Corrigendum - REACH24H Consulting Group

Recommendations

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Organometallic substance/formulation/solution Is the substance pyrophoric? Test N.2 (solid) Test N.3 (liquid) No Is the substance water-reactive? Test N.5 No Is the substance a self-heating solid? Test N.4 No Substance does not have to be classified in division 4.2 or in division 4.3 Copyright@United Nations, 2011. All rights reserved. Figure 2.4.2: a Flowchart scheme for organometallic substances b a Yes Yes No Is the substance water-reactive? Test N.5 Yes Division 4.3, PG I, II or III. Is the substance a solid? No Yes Is the substance a flammable solid? Test N.1 a If applicable and testing is relevant, taking into account reactivity properties, class 6.1 and 8 properties should be considered according to the precedence of hazard table 2.0.3.3. b Test methods N.1 to N.5 can be found in the Manual of tests and Criteria, part III, Section 33. - 96 - Solid Liquid Solid Liquid No Is the substance self-heating? Test N.4 Does the substance contain a diluent with a flash point ≤ 60 °C ? No Yes Yes No Yes Organometallic substance, solid, pyrophoric UN 3391 Organometallic substance, liquid, pyrophoric UN 3392 Organometallic substance, solid, pyrophoric, water-reactive UN 3393 Organometallic substance, liquid, pyrophoric, water-reactive UN 3394 Organometallic substance, solid, water-reactive UN 3395 Organometallic substance, solid, water-reactive, flammable UN 3396 Organometallic substance, solid, water reactive, self-heating UN 3397 Organometallic substance, liquid, water-reactive UN 3398 Organometallic substance, liquid, water-reactive, flammable UN 3399 Organometallic substance, solid, self-heating UN 3400
CHAPTER 2.5 CLASS 5 - OXIDIZING SUBSTANCES AND ORGANIC PEROXIDES Introductory note NOTE: Because of the different properties exhibited by dangerous goods within Divisions 5.1 and 5.2, it is impracticable to establish a single criterion for classification in either division. Tests and criteria for assignment to the two divisions of Class 5 are addressed in this Chapter. 2.5.1 Definitions and general provisions Class 5 is divided into two divisions as follows: (a) Division 5.1 Oxidizing substances Substances which, while in themselves not necessarily combustible, may, generally by yielding oxygen, cause, or contribute to, the combustion of other material. Such substances may be contained in an article; (b) Division 5.2 Organic peroxides Organic substances which contain the bivalent -O-O- structure and may be considered derivatives of hydrogen peroxide, where one or both of the hydrogen atoms have been replaced by organic radicals. Organic peroxides are thermally unstable substances, which may undergo exothermic self-accelerating decomposition. In addition, they may have one or more of the following properties: (i) be liable to explosive decomposition; (ii) burn rapidly; (iii) be sensitive to impact or friction; (iv) react dangerously with other substances; (v) cause damage to the eyes. 2.5.2 Division 5.1 - Oxidizing substances 2.5.2.1 Classification in Division 5.1 Copyright@United Nations, 2011. All rights reserved. 2.5.2.1.1 Oxidizing substances are classified in Division 5.1 in accordance with the test methods, procedures and criteria in 2.5.2.2, 2.5.2.3 and the Manual of Tests and Criteria, Part III, section 34. In the event of divergence between test results and known experience, judgement based on known experience shall take precedence over test results. NOTE: Where substances of this Division are listed in the Dangerous Goods List in Chapter 3.2, reclassification of those substances in accordance with this criteria shall be undertaken only when this is necessary for safety. 2.5.2.1.2 For substances having other risks, e.g. toxicity or corrosivity, the requirements of Chapter 2.0 shall be met. - 97 -
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Recommendations on the Transport of
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16. 4.1.4.1, P802 (1) After 4B, ins
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Copyright@United Nations, 2011. All
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Recommendations on the TRANSPORT OF
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2.8 Appearance at normal transport
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4.9 Does the substance have oxidizi
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CHAPTER 1.1 GENERAL PROVISIONS Intr
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1.2.1 Definitions CHAPTER 1.2 DEFIN
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Consignee means any person, organiz
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Open cryogenic receptacle means a t
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Remanufactured packagings include:
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Clarifying examples for certain def
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The decimal multiples and sub-multi
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CHAPTER 1.4 SECURITY PROVISIONS Int
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1.5.1 Scope and application Copyrig
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2.7.2.2.4 For mixtures of radionucl
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(b) SCO-II: A solid object on which
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2.7.2.3.3.8 For specimens which com
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For mixtures of radionuclides whose
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2.8.1 Definition CHAPTER 2.8 CLASS
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CHAPTER 2.9 CLASS 9 - MISCELLANEOUS
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Other substances or articles presen
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NOTE 1: The organisms fish, crustac
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2.9.3.4.2 The approach for classifi
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2.9.3.4.4.2 Dilution 2.9.3.4.4.2.1
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2.9.3.4.5.3 When applying the addit
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2.9.4 Lithium batteries Copyright@U
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3.1.1 Scope and general provisions
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3.1.2.8 Generic or “not otherwise
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UN No. Name and description Copyrig
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UN No. Name and description Class o
