Corrigendum - REACH24H Consulting Group

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Copyright@United Nations, 2011. All rights reserved. 2.9.3.4.6.3.3 The classification of mixtures for long-term hazards based on this summation of the concentrations of classified ingredients is summarized in Table 2.9.4 below. Table 2.9.4: Classification of a mixture for long-term hazards based on summation of the concentrations of classified ingredients Sum of the concentrations (in %) of ingredients classified as: Mixture classified as: Chronic 1 × M a ≥ 25% Chronic 1 (M × 10 × Chronic 1) + Chronic 2 ≥ 25% Chronic 2 a For explanation of the M factor, see 2.9.3.4.6.4. 2.9.3.4.6.4 Mixtures with highly toxic ingredients 2.9.3.4.6.4.1 Acute 1 or Chronic 1 ingredients with acute toxicities well below 1 mg/l and/or chronic toxicities well below 0.1 mg/l (if non-rapidly degradable) and 0.01 mg/l (if rapidly degradable) may influence the toxicity of the mixture and are given increased weight in applying the summation method. When a mixture contains ingredients classified as Acute 1 or Chronic 1, the tiered approach described in 2.9.3.4.6.2 and 2.9.3.4.6.3 shall be applied using a weighted sum by multiplying the concentrations of Acute 1 and Chronic 1 ingredients by a factor, instead of merely adding up the percentages. This means that the concentration of “Acute 1” in the left column of Table 2.9.3 and the concentration of “Chronic 1” in the left column of Table 2.9.4 are multiplied by the appropriate multiplying factor. The multiplying factors to be applied to these ingredients are defined using the toxicity value, as summarized in Table 2.9.5 below. Therefore, in order to classify a mixture containing Acute 1 and/or Chronic 1 ingredients, the classifier needs to be informed of the value of the M factor in order to apply the summation method. Alternatively, the additivity formula (2.9.3.4.5.2) may be used when toxicity data are available for all highly toxic ingredients in the mixture and there is convincing evidence that all other ingredients, including those for which specific acute and/or chronic toxicity data are not available, are of low or no toxicity and do not significantly contribute to the environmental hazard of the mixture. Table 2.9.5: Multiplying factors for highly toxic ingredients of mixtures Acute toxicity M factor Chronic toxicity M factor L(E)C50 value NOEC value NRD a RD ingredients b ingredients 0.1 < L(E)C50 ≤ 1 1 0.01 < NOEC ≤ 0.1 1 - 0.01 < L(E)C50 ≤ 0.1 10 0.001 < NOEC ≤ 0.01 10 1 0.001 < L(E)C50 ≤ 0.01 100 0.0001 < NOEC ≤ 0.001 100 10 0.0001 < L(E)C50 ≤ 0.001 1 000 0.00001 < NOEC ≤ 0.0001 1 000 100 0.00001 < L(E)C50 ≤ 0.0001 10 000 0.000001 < NOEC ≤ 0.00001 10 000 1 000 (continue in factor 10 intervals) (continue in factor 10 intervals) a Non-rapidly degradable. b Rapidly degradable. 2.9.3.4.6.5 Classification of mixtures with ingredients without any useable information 2.9.3.4.6.5.1 In the event that no useable information on acute and/or chronic aquatic toxicity is available for one or more relevant ingredients, it is concluded that the mixture cannot be attributed (a) definitive hazard category(ies). In this situation the mixture shall be classified based on the known ingredients only with the additional statement that: “× percent of the mixture consists of ingredient(s) of unknown hazards to the aquatic environment.”. - 174 -
2.9.4 Lithium batteries Copyright@United Nations, 2011. All rights reserved. Cells and batteries, cells and batteries contained in equipment, or cells and batteries packed with equipment, containing lithium in any form shall be assigned to UN Nos. 3090, 3091, 3480 or 3481 as appropriate. They may be transported under these entries if they meet the following provisions: (a) Each cell or battery is of the type proved to meet the requirements of each test of the Manual of Tests and Criteria, Part III, sub-section 38.3; (b) Each cell and battery incorporates a safety venting device or is designed to preclude a violent rupture under conditions normally incident to transport; (c) Each cell and battery is equipped with an effective means of preventing external short circuits; (d) Each battery containing cells or series of cells connected in parallel is equipped with effective means as necessary to prevent dangerous reverse current flow (e.g., diodes, fuses, etc.); (e) Cells and batteries shall be manufactured under a quality management programme that includes: (i) A description of the organizational structure and responsibilities of personnel with regard to design and product quality; (ii) The relevant inspection and test, quality control, quality assurance, and process operation instructions that will be used; (iii) Process controls that should include relevant activities to prevent and detect internal short circuit failure during manufacture of cells; (iv) Quality records, such as inspection reports, test data, calibration data and certificates. Test data shall be kept and made available to the competent authority upon request; (v) Management reviews to ensure the effective operation of the quality management programme; (vi) A process for control of documents and their revision; (vii) A means for control of cells or batteries that are not conforming to the type tested as mentioned in (a) above; (viii) Training programmes and qualification procedures for relevant personnel; and (ix) Procedures to ensure that there is no damage to the final product. NOTE: In house quality management programmes may be accepted. Third party certification is not required, but the procedures listed in (i) to (ix) above shall be properly recorded and traceable. A copy of the quality management programme shall be made available to the competent authority upon request. - 175 -
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Recommendations on the Transport of
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16. 4.1.4.1, P802 (1) After 4B, ins
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Copyright@United Nations, 2011. All
