Corrigendum - REACH24H Consulting Group

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Copyright@United Nations, 2011. All rights reserved. (b) Organic azides (-C-N3); (c) Diazonium salts (-CN2 + Z - ); (d) N-nitroso compounds (-N-N=O); and (e) Aromatic sulphohydrazides (-SO2-NH-NH2). This list is not exhaustive and substances with other reactive groups and some mixtures of substances may have similar properties. 2.4.2.3.2 Classification of self-reactive substances 2.4.2.3.2.1 Self-reactive substances are classified into seven types according to the degree of danger they present. The types of self-reactive substance range from type A, which may not be accepted for transport in the packaging in which it is tested, to type G, which is not subject to the provisions for self-reactive substances of Division 4.1. The classification of types B to F is directly related to the maximum quantity allowed in one packaging. 2.4.2.3.2.2 Self-reactive substances permitted for transport in packagings are listed in 2.4.2.3.2.3, those permitted for transport in IBCs are listed in packing instruction IBC520 and those permitted for transport in portable tanks are listed in portable tank instruction T23. For each permitted substance listed, the appropriate generic entry of the Dangerous Goods List (UN Nos. 3221 to 3240) is assigned, and appropriate subsidiary risks and remarks providing relevant transport information are given. The generic entries specify: (a) Self-reactive substance type (B to F); (b) Physical state (liquid or solid); and (c) Temperature control, when required (see 2.4.2.3.4). 2.4.2.3.2.3 List of currently assigned self-reactive substances in packagings In the column “Packing Method”, codes “OP1” to “OP8” refer to packing methods in packing instruction P520. Self-reactive substances to be transported shall fulfil the classification and the control and emergency temperatures (derived from the SADT) as listed. For substances permitted in IBCs, see packing instruction IBC520, and for those permitted in tanks, see portable tank instruction T23. NOTE: The classification given in this table is based on the technically pure substance (except where a concentration of less than 100% is specified). For other concentrations, the substances may be classified differently following the procedures in 2.4.2.3.3 and 2.4.2.3.4. - 84 -
Copyright@United Nations, 2011. All rights reserved. SELF-REACTIVE SUBSTANCE Concentration (%) - 85 - Packing method Control temperature (°C) Emergency temperature (°C) UN generic entry Remarks ACETONE-PYROGALLOL COPOLYMER 2- DIAZO-1-NAPHTHOL-5-SULPHONATE 100 OP8 3228 AZODICARBONAMIDE FORMULATION TYPE B, TEMPERATURE CONTROLLED < 100 OP5 3232 (1) (2) AZODICARBONAMIDE FORMULATION TYPE C < 100 OP6 3224 (3) AZODICARBONAMIDE FORMULATION TYPE C, TEMPERATURE CONTROLLED < 100 OP6 3234 (4) AZODICARBONAMIDE FORMULATION TYPE D < 100 OP7 3226 (5) AZODICARBONAMIDE FORMULATION TYPE D, TEMPERATURE CONTROLLED < 100 OP7 3236 (6) 2,2' -AZODI(2,4-DIMETHYL- 4-METHOXYVALERONITRILE) 100 OP7 -5 +5 3236 2,2' -AZODI(2,4-DIMETHYL- VALERONITRILE) 100 OP7 +10 +15 3236 2,2' -AZODI(ETHYL- 2-METHYLPROPIONATE) 100 OP7 +20 +25 3235 1,1-AZODI(HEXAHYDROBENZONITRILE) 100 OP7 3226 2,2'-AZODI(ISOBUTYRONITRILE) 100 OP6 +40 +45 3234 2,2'-AZODI(ISOBUTYRONITRILE) as a water based paste ≤ 50 OP6 3224 2,2'-AZODI(2-METHYLBUTYRONITRILE) 100 OP7 +35 +40 3236 BENZENE-1,3-DISULPHONYL HYDRAZIDE, as a paste 52 OP7 3226 BENZENESULPHONYL HYDRAZIDE 100 OP7 3226 4-(BENZYL(ETHYL)AMINO)-3-ETHOXY- BENZENEDIAZONIUM ZINC CHLORIDE 100 OP7 3226 4-(BENZYL(METHYL)AMINO)-3-ETHOXY BENZENEDIAZONIUM ZINC CHLORIDE 100 OP7 +40 +45 3236 3-CHLORO-4-DIETHYLAMINOBENZENE- DIAZONIUM ZINC CHLORIDE 100 OP7 3226 2-DIAZO-1-NAPHTHOL-4- SULPHONYL- CHLORIDE 100 OP5 3222 (2) 2-DIAZO-1-NAPHTHOL-5- SULPHONYL CHLORIDE 100 OP5 3222 (2) 2-DIAZO-1-NAPHTHOL SULPHONIC ACID ESTER MIXTURE, TYPE D
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Recommendations on the Transport of
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16. 4.1.4.1, P802 (1) After 4B, ins
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Copyright@United Nations, 2011. All
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Recommendations on the TRANSPORT OF
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2.8 Appearance at normal transport
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4.9 Does the substance have oxidizi
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CHAPTER 1.1 GENERAL PROVISIONS Intr
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1.2.1 Definitions CHAPTER 1.2 DEFIN
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Consignee means any person, organiz
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Open cryogenic receptacle means a t
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Remanufactured packagings include:
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Radionuclide (atomic number) A1 A2
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Osmium (76) Radionuclide (atomic nu
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2.7.2.2.4 For mixtures of radionucl
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(b) SCO-II: A solid object on which
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2.7.2.3.3.8 For specimens which com