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P200 PACKING INSTRUCTION (cont'd) P
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P207 PACKING INSTRUCTION P207 This
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P502 PACKING INSTRUCTION P502 The f
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IBC520 PACKING INSTRUCTION IBC520 T
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IBC620 PACKING INSTRUCTION IBC620 T
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equirements. Copyright@United Natio
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4.2.1.9.6 Portable tanks shall not
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4.2.1.13.9 For insulated portable t
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(b) When leaking; (c) When damaged
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4.2.4.4 The periodic testing and in
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T23 PORTABLE TANK INSTRUCTION T23 T
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T50 PORTABLE TANK INSTRUCTION T50 T
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T50 PORTABLE TANK INSTRUCTION (cont
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4.2.5.3 Portable tank special provi
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(c) Substances shall not be allowed
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4.3.1 General provisions Copyright@
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4.3.1.16 Before a flexible bulk con
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5.1.1 Application and general provi
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5.2.1 Marking Copyright@United Nati
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5.2.1.6 Special marking provisions
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.2.7 The following table indicat
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6.1.3.10 Examples of markings for N
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6.1.4.2.6 Maximum capacity of drum:
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6.1.4.8 Plastics drums and jerrican
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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6.1.5.3.2 Special preparation of te
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6.1.5.5 Internal pressure (hydrauli
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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6.2.1.3.4 Individual pressure recep
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6.2.1.5.2 On an adequate sample of
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ISO 4706:2008 Gas cylinders - Refil
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6.2.2.4 Periodic inspection and tes
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6.2.2.5.4.8 The application shall i
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pressure receptacle is not the comp
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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6.4.7.9 If the containment system f
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6.4.18 Enhanced water immersion tes
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Marking shall be applied in the seq
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6.5.2.4 Marking of remanufactured c
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6.5.6.3 Preparation of IBCs for tes
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6.5.6.5.5 Criteria for passing the
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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6.5.6.14 Test report Copyright@Unit
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6.6.1 General Copyright@United Nati
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6.6.3.2 Examples of the marking 50
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6.6.5.2.2 In the drop tests for liq
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6.6.5.3.4 Drop test 6.6.5.3.4.1 App
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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6.7.2.2.14 The values of yield stre
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6.7.2.4.7 When in the applicable po
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(b) A liquid tight closure at the e
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6.7.2.12.2.3 Minimum required rate
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6.7.2.17.5 When portable tanks are
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(d) Missing or loose bolts or nuts
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Figure 6.7.2.20.1: Example of ident
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(b) For steels with no clearly defi
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6.7.3.5 Service equipment Copyright
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where: 0. 82 FA Q = 12. 4 LC - 317
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There shall be no obstruction in an
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(f) Materials (i) Shell material(s)
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6.7.4.2.13 Under each of the forces
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6.7.4.8.2 The rated flow capacity m
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6.7.4.14.3 The initial inspection a
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(d) Pressures (i) MAWP (in bar gaug
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6.7.4.15.3 If a portable tank is de
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6.7.5.3.3 For filling and discharge
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6.7.5.10 MEGC supports, frameworks,
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the inspection and test, the test p
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CHAPTER 6.8 REQUIREMENTS FOR THE DE
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6.8.4.3 Vehicles shall comply with
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6.8.5.3.6.2 Preparation for testing
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8. Characteristics of test contents
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oken, missing or otherwise inoperat
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(c) Inform the appropriate public h
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7.2.1 Application and general provi
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TS-R-1 UN 101 1.5.1.1 102 X 103 1.1
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TS-R-1 UN 667 6.4.10.1 668 6.4.10.2
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