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Recommendations on the TRANSPORT OF
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2.8 Appearance at normal transport
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4.9 Does the substance have oxidizi
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CHAPTER 1.1 GENERAL PROVISIONS Intr
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1.2.1 Definitions CHAPTER 1.2 DEFIN
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Consignee means any person, organiz
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Open cryogenic receptacle means a t
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Remanufactured packagings include:
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Clarifying examples for certain def
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The decimal multiples and sub-multi
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CHAPTER 1.4 SECURITY PROVISIONS Int
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2.0.0 Responsibilities CHAPTER 2.0
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2.0.4 Transport of samples Copyrigh
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CHAPTER 2.1 CLASS 1 - EXPLOSIVES In
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(e) Division 1.5 Very insensitive s
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NOTE 1: Articles of compatibility g
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2.2.1 Definitions and general provi
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2.2.3 Mixtures of gases Copyright@U
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2.4.2.2.3.3 For solids which may ca
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SELF-REACTIVE SUBSTANCE Concentrati
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Figure 2.4.1: FLOW CHART SCHEME FOR
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2.4.3 Division 4.2 - Substances lia
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2.4.4.3 Assignment of packing group
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CHAPTER 2.5 CLASS 5 - OXIDIZING SUB
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2.5.2.3.1.2 The classification test
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Notes on 2.5.3.2.4: 1) Diluent type
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Exit E Box 11 Figure 2.5.1: FLOW CH
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CHAPTER 2.6 CLASS 6 - TOXIC AND INF
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2.6.2.2.4.2 The criteria for inhala
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UN No. Name and description Class o
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UN No. Name and description Copyrig
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P207 PACKING INSTRUCTION P207 This
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IBC520 PACKING INSTRUCTION IBC520 T
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IBC620 PACKING INSTRUCTION IBC620 T
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equirements. Copyright@United Natio
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4.2.1.9.6 Portable tanks shall not
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4.2.1.13.9 For insulated portable t
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(b) When leaking; (c) When damaged
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4.2.4.4 The periodic testing and in
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T23 PORTABLE TANK INSTRUCTION T23 T
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T50 PORTABLE TANK INSTRUCTION T50 T
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T50 PORTABLE TANK INSTRUCTION (cont
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4.2.5.3 Portable tank special provi
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(c) Substances shall not be allowed
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4.3.1 General provisions Copyright@
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5.1.1 Application and general provi
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5.2.1 Marking Copyright@United Nati
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5.2.1.6 Special marking provisions
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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ISO 4706:2008 Gas cylinders - Refil
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pressure receptacle is not the comp
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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Marking shall be applied in the seq
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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6.5.6.14 Test report Copyright@Unit
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6.6.1 General Copyright@United Nati
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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6.7.3.5 Service equipment Copyright
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where: 0. 82 FA Q = 12. 4 LC - 317
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There shall be no obstruction in an
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(f) Materials (i) Shell material(s)
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the inspection and test, the test p
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CHAPTER 6.8 REQUIREMENTS FOR THE DE
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6.8.4.3 Vehicles shall comply with
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8. Characteristics of test contents
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oken, missing or otherwise inoperat
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(c) Inform the appropriate public h
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TS-R-1 UN 101 1.5.1.1 102 X 103 1.1
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TS-R-1 UN 667 6.4.10.1 668 6.4.10.2
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