Corrigendum - REACH24H Consulting Group

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10 000 LC50 ml/m 3 1 000 100 10 Copyright@United Nations, 2011. All rights reserved. Figure 2.6.1: INHALATION TOXICITY: PACKING GROUP BORDERLINES NOT DANGEROUS FOR TRANSPORT 10 100 1 000 10 000 100 000 Volatility ml/m 3 2.6.2.2.4.5 The criteria for inhalation toxicity of vapours in 2.6.2.2.4.3 are based on LC50 data relating to 1 hour exposure, and where such information is available it shall be used. However, where only LC50 data relating to 4 hours exposures to the vapours are available, such figures can be multiplied by two and the product substituted in the above criteria, i.e. LC50 (4 hours) × 2 is considered to be the equivalent of LC50 (1 hour). 2.6.2.2.4.6 Mixtures of liquids that are toxic by inhalation shall be assigned to packing groups according to 2.6.2.2.4.7 or 2.6.2.2.4.8. - 120 - PACKING GROUP III PACKING GROUP II PACKING GROUP I
Copyright@United Nations, 2011. All rights reserved. 2.6.2.2.4.7 If LC50 data are available for each of the toxic substances comprising a mixture, the packing group may be determined as follows: (a) Estimate the LC50 of the mixture using the formula: LC 50 1 (mixture) = n ⎛ ∑ ⎜ f i i= 1⎝ LC where: fi = mole fraction of the i th component substance of the mixture; LC50i = mean lethal concentration of the i th component substance in ml/m 3 ; (b) Estimate the volatility of each component substance comprising the mixture using the formula: where: Pi = partial pressure of the i th component substance in kPa at 20 °C and one atmosphere pressure; (c) Calculate the ratio of the volatility to the LC50 using the formula: (d) Using the calculated values LC50(mixture) and R, the packing group for the mixture is determined: (i) Packing group I: R ≥ 10 and LC50(mixture) ≤ 1 000 ml/m 3 ; (ii) Packing group II: R ≥ 1 and LC50(mixture) ≤ 3 000 ml/m 3 and not meeting criteria for packing group I; (iii) Packing group III: R ≥ 1/5 and LC50(mixture) ≤ 5 000 ml/m 3 and not meeting criteria for packing groups I or II. 2.6.2.2.4.8 In the absence of LC50 data on the toxic constituent substances, the mixture may be assigned a packing group based on the following simplified threshold toxicity tests. When these threshold tests are used, the most restrictive packing group determined is used for transporting the mixture. (a) A mixture is assigned to packing group I only if it meets both of the following criteria: (i) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 1 000 ml/m 3 vaporized mixture in air. Ten albino rats (five male and five female) are exposed to the test atmosphere for one hour and observed for fourteen days. If five or more of the animals die within the fourteen day observation period, the mixture is presumed to have an LC50 equal to or less than 1 000 ml/m 3 ; - 121 - 50i 6 ⎛ Pi × 10 ⎞ 3 Vi = ⎜ ⎟ ⎜ ml / m 101. 3 ⎟ ⎝ ⎠ R = n ∑ ⎛ ⎜ Vi ⎜ ⎝ LC ⎞ ⎟ ⎠ i= 1 50i ⎞ ⎟ ; ⎠
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Recommendations on the Transport of
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16. 4.1.4.1, P802 (1) After 4B, ins
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Copyright@United Nations, 2011. All
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Recommendations on the TRANSPORT OF
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2.8 Appearance at normal transport
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4.9 Does the substance have oxidizi
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CHAPTER 1.1 GENERAL PROVISIONS Intr
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1.2.1 Definitions CHAPTER 1.2 DEFIN
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Consignee means any person, organiz
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Open cryogenic receptacle means a t
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Remanufactured packagings include:
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Clarifying examples for certain def
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The decimal multiples and sub-multi
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CHAPTER 1.4 SECURITY PROVISIONS Int
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1.5.1 Scope and application Copyrig
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1.5.2.4 For occupational exposures
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2.0.0 Responsibilities CHAPTER 2.0
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2.0.4 Transport of samples Copyrigh
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CHAPTER 2.1 CLASS 1 - EXPLOSIVES In
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(e) Division 1.5 Very insensitive s
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NOTE 1: Articles of compatibility g
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- 67 - Type Includes: / Synonym: De
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Page 131 and 132: Notes on 2.5.3.2.4: 1) Diluent type
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2.9.3.4.4.2 Dilution 2.9.3.4.4.2.1
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2.9.3.4.5.3 When applying the addit
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2.9.4 Lithium batteries Copyright@U
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3.1.1 Scope and general provisions
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3.1.2.8 Generic or “not otherwise
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UN No. Name and description Copyrig
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UN No. Name and description Class o
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P200 PACKING INSTRUCTION (cont'd) P
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P207 PACKING INSTRUCTION P207 This
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P502 PACKING INSTRUCTION P502 The f
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IBC520 PACKING INSTRUCTION IBC520 T
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IBC620 PACKING INSTRUCTION IBC620 T
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equirements. Copyright@United Natio
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4.2.1.9.6 Portable tanks shall not
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4.2.1.13.9 For insulated portable t
