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Corrigendum - REACH24H Consulting Group

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Copyright@United Nations, 2011. All rights reserved.<br />

P203 PACKING INSTRUCTION P203<br />

This instruction applies to Class 2 refrigerated liquefied gases.<br />

Requirements for closed cryogenic receptacles:<br />

(1) The general requirements of 4.1.6.1 shall be met.<br />

(2) The requirements of Chapter 6.2 shall be met.<br />

(3) The closed cryogenic receptacles shall be so insulated that they do not become coated with frost.<br />

(4) Test pressure<br />

Refrigerated liquids shall be filled in closed cryogenic receptacles with the following minimum test pressures:<br />

(a) For closed cryogenic receptacles with vacuum insulation, the test pressure shall not be less than 1.3 times the sum<br />

of the maximum internal pressure of the filled receptacle, including during filling and discharge, plus 100 kPa<br />

(1 bar);<br />

(b) For other closed cryogenic receptacles, the test pressure shall be not less than 1.3 times the maximum internal<br />

pressure of the filled receptacle, taking into account the pressure developed during filling and discharge.<br />

(5) Degree of filling<br />

For non-flammable, non-toxic refrigerated liquefied gases the volume of liquid phase at the filling temperature<br />

and at a pressure of 100 kPa (1 bar) shall not exceed 98% of the water capacity of the pressure receptacle.<br />

For flammable refrigerated liquefied gases the degree of filling shall remain below the level at which, if the<br />

contents were raised to the temperature at which the vapour pressure equalled the opening pressure of the relief<br />

valve, the volume of the liquid phase would reach 98% of the water capacity at that temperature.<br />

(6) Pressure-relief devices<br />

Closed cryogenic receptacles shall be fitted with at least one pressure-relief device.<br />

(7) Compatibility<br />

Materials used to ensure the leakproofness of the joints or for the maintenance of the closures shall be compatible<br />

with the contents. In the case of receptacles intended for the transport of oxidizing gases (i.e. with a subsidiary<br />

risk of 5.1), these materials shall not react with these gases in a dangerous manner.<br />

(8) Periodic inspection<br />

The periodic inspection and test frequencies of pressure relief valves in accordance with 6.2.1.6.3 shall not exceed<br />

five years.<br />

Requirements for open cryogenic receptacles:<br />

Only the following non oxidizing refrigerated liquefied gases of Division 2.2 may be transported in open cryogenic<br />

receptacles: UN Nos. 1913, 1951, 1963, 1970, 1977, 2591, 3136 and 3158.<br />

Open cryogenic receptacles shall be constructed to meet the following requirements:<br />

(1) The receptacles shall be designed, manufactured, tested and equipped in such a way as to withstand all conditions,<br />

including fatigue, to which they will be subjected during their normal use and during normal conditions of<br />

transport.<br />

(2) The capacity shall be not more than 450 litres.<br />

(3) The receptacle shall have a double wall construction with the space between the inner and outer wall being<br />

evacuated (vacuum insulation). The insulation shall prevent the formation of hoar frost on the exterior of the<br />

receptacle.<br />

(4) The materials of construction shall have suitable mechanical properties at the service temperature.<br />

(5) Materials which are in direct contact with the dangerous goods shall not be affected or weakened by the<br />

dangerous goods intended to be transported and shall not cause a dangerous effect, e.g. catalysing a reaction or<br />

reacting with the dangerous goods.<br />

(6) Receptacles of glass double wall construction shall have an outer packaging with suitable cushioning or absorbent<br />

materials which withstand the pressures and impacts liable to occur under normal conditions of transport.<br />

(7) The receptacle shall be designed to remain in an upright position during transport, e.g. have a base whose smaller<br />

horizontal dimension is greater than the height of the centre of gravity when filled to capacity or be mounted on<br />

gimbals.<br />

(8) The openings of the receptacles shall be fitted with devices allowing gases to escape, preventing any splashing out<br />

of liquid, and so configured that they remain in place during transport.<br />

(9) Open cryogenic receptacles shall bear the following marks permanently affixed e.g. by stamping, engraving or<br />

etching:<br />

- The manufacturer’s name and address;<br />

- The model number or name;<br />

- The serial or batch number;<br />

- The UN number and proper shipping name of gases for which the receptacle is intended;<br />

- The capacity of the receptacle in litres.<br />

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