................................................................. 329 Appendix A - List of generic and N.O.S. proper shipping names.......................................... 331 Appendix B - Glossary of terms .......................................................................................... 351 ALPHABETICAL INDEX OF SUBSTANCES AND ARTICLES............................................... 363
Page 1 and 2: Recommendations on the Transport of
Page 3 and 4: 16. 4.1.4.1, P802 (1) After 4B, ins
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Page 13 and 14: Recommendations on the TRANSPORT OF
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Page 25 and 26: 2.8 Appearance at normal transport
Page 27 and 28: 4.9 Does the substance have oxidizi
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Copyright@United Nations, 2011. All
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CHAPTER 1.4 SECURITY PROVISIONS Int
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1.5.1 Scope and application Copyrig
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1.5.2.4 For occupational exposures
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2.0.0 Responsibilities CHAPTER 2.0
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2.0.4 Transport of samples Copyrigh
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CHAPTER 2.1 CLASS 1 - EXPLOSIVES In
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(e) Division 1.5 Very insensitive s
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NOTE 1: Articles of compatibility g
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- 67 - Type Includes: / Synonym: De
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- 69 - Type Includes: / Synonym: De
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2.1.3.6 Exclusion from Class 1 Copy
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2.2.1 Definitions and general provi
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2.2.3 Mixtures of gases Copyright@U
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2.3.2.6 Hazard grouping based on fl
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2.4.2.2.3.3 For solids which may ca
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SELF-REACTIVE SUBSTANCE Concentrati
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Figure 2.4.1: FLOW CHART SCHEME FOR
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2.4.3 Division 4.2 - Substances lia
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2.4.4.3 Assignment of packing group
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CHAPTER 2.5 CLASS 5 - OXIDIZING SUB
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2.5.2.3.1.2 The classification test
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- 101 - ORGANIC PEROXIDE Concentrat
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- 103 - Copyright@United Nations, 2
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Notes on 2.5.3.2.4: 1) Diluent type
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Exit E Box 11 Figure 2.5.1: FLOW CH
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CHAPTER 2.6 CLASS 6 - TOXIC AND INF
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2.6.2.2.4.2 The criteria for inhala
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(a) Classify the formulation accord
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INDICATIVE EXAMPLES OF INFECTIOUS S
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2.6.3.2.3.7 Except for: Copyright@U
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CHAPTER 2.7 CLASS 7 - RADIOACTIVE M
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Gold (79) Radionuclide (atomic numb
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Radionuclide (atomic number) A1 A2
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Osmium (76) Radionuclide (atomic nu
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2.7.2.2.4 For mixtures of radionucl
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(b) SCO-II: A solid object on which
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2.7.2.3.3.8 For specimens which com
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For mixtures of radionuclides whose
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2.8.1 Definition CHAPTER 2.8 CLASS
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CHAPTER 2.9 CLASS 9 - MISCELLANEOUS
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Other substances or articles presen
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NOTE 1: The organisms fish, crustac
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2.9.3.4.2 The approach for classifi
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2.9.3.4.4.2 Dilution 2.9.3.4.4.2.1
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2.9.3.4.5.3 When applying the addit
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2.9.4 Lithium batteries Copyright@U
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3.1.1 Scope and general provisions
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3.1.2.8 Generic or “not otherwise
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UN No. Name and description Copyrig
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UN No. Name and description Class o
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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Recommendations on the TRANSPORT OF
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Recommendations on the TRANSPORT OF
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P200 PACKING INSTRUCTION (cont'd) P
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P207 PACKING INSTRUCTION P207 This
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P502 PACKING INSTRUCTION P502 The f
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IBC520 PACKING INSTRUCTION IBC520 T
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IBC620 PACKING INSTRUCTION IBC620 T
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equirements. Copyright@United Natio
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4.2.1.9.6 Portable tanks shall not
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4.2.1.13.9 For insulated portable t
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(b) When leaking; (c) When damaged
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4.2.4.4 The periodic testing and in
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T23 PORTABLE TANK INSTRUCTION T23 T
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T50 PORTABLE TANK INSTRUCTION T50 T
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T50 PORTABLE TANK INSTRUCTION (cont
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4.2.5.3 Portable tank special provi
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(c) Substances shall not be allowed
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4.3.1 General provisions Copyright@
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4.3.1.16 Before a flexible bulk con
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5.1.1 Application and general provi
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5.2.1 Marking Copyright@United Nati
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5.2.1.6 Special marking provisions
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.2.7 The following table indicat
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6.1.3.10 Examples of markings for N
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6.1.4.2.6 Maximum capacity of drum:
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6.1.4.8 Plastics drums and jerrican
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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6.1.5.3.2 Special preparation of te
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6.1.5.5 Internal pressure (hydrauli
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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6.2.1.3.4 Individual pressure recep
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6.2.1.5.2 On an adequate sample of
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ISO 4706:2008 Gas cylinders - Refil
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6.2.2.4 Periodic inspection and tes
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6.2.2.5.3 Manufacturer's quality sy
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6.2.2.5.4.8 The application shall i
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pressure receptacle is not the comp
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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6.4.7.9 If the containment system f
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6.4.18 Enhanced water immersion tes
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Marking shall be applied in the seq
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6.5.2.4 Marking of remanufactured c
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6.5.4.4.3 A report of each inspecti
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6.5.6.3 Preparation of IBCs for tes
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6.5.6.5.5 Criteria for passing the
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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6.5.6.14 Test report Copyright@Unit
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6.6.1 General Copyright@United Nati
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6.6.3.2 Examples of the marking 50
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6.6.5.2.2 In the drop tests for liq
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6.6.5.3.4 Drop test 6.6.5.3.4.1 App
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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6.7.2.2.14 The values of yield stre
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6.7.2.4.7 When in the applicable po
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(b) A liquid tight closure at the e
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6.7.2.12.2 The combined delivery ca
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6.7.2.12.2.3 Minimum required rate
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6.7.2.17.5 When portable tanks are
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(d) Missing or loose bolts or nuts
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Figure 6.7.2.20.1: Example of ident
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(b) For steels with no clearly defi
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6.7.3.5 Service equipment Copyright
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where: 0. 82 FA Q = 12. 4 LC - 317
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There shall be no obstruction in an
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(f) Materials (i) Shell material(s)
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6.7.4.2.13 Under each of the forces
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6.7.4.8.2 The rated flow capacity m
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6.7.4.14.3 The initial inspection a
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(d) Pressures (i) MAWP (in bar gaug
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6.7.4.15.3 If a portable tank is de
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6.7.5.3.3 For filling and discharge
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6.7.5.10 MEGC supports, frameworks,
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the inspection and test, the test p
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CHAPTER 6.8 REQUIREMENTS FOR THE DE
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6.8.4.3 Vehicles shall comply with
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6.8.5.3.6.2 Preparation for testing
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8. Characteristics of test contents
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oken, missing or otherwise inoperat
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(c) Inform the appropriate public h
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7.2.1 Application and general provi
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TS-R-1 UN 101 1.5.1.1 102 X 103 1.1
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TS-R-1 UN 667 6.4.10.1 668 6.4.10.2
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