Corrigendum - REACH24H Consulting Group
Corrigendum - REACH24H Consulting Group Corrigendum - REACH24H Consulting Group
(c) Contents in a form, or a physical or chemical state different from those authorized for the package design; as specified in the certificate of approval. 2.7.2.4.6.4 A package may only be classified as a Type C if it does not contain: (a) Activities greater than those authorized for the package design; (b) Radionuclides different from those authorized for the package design; or (c) Contents in a form, or physical or chemical state different from those authorized for the package design; as specified in the certificate of approval. 2.7.2.5 Special arrangements Copyright@United Nations, 2011. All rights reserved. Radioactive material shall be classified as transported under special arrangement when it is intended to be transported in accordance with 1.5.4. - 158 -
2.8.1 Definition CHAPTER 2.8 CLASS 8 - CORROSIVE SUBSTANCES Class 8 substances (corrosive substances) are substances which, by chemical action, will cause severe damage when in contact with living tissue, or, in the case of leakage, will materially damage, or even destroy, other goods or the means of transport. 2.8.2 Assignment of packing groups 2.8.2.1 Substances and preparations of Class 8 are divided among the three packing groups according to their degree of hazard in transport as follows: (a) Packing group I: Very dangerous substances and preparations; (b) Packing group II: Substances and preparations presenting medium danger; (c) Packing group III: Substances and preparations presenting minor danger. 2.8.2.2 Allocation of substances listed in the Dangerous Goods List in Chapter 3.2 to the packing groups in Class 8 has been made on the basis of experience taking into account such additional factors as inhalation risk (see 2.8.2.3) and reactivity with water (including the formation of dangerous decomposition products). New substances, including mixtures, can be assigned to packing groups on the basis of the length of time of contact necessary to produce full thickness destruction of human skin in accordance with the criteria in 2.8.2.4. Liquids, and solids which may become liquid during transport, which are judged not to cause full thickness destruction of human skin shall still be considered for their potential to cause corrosion to certain metal surfaces in accordance with the criteria in 2.8.2.5 (c) (ii). 2.8.2.3 A substance or preparation meeting the criteria of Class 8 having an inhalation toxicity of dusts and mists (LC50) in the range of packing group I, but toxicity through oral ingestion or dermal contact only in the range of packing group III or less, shall be allocated to Class 8 (see note under 2.6.2.2.4.1). 2.8.2.4 In assigning the packing group to a substance in accordance with 2.8.2.2, account shall be taken of human experience in instances of accidental exposure. In the absence of human experience the grouping shall be based on data obtained from experiments in accordance with OECD Test Guideline 404 1 or 435 2 . A substance which is determined not to be corrosive in accordance with OECD Test Guideline 430 3 or 431 4 may be considered not to be corrosive to skin for the purposes of these Regulations without further testing. 1 OECD Guideline for the testing of chemicals No. 404 "Acute Dermal Irritation/Corrosion" 2002. 2 OECD Guideline for the testing of chemicals No. 435 "In Vitro Membrane Barrier Test Method for Skin Corrosion" 2006. 3 OECD Guideline for the testing of chemicals No. 430 "In Vitro Skin Corrosion: Transcutaneous Electrical Resistance Test (TER)" 2004. 4 OECD Guideline for the testing of chemicals No. 431 "In Vitro Skin Corrosion: Human Skin Model Test" 2004. Copyright@United Nations, 2011. All rights reserved. - 159 -
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2.8.1 Definition<br />
CHAPTER 2.8<br />
CLASS 8 - CORROSIVE SUBSTANCES<br />
Class 8 substances (corrosive substances) are substances which, by chemical action, will cause<br />
severe damage when in contact with living tissue, or, in the case of leakage, will materially damage, or even<br />
destroy, other goods or the means of transport.<br />
2.8.2 Assignment of packing groups<br />
2.8.2.1 Substances and preparations of Class 8 are divided among the three packing groups according to<br />
their degree of hazard in transport as follows:<br />
(a) Packing group I: Very dangerous substances and preparations;<br />
(b) Packing group II: Substances and preparations presenting medium danger;<br />
(c) Packing group III: Substances and preparations presenting minor danger.<br />
2.8.2.2 Allocation of substances listed in the Dangerous Goods List in Chapter 3.2 to the packing groups<br />
in Class 8 has been made on the basis of experience taking into account such additional factors as inhalation risk<br />
(see 2.8.2.3) and reactivity with water (including the formation of dangerous decomposition products). New<br />
substances, including mixtures, can be assigned to packing groups on the basis of the length of time of contact<br />
necessary to produce full thickness destruction of human skin in accordance with the criteria in 2.8.2.4. Liquids,<br />
and solids which may become liquid during transport, which are judged not to cause full thickness destruction of<br />
human skin shall still be considered for their potential to cause corrosion to certain metal surfaces in accordance<br />
with the criteria in 2.8.2.5 (c) (ii).<br />
2.8.2.3 A substance or preparation meeting the criteria of Class 8 having an inhalation toxicity of dusts<br />
and mists (LC50) in the range of packing group I, but toxicity through oral ingestion or dermal contact only in the<br />
range of packing group III or less, shall be allocated to Class 8 (see note under 2.6.2.2.4.1).<br />
2.8.2.4 In assigning the packing group to a substance in accordance with 2.8.2.2, account shall be taken<br />
of human experience in instances of accidental exposure. In the absence of human experience the grouping shall<br />
be based on data obtained from experiments in accordance with OECD Test Guideline 404 1 or 435 2 . A substance<br />
which is determined not to be corrosive in accordance with OECD Test Guideline 430 3 or 431 4 may be considered<br />
not to be corrosive to skin for the purposes of these Regulations without further testing.<br />
1 OECD Guideline for the testing of chemicals No. 404 "Acute Dermal Irritation/Corrosion" 2002.<br />
2 OECD Guideline for the testing of chemicals No. 435 "In Vitro Membrane Barrier Test Method for Skin<br />
Corrosion" 2006.<br />
3 OECD Guideline for the testing of chemicals No. 430 "In Vitro Skin Corrosion: Transcutaneous Electrical<br />
Resistance Test (TER)" 2004.<br />
4 OECD Guideline for the testing of chemicals No. 431 "In Vitro Skin Corrosion: Human Skin Model Test"<br />
2004.<br />
Copyright@United Nations, 2011. All rights reserved.<br />
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