Corrigendum - REACH24H Consulting Group

Recommendations

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2.4.3.2.3.2 A substance shall not be classified in Division 4.2 if: (a) A negative result is obtained in a test using a 100 mm cube sample at 140 °C; (b) A positive result is obtained in a test using a 100 mm sample cube at 140 °C and a negative result is obtained in a test using a 25 mm cube sample at 140 °C, a negative result is obtained in a test using a 100 mm cube sample at 120 °C and the substance is to be transported in packages with a volume not more than 3 m 3 ; (c) A positive result is obtained in a test using a 100 mm sample cube at 140 °C and a negative result is obtained in a test using a 25 mm cube sample at 140 °C, a negative result is obtained in a test using a 100 mm cube sample at 100 °C and the substance is to be transported in packages with a volume not more than 450 litres. 2.4.3.3 Assignment of packing groups 2.4.3.3.1 Packing group I shall be assigned to all pyrophoric solids and liquids. 2.4.3.3.2 Packing group II shall be assigned to self-heating substances which give a positive result in a test using a 25 mm sample cube at 140 °C. 2.4.3.3.3 Packing group III shall be assigned to self-heating substances if: (a) A positive result is obtained in a test using a 100 mm sample cube at 140 °C and a negative result is obtained in a test using a 25 mm cube sample at 140 °C and the substance is to be transported in packages with a volume of more than 3 m 3 ; (b) A positive result is obtained in a test using a 100 mm sample cube at 140 °C and a negative result is obtained in a test using a 25 mm cube sample at 140 °C, a positive result is obtained in a test using a 100 mm cube sample at 120 °C and the substance is to be transported in packages with a volume of more than 450 litres; (c) A positive result is obtained in a test using a 100 mm sample cube at 140 °C and a negative result is obtained in a test using a 25 mm cube sample at 140 °C and a positive result is obtained in a test using a 100 mm cube sample at 100 °C. 2.4.4 Division 4.3 - Substances which in contact with water emit flammable gases 2.4.4.1 Definitions and properties Certain substances in contact with water may emit flammable gases that can form explosive mixtures with air. Such mixtures are easily ignited by all ordinary sources of ignition, for example naked lights, sparking handtools or unprotected light bulbs. The resulting blast wave and flames may endanger people and the environment. The test method referred to in 2.4.4.2 is used to determine whether the reaction of a substance with water leads to the development of a dangerous amount of gases which may be flammable. This test method shall not be applied to pyrophoric substances. 2.4.4.2 Classification in Division 4.3 Copyright@United Nations, 2011. All rights reserved. Substances which in contact with water emit flammable gases shall be classified in Division 4.3 if, in tests performed in accordance with the test method given in the Manual of Tests and Criteria, Part III, sub-section 33.4.1: (a) Spontaneous ignition takes place in any step of the test procedure; or (b) There is an evolution of a flammable gas at a rate greater than 1 litre per kilogram of the substance per hour. - 94 -
2.4.4.3 Assignment of packing groups Copyright@United Nations, 2011. All rights reserved. 2.4.4.3.1 Packing group I shall be assigned to any substance which reacts vigorously with water at ambient temperatures and demonstrates generally a tendency for the gas produced to ignite spontaneously, or which reacts readily with water at ambient temperatures such that the rate of evolution of flammable gas is equal to or greater than 10 litres per kilogram of substance over any one minute. 2.4.4.3.2 Packing group II shall be assigned to any substance which reacts readily with water at ambient temperatures such that the maximum rate of evolution of flammable gas is equal to or greater than 20 litres per kilogram of substance per hour, and which does not meet the criteria for packing group I. 2.4.4.3.3 Packing group III shall be assigned to any substance which reacts slowly with water at ambient temperatures such that the maximum rate of evolution of flammable gas is equal to or greater than 1 litre per kilogram of substance per hour, and which does not meet the criteria for packing groups I or II. 2.4.5 Classification of organometallic substances Depending on their properties, organometallic substances may be classified in divisions 4.2 or 4.3, as appropriate, in accordance with the flowchart scheme given in figure 2.4.2. - 95 -
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Recommendations on the Transport of
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16. 4.1.4.1, P802 (1) After 4B, ins
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Copyright@United Nations, 2011. All
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Recommendations on the TRANSPORT OF
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2.8 Appearance at normal transport
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4.9 Does the substance have oxidizi
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CHAPTER 1.1 GENERAL PROVISIONS Intr
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1.2.1 Definitions CHAPTER 1.2 DEFIN
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Consignee means any person, organiz
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Open cryogenic receptacle means a t
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Remanufactured packagings include:
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Clarifying examples for certain def
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The decimal multiples and sub-multi
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CHAPTER 1.4 SECURITY PROVISIONS Int
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Page 63 and 64: 1.5.1 Scope and application Copyrig
Page 65 and 66: 1.5.2.4 For occupational exposures
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Page 69 and 70: 2.0.0 Responsibilities CHAPTER 2.0
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Page 131 and 132: Notes on 2.5.3.2.4: 1) Diluent type
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Page 149 and 150: CHAPTER 2.7 CLASS 7 - RADIOACTIVE M
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Radionuclide (atomic number) A1 A2
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2.7.2.2.4 For mixtures of radionucl
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(b) SCO-II: A solid object on which
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2.7.2.3.3.8 For specimens which com
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For mixtures of radionuclides whose
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2.8.1 Definition CHAPTER 2.8 CLASS
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CHAPTER 2.9 CLASS 9 - MISCELLANEOUS
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Other substances or articles presen
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NOTE 1: The organisms fish, crustac
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2.9.3.4.2 The approach for classifi
