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- 108 - ORGANIC PEROXIDE Concentration (%) Diluent type A (%) Diluent type B 1) (%) Inert solid (%) Water (%) Packing Method Control temperature (°C) Emergency temperature 2,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXANE > 90 - 100 OP5 3103 (°C) Number (Generic entry) " > 52 - 90 ≥ 10 OP7 3105 " ≤ 77 ≥ 23 OP8 3108 " ≤ 52 ≥ 48 OP8 3109 " ≤ 47 as a paste OP8 3108 2,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXYNE-3 > 86-100 OP5 3101 3) " >52-86 ≥ 14 OP5 3103 26) " ≤ 52 ≥ 48 OP7 3106 2,5-DIMETHYL-2,5-DI-(2-ETHYLHEXANOYLPEROXY) HEXANE ≤ 100 OP5 +20 +25 3113 2,5-DIMETHYL-2,5-DIHYDROPEROXYHEXANE ≤ 82 ≥ 18 OP6 3104 2,5-DIMETHYL-2,5-DI-(3,5,5-TRIMETHYLHEXANOYL- PEROXY)HEXANE Copyright@United Nations, 2011. All rights reserved. ≤ 77 ≥ 23 OP7 3105 1,1-DIMETHYL-3-HYDROXYBUTYL PEROXYNEOHEPTANOATE ≤ 52 ≥ 48 OP8 0 +10 3117 DIMYRISTYL PEROXYDICARBONATE ≤ 100 OP7 +20 +25 3116 " ≤ 42 as a stable dispersion in water OP8 +20 +25 3119 DI-(2-NEODECANOYLPEROXYISOPROPYL) BENZENE ≤ 52 ≥ 48 OP7 -10 0 3115 DI-n-NONANOYL PEROXIDE ≤ 100 OP7 0 +10 3116 DI-n-OCTANOYL PEROXIDE ≤ 100 OP5 +10 +15 3114 DI-(2-PHENOXYETHYL) PEROXYDICARBONATE >85-100 OP5 3102 3) " ≤ 85 ≥ 15 OP7 3106 DIPROPIONYL PEROXIDE ≤ 27 ≥ 73 OP8 +15 +20 3117 DI-n-PROPYL PEROXYDICARBONATE ≤ 100 OP3 -25 -15 3113 " ≤ 77 ≥ 23 OP5 -20 -10 3113 DISUCCINIC ACID PEROXIDE > 72-100 OP4 3102 3) 17) " ≤ 72 ≥ 28 OP7 +10 +15 3116 Subsidiary risks and remarks
- 109 - ORGANIC PEROXIDE Concentration Diluent Diluent Inert Wate Packing Control Emergency Number type A type B solid r Method tempe- temperature (Generic 1) rature entry) (%) (%) (%) (%) (°C) (°C) DI-(3,5,5-TRIMETHYLHEXANOYL) PEROXIDE > 52-82 ≥ 18 (%) OP7 0 +10 3115 " ≤ 52 as a stable dispersion in water OP8 +10 +15 3119 " > 38-52 ≥ 48 OP8 +10 +15 3119 " ≤ 38 ≥ 62 OP8 +20 +25 3119 ETHYL 3,3-DI-(tert-AMYLPEROXY)BUTYRATE ≤ 67 ≥ 33 OP7 3105 ETHYL 3,3-DI-(tert-BUTYLPEROXY)BUTYRATE > 77 - 100 OP5 3103 1-(2-ETHYLHEXANOYLPEROXY)-1,3-DIMETHYLBUTYL PEROXYPIVALATE " ≤ 77 ≥ 23 OP7 3105 " ≤ 52 ≥ 48 OP7 3106 ≤ 52 ≥ 45 ≥ 10 OP7 -20 -10 3115 tert-HEXYL PEROXYNEODECANOATE ≤ 71 ≥ 29 OP7 0 +10 3115 tert-HEXYL PEROXYPIVALATE ≤ 72 ≥ 28 OP7 +10 +15 3115 3-HYDROXY-1,1-DIMETHYLBUTYL PEROXYNEODECANOATE ≤ 77 ≥ 23 OP 7 - 5 + 5 3115 " ≤ 52 ≥ 48 OP 8 - 5 + 5 3117 " ≤ 52 as a stable dispersion in water ISOPROPYL sec-BUTYL PEROXYDICARBONATE + DI-sec-BUTYL PEROXYDICARBONATE+DI-ISOPROPYL PEROXYDICARBONATE Copyright@United Nations, 2011. All rights reserved. ≤ 32 + ≤ 15 - 18 ≤ 12 - 15 OP 8 - 5 + 5 3119 ≥ 38 OP7 -20 -10 3115 " ≤ 52 + ≤ 28 + ≤ 22 OP5 -20 -10 3111 3) ISOPROPYLCUMYL HYDROPEROXIDE ≤ 72 ≥ 28 OP8 3109 13) p-MENTHYL HYDROPEROXIDE > 72 - 100 OP7 3105 13) " ≤ 72 ≥ 28 OP8 3109 27) METHYLCYCLOHEXANONE PEROXIDE(S) ≤ 67 ≥ 33 OP7 +35 +40 3115 Subsidiary risks and remarks
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Recommendations on the Transport of
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16. 4.1.4.1, P802 (1) After 4B, ins
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Copyright@United Nations, 2011. All
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Recommendations on the TRANSPORT OF
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2.8 Appearance at normal transport
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4.9 Does the substance have oxidizi
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CHAPTER 1.1 GENERAL PROVISIONS Intr
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1.2.1 Definitions CHAPTER 1.2 DEFIN
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Consignee means any person, organiz
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Open cryogenic receptacle means a t
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Remanufactured packagings include:
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Clarifying examples for certain def
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The decimal multiples and sub-multi
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CHAPTER 1.4 SECURITY PROVISIONS Int
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1.5.1 Scope and application Copyrig
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1.5.2.4 For occupational exposures
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2.0.0 Responsibilities CHAPTER 2.0
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2.0.4 Transport of samples Copyrigh
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Page 119 and 120: 2.5.2.3.1.2 The classification test
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Page 125 and 126: - 105 - ORGANIC PEROXIDE Concentrat
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Page 131 and 132: Notes on 2.5.3.2.4: 1) Diluent type
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2.8.1 Definition CHAPTER 2.8 CLASS
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CHAPTER 2.9 CLASS 9 - MISCELLANEOUS
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Other substances or articles presen
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NOTE 1: The organisms fish, crustac
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2.9.3.4.2 The approach for classifi
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2.9.3.4.4.2 Dilution 2.9.3.4.4.2.1
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2.9.3.4.5.3 When applying the addit
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2.9.4 Lithium batteries Copyright@U
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3.1.1 Scope and general provisions
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3.1.2.8 Generic or “not otherwise
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UN No. Name and description Copyrig
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UN No. Name and description Class o
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P200 PACKING INSTRUCTION (cont'd) P
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P207 PACKING INSTRUCTION P207 This
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P502 PACKING INSTRUCTION P502 The f
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IBC520 PACKING INSTRUCTION IBC520 T
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IBC620 PACKING INSTRUCTION IBC620 T
