Corrigendum - REACH24H Consulting Group

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Copyright@United Nations, 2011. All rights reserved. 4.1.6.1.13 Filled pressure receptacles shall not be offered for transport; (a) When leaking; (b) When damaged to such an extent that the integrity of the pressure receptacle or its service equipment may be affected; (c) Unless the pressure receptacle and its service equipment has been examined and found to be in good working order; or (d) Unless the required certification, retest, and filling markings are legible. 4.1.7 Special packing provisions for organic peroxides (Division 5.2) and self-reactive substances of Division 4.1 4.1.7.0.1 For organic peroxides, all receptacles shall be “effectively closed”. Where significant internal pressure may develop in a package by the evolution of a gas, a vent may be fitted, provided the gas emitted will not cause danger, otherwise the degree of filling shall be limited. Any venting device shall be so constructed that liquid will not escape when the package is in an upright position and it shall be able to prevent ingress of impurities. The outer packaging, if any, shall be so designed as not to interfere with the operation of the venting device. 4.1.7.1 Use of packagings (except IBCs) 4.1.7.1.1 Packagings for organic peroxides and self-reactive substances shall conform to the requirements of Chapter 6.1 and shall meet its test requirements for packing group II. 4.1.7.1.2 The packing methods for organic peroxides and self-reactive substances are listed in packing instruction P520 and are designated OP1 to OP8. The quantities specified for each packing method are the maximum quantities authorized per package. 4.1.7.1.3 The packing methods appropriate for the individual currently assigned organic peroxides and self-reactive substances are listed in 2.4.2.3.2.3 and 2.5.3.2.4. 4.1.7.1.4 For new organic peroxides, new self-reactive substances or new formulations of currently assigned organic peroxides or self-reactive substances, the following procedure shall be used to assign the appropriate packing method: (a) ORGANIC PEROXIDE, TYPE B or SELF-REACTIVE SUBSTANCE, TYPE B: Packing method OP5 shall be assigned, provided that the organic peroxide (or selfreactive substance) satisfies the criteria of 2.5.3.3.2 (b) (resp. 2.4.2.3.3.2 (b)) in a packaging authorized by the packing method. If the organic peroxide (or self-reactive substance) can only satisfy these criteria in a smaller packaging than those authorized by packing method OP5 (viz. one of the packagings listed for OP1 to OP4), then the corresponding packing method with the lower OP number is assigned; (b) ORGANIC PEROXIDE, TYPE C or SELF-REACTIVE SUBSTANCE, TYPE C: Packing method OP6 shall be assigned, provided that the organic peroxide (or selfreactive substance) satisfies the criteria of 2.5.3.3.2 (c) (resp. 2.4.2.3.3.2 (c)) in packaging authorized by the packing method. If the organic peroxide (or self-reactive substance) can only satisfy these criteria in a smaller packaging than those authorized by packing method OP6 then the corresponding packing method with the lower OP number is assigned; - 94 -
Copyright@United Nations, 2011. All rights reserved. (c) ORGANIC PEROXIDE, TYPE D or SELF-REACTIVE SUBSTANCE, TYPE D: Packing method OP7 shall be assigned to this type of organic peroxide or self-reactive substance; (d) ORGANIC PEROXIDE, TYPE E or SELF-REACTIVE SUBSTANCE, TYPE E: Packing method OP8 shall be assigned to this type of organic peroxide or self-reactive substance; (e) ORGANIC PEROXIDE, TYPE F or SELF-REACTIVE SUBSTANCE, TYPE F: Packing method OP8 shall be assigned to this type of organic peroxide or self-reactive substance. 4.1.7.2 Use of intermediate bulk containers 4.1.7.2.1 The currently assigned organic peroxides specifically listed in packing instruction IBC520 may be transported in IBCs in accordance with this packing instruction. IBCs shall conform to the requirements of Chapter 6.5 and shall meet its test requirements for packing group II. 4.1.7.2.2 Other organic peroxides and self-reactive substances of type F may be transported in IBCs under conditions established by the competent authority of the country of origin when, on the basis of the appropriate tests, that competent authority is satisfied that such transport may be safely conducted. The tests undertaken shall include those necessary: (a) To prove that the organic peroxide (or self-reactive substance) complies with the principles for classification given in 2.5.3.3.2 (f), exit box F of Figure 2.5.1; (resp. 2.4.2.3.3.2 (f), exit box F of Figure 2.4.1); (b) To prove the compatibility of all materials normally in contact with the substance during the transport; (c) To determine, when applicable, the control and emergency temperatures associated with the transport of the product in the IBC concerned as derived from the SADT; (d) To design, when applicable, pressure and emergency relief devices; and (e) To determine if any special provisions are necessary for safe transport of the substance. 4.1.7.2.3 For self-reactive substances temperature control is required according to 2.4.2.3.4. For organic peroxides temperature control is required according to 2.5.3.4.1. Temperature control provisions are given in 7.1.5.3.1. 4.1.7.2.4 Emergencies to be taken into account are self-accelerating decomposition and fire engulfment. To prevent explosive rupture of metal IBCs with a complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapours evolved during selfaccelerating decomposition or during a period of not less than one hour of complete fire engulfment calculated by the equations given in 4.2.1.13.8. - 95 -
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Recommendations on the Transport of
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16. 4.1.4.1, P802 (1) After 4B, ins
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Copyright@United Nations, 2011. All
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Recommendations on the TRANSPORT OF
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2.8 Appearance at normal transport
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4.9 Does the substance have oxidizi
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CHAPTER 1.1 GENERAL PROVISIONS Intr
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1.2.1 Definitions CHAPTER 1.2 DEFIN
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Consignee means any person, organiz
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Open cryogenic receptacle means a t
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Remanufactured packagings include:
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Clarifying examples for certain def
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The decimal multiples and sub-multi
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CHAPTER 1.4 SECURITY PROVISIONS Int
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1.5.1 Scope and application Copyrig
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1.5.2.4 For occupational exposures
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2.0.0 Responsibilities CHAPTER 2.0
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2.0.4 Transport of samples Copyrigh
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CHAPTER 2.1 CLASS 1 - EXPLOSIVES In
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(e) Division 1.5 Very insensitive s
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NOTE 1: Articles of compatibility g
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2.1.3.6 Exclusion from Class 1 Copy