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2.9.3.4.4.2 Dilution 2.9.3.4.4.2.1
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2.9.3.4.5.3 When applying the addit
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2.9.4 Lithium batteries Copyright@U
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3.1.1 Scope and general provisions
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3.1.2.8 Generic or “not otherwise
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UN No. Name and description Copyrig
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UN No. Name and description Class o
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P200 PACKING INSTRUCTION (cont'd) P
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P207 PACKING INSTRUCTION P207 This
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P502 PACKING INSTRUCTION P502 The f
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IBC520 PACKING INSTRUCTION IBC520 T
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IBC620 PACKING INSTRUCTION IBC620 T
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equirements. Copyright@United Natio
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4.2.1.9.6 Portable tanks shall not
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4.2.1.13.9 For insulated portable t
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(b) When leaking; (c) When damaged
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4.2.4.4 The periodic testing and in
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T23 PORTABLE TANK INSTRUCTION T23 T
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T50 PORTABLE TANK INSTRUCTION T50 T
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T50 PORTABLE TANK INSTRUCTION (cont
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4.2.5.3 Portable tank special provi
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(c) Substances shall not be allowed
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4.3.1 General provisions Copyright@
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4.3.1.16 Before a flexible bulk con
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5.1.1 Application and general provi
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5.2.1 Marking Copyright@United Nati
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5.2.1.6 Special marking provisions
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.2.7 The following table indicat
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6.1.3.10 Examples of markings for N
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6.1.4.2.6 Maximum capacity of drum:
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6.1.4.8 Plastics drums and jerrican
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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6.1.5.3.2 Special preparation of te
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6.1.5.5 Internal pressure (hydrauli
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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6.2.1.3.4 Individual pressure recep
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6.2.1.5.2 On an adequate sample of
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ISO 4706:2008 Gas cylinders - Refil
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6.2.2.4 Periodic inspection and tes
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6.2.2.5.3 Manufacturer's quality sy
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6.2.2.5.4.8 The application shall i
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pressure receptacle is not the comp
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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6.4.7.9 If the containment system f
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6.4.18 Enhanced water immersion tes
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Marking shall be applied in the seq
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6.5.6.5.5 Criteria for passing the
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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6.5.6.14 Test report Copyright@Unit
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6.6.1 General Copyright@United Nati
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6.6.3.2 Examples of the marking 50
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6.6.5.2.2 In the drop tests for liq
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6.6.5.3.4 Drop test 6.6.5.3.4.1 App
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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6.7.2.2.14 The values of yield stre
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6.7.2.4.7 When in the applicable po
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(b) A liquid tight closure at the e
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6.7.2.12.2.3 Minimum required rate
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6.7.2.17.5 When portable tanks are
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(d) Missing or loose bolts or nuts
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Figure 6.7.2.20.1: Example of ident
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(b) For steels with no clearly defi
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6.7.3.5 Service equipment Copyright
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where: 0. 82 FA Q = 12. 4 LC - 317
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There shall be no obstruction in an
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(f) Materials (i) Shell material(s)
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6.7.4.2.13 Under each of the forces
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6.7.4.14.3 The initial inspection a
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(d) Pressures (i) MAWP (in bar gaug
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6.7.5.3.3 For filling and discharge
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6.7.5.10 MEGC supports, frameworks,
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the inspection and test, the test p
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CHAPTER 6.8 REQUIREMENTS FOR THE DE
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6.8.4.3 Vehicles shall comply with
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6.8.5.3.6.2 Preparation for testing
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8. Characteristics of test contents
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oken, missing or otherwise inoperat
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(c) Inform the appropriate public h
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7.2.1 Application and general provi
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TS-R-1 UN 101 1.5.1.1 102 X 103 1.1
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TS-R-1 UN 667 6.4.10.1 668 6.4.10.2
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Corrigendum - REACH24H Consulting Group

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