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For mixtures of radionuclides whose
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2.8.1 Definition CHAPTER 2.8 CLASS
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CHAPTER 2.9 CLASS 9 - MISCELLANEOUS
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Other substances or articles presen
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NOTE 1: The organisms fish, crustac
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2.9.3.4.2 The approach for classifi
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2.9.3.4.4.2 Dilution 2.9.3.4.4.2.1
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2.9.3.4.5.3 When applying the addit
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2.9.4 Lithium batteries Copyright@U
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3.1.1 Scope and general provisions
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3.1.2.8 Generic or “not otherwise
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UN No. Name and description Copyrig
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UN No. Name and description Class o
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(a) Fusee matches are matches the h
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308 Fish scrap or fish meal shall c
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Fuel cell cartridge design types us
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CHAPTER 3.4 DANGEROUS GOODS PACKED
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3.5.1 Excepted quantities CHAPTER 3
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(ii) Where the sample is in the sha
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Class or Division Subsidiary Risk C
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APPENDIX B GLOSSARY OF TERMS Cautio
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BOOSTERS BOMBS, PHOTO-FLASH; BOMBS
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CHARGES, SHAPED, without detonator
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EXPLOSIVE, BLASTING, TYPE D Substan
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IGNITERS Articles containing one or
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PROPELLANTS, LIQUID PROPELLANTS, SO
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Name and description Class UN No. N
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4.1.1.18 Use of salvage packagings
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sections 4.1.5, 4.1.6, 4.1.7, 4.1.8
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P114(a) PACKING INSTRUCTION (Solid
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P200 PACKING INSTRUCTION (cont'd) P
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P207 PACKING INSTRUCTION P207 This
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P502 PACKING INSTRUCTION P502 The f
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IBC520 PACKING INSTRUCTION IBC520 T
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IBC620 PACKING INSTRUCTION IBC620 T
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equirements. Copyright@United Natio
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4.2.1.9.6 Portable tanks shall not
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4.2.1.13.9 For insulated portable t
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(b) When leaking; (c) When damaged
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4.2.4.4 The periodic testing and in
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T23 PORTABLE TANK INSTRUCTION T23 T
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T50 PORTABLE TANK INSTRUCTION T50 T
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T50 PORTABLE TANK INSTRUCTION (cont
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4.2.5.3 Portable tank special provi
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(c) Substances shall not be allowed
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4.3.1 General provisions Copyright@
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4.3.1.16 Before a flexible bulk con
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5.1.1 Application and general provi
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5.2.1 Marking Copyright@United Nati
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5.2.1.6 Special marking provisions
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container except that on labels for
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5.2.2.2.2 Specimen labels CLASS 1 E
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CLASS 7 Radioactive material (No. 7
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5.3.1 Placarding 5.3.1.1 Placarding
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5.3.2 Marking 5.3.2.1 Display of UN
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CHAPTER 5.4 DOCUMENTATION Introduct
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5.4.1.4.2 Sequence of the dangerous
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5.4.1.5.7 Radioactive material Copy
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* FOR DANGEROUS GOODS: you must spe
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5.5.1 Deleted. CHAPTER 5.5 SPECIAL
