Corrigendum - REACH24H Consulting Group

Corrigendum - REACH24H Consulting Group Corrigendum - REACH24H Consulting Group

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2.8.2.5 Packing groups are assigned to corrosive substances in accordance with the following criteria: Packing Group Copyright@United Nations, 2011. All rights reserved. (a) Packing group I is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 60 minutes starting after the exposure time of three minutes or less; (b) Packing group II is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than three minutes but not more than 60 minutes; (c) Packing group III is assigned to substances that: (i) cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 60 minutes but not more than 4 hours; or (ii) are judged not to cause full thickness destruction of intact skin tissue but which exhibit a corrosion rate on either steel or aluminium surfaces exceeding 6.25 mm a year at a test temperature of 55 °C when tested on both materials. For the purposes of testing steel, type S235JR+CR (1.0037 resp. St 37-2), S275J2G3+CR (1.0144 resp. St 44-3), ISO 3574 or Unified Numbering System (UNS) G10200 or a similar type or SAE 1020, and for testing aluminium, non-clad, types 7075–T6 or AZ5GU-T6 shall be used. An acceptable test is prescribed in the Manual of Tests and Criteria, Part III, Section 37. NOTE: Where an initial test on either steel or aluminium indicates the substance being tested is corrosive the follow up test on the other metal is not required. Table 2.8.2.5: Table summarizing the criteria in 2.8.2.5 Exposure Time Observation Period - 160 - Effect I ≤ 3 min ≤ 60 min Full thickness destruction of intact skin II > 3 min ≤ 1 h ≤ 14 d Full thickness destruction of intact skin III > 1 h ≤ 4 h ≤ 14 d Full thickness destruction of intact skin III - - Corrosion rate on either steel or aluminium surfaces exceeding 6.25 mm a year at a test temperature of 55 ºC when tested on both materials

CHAPTER 2.9 CLASS 9 – MISCELLANEOUS DANGEROUS SUBSTANCES AND ARTICLES, INCLUDING ENVIRONMENTALLY HAZARDOUS SUBSTANCES 2.9.1 Definitions 2.9.1.1 Class 9 substances and articles (miscellaneous dangerous substances and articles) are substances and articles which, during transport present a danger not covered by other classes. 2.9.1.2 Deleted. 2.9.2 Assignment to Class 9 The substances and articles of Class 9 are subdivided as follows: Substances which, on inhalation as fine dust, may endanger health 2212 BLUE ASBESTOS (crocidolite) or 2212 BROWN ASBESTOS (amosite, mysorite) 2590 WHITE ASBESTOS (chrysotile, actinolite, anthophyllite, tremolite) Substances evolving flammable vapour 2211 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour 3314 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour Lithium batteries 3090 LITHIUM METAL BATTERIES (including lithium alloy batteries) 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT (including lithium alloy batteries) or 3091 LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) 3480 LITHIUM ION BATTERIES (including lithium ion polymer batteries) 3481 LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT (including lithium ion polymer batteries) or 3481 LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries) NOTE: See 2.9.4. Electric double layer capacitors 3499 CAPACITOR, electric double layer (with an energy storage capacity greater than 0.3 Wh) Live-saving appliances Copyright@United Nations, 2011. All rights reserved. 2990 LIFE-SAVING APPLIANCES, SELF-INFLATING 3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment 3268 AIR BAG INFLATORS or 3268 AIR BAG MODULES or 3268 SEAT-BELT PRETENSIONERS - 161 -

2.8.2.5 Packing groups are assigned to corrosive substances in accordance with the following criteria:<br />

Packing<br />

<strong>Group</strong><br />

Copyright@United Nations, 2011. All rights reserved.<br />

(a) Packing group I is assigned to substances that cause full thickness destruction of intact<br />

skin tissue within an observation period up to 60 minutes starting after the exposure time<br />

of three minutes or less;<br />

(b) Packing group II is assigned to substances that cause full thickness destruction of intact<br />

skin tissue within an observation period up to 14 days starting after the exposure time of<br />

more than three minutes but not more than 60 minutes;<br />

(c) Packing group III is assigned to substances that:<br />

(i) cause full thickness destruction of intact skin tissue within an observation period up<br />

to 14 days starting after the exposure time of more than 60 minutes but not more<br />

than 4 hours; or<br />

(ii) are judged not to cause full thickness destruction of intact skin tissue but which<br />

exhibit a corrosion rate on either steel or aluminium surfaces exceeding 6.25 mm a<br />

year at a test temperature of 55 °C when tested on both materials. For the purposes<br />

of testing steel, type S235JR+CR (1.0037 resp. St 37-2), S275J2G3+CR<br />

(1.0144 resp. St 44-3), ISO 3574 or Unified Numbering System (UNS) G10200 or a<br />

similar type or SAE 1020, and for testing aluminium, non-clad, types 7075–T6<br />

or AZ5GU-T6 shall be used. An acceptable test is prescribed in the Manual of Tests<br />

and Criteria, Part III, Section 37.<br />

NOTE: Where an initial test on either steel or aluminium indicates the substance<br />

being tested is corrosive the follow up test on the other metal is not required.<br />

Table 2.8.2.5: Table summarizing the criteria in 2.8.2.5<br />

Exposure Time Observation<br />

Period<br />

- 160 -<br />

Effect<br />

I ≤ 3 min ≤ 60 min Full thickness destruction of intact skin<br />

II > 3 min ≤ 1 h ≤ 14 d Full thickness destruction of intact skin<br />

III > 1 h ≤ 4 h ≤ 14 d Full thickness destruction of intact skin<br />

III - - Corrosion rate on either steel or aluminium surfaces<br />

exceeding 6.25 mm a year at a test temperature of<br />

55 ºC when tested on both materials

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