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(b) When leaking; (c) When damaged
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4.2.4.4 The periodic testing and in
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T23 PORTABLE TANK INSTRUCTION T23 T
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T50 PORTABLE TANK INSTRUCTION T50 T
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T50 PORTABLE TANK INSTRUCTION (cont
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4.2.5.3 Portable tank special provi
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(c) Substances shall not be allowed
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4.3.1 General provisions Copyright@
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4.3.1.16 Before a flexible bulk con
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5.1.1 Application and general provi
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5.2.1 Marking Copyright@United Nati
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5.2.1.6 Special marking provisions
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.2.7 The following table indicat
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6.1.3.10 Examples of markings for N
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6.1.4.2.6 Maximum capacity of drum:
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6.1.4.8 Plastics drums and jerrican
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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6.1.5.3.2 Special preparation of te
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6.1.5.5 Internal pressure (hydrauli
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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6.2.1.3.4 Individual pressure recep
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6.2.1.5.2 On an adequate sample of
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ISO 4706:2008 Gas cylinders - Refil
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6.2.2.4 Periodic inspection and tes
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6.2.2.5.3 Manufacturer's quality sy
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6.2.2.5.4.8 The application shall i
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pressure receptacle is not the comp
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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6.4.7.9 If the containment system f
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6.4.18 Enhanced water immersion tes
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Marking shall be applied in the seq
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6.5.2.4 Marking of remanufactured c
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6.5.4.4.3 A report of each inspecti
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6.5.6.3 Preparation of IBCs for tes
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6.5.6.5.5 Criteria for passing the
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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6.5.6.14 Test report Copyright@Unit
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6.6.1 General Copyright@United Nati
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6.6.3.2 Examples of the marking 50
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6.6.5.2.2 In the drop tests for liq
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6.6.5.3.4 Drop test 6.6.5.3.4.1 App
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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6.7.2.2.14 The values of yield stre
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6.7.2.4.7 When in the applicable po
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(b) A liquid tight closure at the e
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6.7.2.12.2 The combined delivery ca
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6.7.2.12.2.3 Minimum required rate
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6.7.2.17.5 When portable tanks are
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(d) Missing or loose bolts or nuts
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Figure 6.7.2.20.1: Example of ident
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(b) For steels with no clearly defi
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6.7.3.5 Service equipment Copyright
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where: 0. 82 FA Q = 12. 4 LC - 317
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There shall be no obstruction in an
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(f) Materials (i) Shell material(s)
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6.7.4.2.13 Under each of the forces
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6.7.4.8.2 The rated flow capacity m
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6.7.4.14.3 The initial inspection a
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(d) Pressures (i) MAWP (in bar gaug
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6.7.4.15.3 If a portable tank is de
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6.7.5.3.3 For filling and discharge
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6.7.5.10 MEGC supports, frameworks,
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the inspection and test, the test p
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CHAPTER 6.8 REQUIREMENTS FOR THE DE
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6.8.4.3 Vehicles shall comply with
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6.8.5.3.6.2 Preparation for testing
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8. Characteristics of test contents
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oken, missing or otherwise inoperat
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(c) Inform the appropriate public h
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7.2.1 Application and general provi
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TS-R-1 UN 101 1.5.1.1 102 X 103 1.1
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TS-R-1 UN 667 6.4.10.1 668 6.4.10.2
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