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equirements. Copyright@United Natio
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4.2.1.9.6 Portable tanks shall not
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4.2.1.13.9 For insulated portable t
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(b) When leaking; (c) When damaged
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4.2.4.4 The periodic testing and in
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T23 PORTABLE TANK INSTRUCTION T23 T
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T50 PORTABLE TANK INSTRUCTION T50 T
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T50 PORTABLE TANK INSTRUCTION (cont
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4.2.5.3 Portable tank special provi
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(c) Substances shall not be allowed
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4.3.1 General provisions Copyright@
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4.3.1.16 Before a flexible bulk con
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5.1.1 Application and general provi
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5.2.1 Marking Copyright@United Nati
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5.2.1.6 Special marking provisions
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.2.7 The following table indicat
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6.1.3.10 Examples of markings for N
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6.1.4.2.6 Maximum capacity of drum:
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6.1.4.8 Plastics drums and jerrican
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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6.1.5.3.2 Special preparation of te
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6.1.5.5 Internal pressure (hydrauli
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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6.2.1.3.4 Individual pressure recep
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6.2.1.5.2 On an adequate sample of
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ISO 4706:2008 Gas cylinders - Refil
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6.2.2.4 Periodic inspection and tes
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6.2.2.5.3 Manufacturer's quality sy
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6.2.2.5.4.8 The application shall i
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pressure receptacle is not the comp
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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6.4.7.9 If the containment system f
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6.4.18 Enhanced water immersion tes
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Marking shall be applied in the seq
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6.5.6.3 Preparation of IBCs for tes
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6.5.6.5.5 Criteria for passing the
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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6.5.6.14 Test report Copyright@Unit
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6.6.1 General Copyright@United Nati
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6.6.3.2 Examples of the marking 50
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6.6.5.2.2 In the drop tests for liq
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6.6.5.3.4 Drop test 6.6.5.3.4.1 App
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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6.7.2.2.14 The values of yield stre
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6.7.2.4.7 When in the applicable po
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(b) A liquid tight closure at the e
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6.7.2.12.2.3 Minimum required rate
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6.7.2.17.5 When portable tanks are
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(d) Missing or loose bolts or nuts
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Figure 6.7.2.20.1: Example of ident
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(b) For steels with no clearly defi
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6.7.3.5 Service equipment Copyright
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where: 0. 82 FA Q = 12. 4 LC - 317
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There shall be no obstruction in an
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(f) Materials (i) Shell material(s)
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6.7.4.2.13 Under each of the forces
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6.7.4.8.2 The rated flow capacity m
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6.7.4.14.3 The initial inspection a
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(d) Pressures (i) MAWP (in bar gaug
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6.7.4.15.3 If a portable tank is de
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6.7.5.3.3 For filling and discharge
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6.7.5.10 MEGC supports, frameworks,
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the inspection and test, the test p
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CHAPTER 6.8 REQUIREMENTS FOR THE DE
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6.8.4.3 Vehicles shall comply with
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6.8.5.3.6.2 Preparation for testing
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8. Characteristics of test contents
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oken, missing or otherwise inoperat
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(c) Inform the appropriate public h
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7.2.1 Application and general provi
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TS-R-1 UN 101 1.5.1.1 102 X 103 1.1
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TS-R-1 UN 667 6.4.10.1 668 6.4.10.2
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