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2.2.1 Definitions and general provi
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2.2.3 Mixtures of gases Copyright@U
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2.3.2.6 Hazard grouping based on fl
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2.4.2.2.3.3 For solids which may ca
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SELF-REACTIVE SUBSTANCE Concentrati
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Figure 2.4.1: FLOW CHART SCHEME FOR
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2.4.3 Division 4.2 - Substances lia
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2.4.4.3 Assignment of packing group
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CHAPTER 2.5 CLASS 5 - OXIDIZING SUB
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2.5.2.3.1.2 The classification test
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- 101 - ORGANIC PEROXIDE Concentrat
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- 103 - Copyright@United Nations, 2
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Notes on 2.5.3.2.4: 1) Diluent type
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Exit E Box 11 Figure 2.5.1: FLOW CH
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CHAPTER 2.6 CLASS 6 - TOXIC AND INF
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2.6.2.2.4.2 The criteria for inhala
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(a) Classify the formulation accord
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INDICATIVE EXAMPLES OF INFECTIOUS S
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2.6.3.2.3.7 Except for: Copyright@U
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CHAPTER 2.7 CLASS 7 - RADIOACTIVE M
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Gold (79) Radionuclide (atomic numb
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Radionuclide (atomic number) A1 A2
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Osmium (76) Radionuclide (atomic nu
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2.7.2.2.4 For mixtures of radionucl
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(b) SCO-II: A solid object on which
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2.7.2.3.3.8 For specimens which com
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For mixtures of radionuclides whose
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2.8.1 Definition CHAPTER 2.8 CLASS
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CHAPTER 2.9 CLASS 9 - MISCELLANEOUS
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Other substances or articles presen
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NOTE 1: The organisms fish, crustac
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2.9.3.4.2 The approach for classifi
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2.9.3.4.4.2 Dilution 2.9.3.4.4.2.1
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2.9.3.4.5.3 When applying the addit
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2.9.4 Lithium batteries Copyright@U
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3.1.1 Scope and general provisions
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3.1.2.8 Generic or “not otherwise
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UN No. Name and description Copyrig
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UN No. Name and description Class o
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P200 PACKING INSTRUCTION (cont'd) P
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Page 515 and 516: P207 PACKING INSTRUCTION P207 This
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Page 545 and 546: IBC520 PACKING INSTRUCTION IBC520 T
Page 547 and 548: IBC620 PACKING INSTRUCTION IBC620 T
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.2.7 The following table indicat
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6.1.3.10 Examples of markings for N
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6.1.4.2.6 Maximum capacity of drum:
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6.1.4.8 Plastics drums and jerrican
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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6.1.5.3.2 Special preparation of te
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6.1.5.5 Internal pressure (hydrauli
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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6.2.1.3.4 Individual pressure recep
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6.2.1.5.2 On an adequate sample of
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ISO 4706:2008 Gas cylinders - Refil
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6.2.2.4 Periodic inspection and tes
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pressure receptacle is not the comp
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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6.4.7.9 If the containment system f
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6.4.18 Enhanced water immersion tes
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Marking shall be applied in the seq
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6.5.6.3 Preparation of IBCs for tes
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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6.5.6.14 Test report Copyright@Unit
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6.6.1 General Copyright@United Nati
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6.6.5.3.4 Drop test 6.6.5.3.4.1 App
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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(b) A liquid tight closure at the e
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(d) Missing or loose bolts or nuts
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Figure 6.7.2.20.1: Example of ident
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(b) For steels with no clearly defi
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6.7.3.5 Service equipment Copyright
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where: 0. 82 FA Q = 12. 4 LC - 317
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There shall be no obstruction in an
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(f) Materials (i) Shell material(s)
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(d) Pressures (i) MAWP (in bar gaug
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6.7.5.3.3 For filling and discharge
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6.7.5.10 MEGC supports, frameworks,
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the inspection and test, the test p
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CHAPTER 6.8 REQUIREMENTS FOR THE DE
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6.8.4.3 Vehicles shall comply with
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6.8.5.3.6.2 Preparation for testing
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8. Characteristics of test contents
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oken, missing or otherwise inoperat
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(c) Inform the appropriate public h
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7.2.1 Application and general provi
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TS-R-1 UN 101 1.5.1.1 102 X 103 1.1
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TS-R-1 UN 667 6.4.10.1 668 6.4.10.2
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