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5.5.3 Special provisions applicable
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Figure 5.5.2 * insert the proper sh
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6.1.1 General Copyright@United Nati
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6.1.2.7 The following table indicat
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6.1.3.10 Examples of markings for N
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6.1.4.2.6 Maximum capacity of drum:
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6.1.4.8 Plastics drums and jerrican
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6.1.4.13 Plastics boxes Copyright@U
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6.1.4.17 Plastics film bags 5H4 6.1
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6.1.4.20.1 Inner receptacle 6.1.4.2
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(f) If the outer packaging is inten
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6.1.5.3.2 Special preparation of te
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6.1.5.5 Internal pressure (hydrauli
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CHAPTER 6.2 REQUIREMENTS FOR THE CO
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6.2.1.3.4 Individual pressure recep
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6.2.1.5.2 On an adequate sample of
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ISO 4706:2008 Gas cylinders - Refil
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6.2.2.4 Periodic inspection and tes
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6.2.2.5.3 Manufacturer's quality sy
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6.2.2.5.4.8 The application shall i
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pressure receptacle is not the comp
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(d) The designation of the pressure
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6.2.3.4 Marking shall be in accorda
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(d) flat on the shortest side; (e)
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6.4.7.9 If the containment system f
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Marking shall be applied in the seq
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6.5.6.3 Preparation of IBCs for tes
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6.5.6.5.5 Criteria for passing the
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(b) For IBCs of types 31H1, 31H2, 3
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6.5.6.10 Tear test 6.5.6.10.1 Appli
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6.5.6.14 Test report Copyright@Unit
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6.6.1 General Copyright@United Nati
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6.6.3.2 Examples of the marking 50
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6.6.5.3.4 Drop test 6.6.5.3.4.1 App
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CHAPTER 6.7 REQUIREMENTS FOR THE DE
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(b) A liquid tight closure at the e
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6.7.2.12.2.3 Minimum required rate
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(d) Missing or loose bolts or nuts
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Figure 6.7.2.20.1: Example of ident
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(b) For steels with no clearly defi
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6.7.3.5 Service equipment Copyright
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where: 0. 82 FA Q = 12. 4 LC - 317
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There shall be no obstruction in an
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(f) Materials (i) Shell material(s)
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6.7.4.8.2 The rated flow capacity m
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6.7.4.14.3 The initial inspection a
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(d) Pressures (i) MAWP (in bar gaug
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6.7.5.3.3 For filling and discharge
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6.7.5.10 MEGC supports, frameworks,
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the inspection and test, the test p
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CHAPTER 6.8 REQUIREMENTS FOR THE DE
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6.8.4.3 Vehicles shall comply with
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6.8.5.3.6.2 Preparation for testing
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8. Characteristics of test contents
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oken, missing or otherwise inoperat
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(c) Inform the appropriate public h
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7.2.1 Application and general provi
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TS-R-1 UN 101 1.5.1.1 102 X 103 1.1
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TS-R-1 UN 667 6.4.10.1 668 6.4.10.2
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