BASF Glysacorr P113-EN - MAN Diesel & Turbo

Safety data sheet
Page: 1/8
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 26.08.2009 Version: 1.1
Product: Glysacorr* P 113
(30278797/SDS_GEN_EU/EN)
Date of print 27.08.2009
1. Substance/preparation and company identification
Glysacorr* P 113
Use: Coolant concentrate
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Automotive and Refinery Chemicals
Telephone: +49 621 60-93571
Telefax number: +49 621 60-41517
E-mail address: product-safety-auto-refinery@basf.com
Emergency information:
International emergency number:
Telephone: +49 180 2273-112
2. Hazard identification
According to REGULATION (EC) No 1272/2008 on classification, labelling and packaging of
substances and mixtures
Label elements and precautionary statement:
Pictogram:
Signal Word:
Warning
Hazard Statement:

Page: 2/8
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 26.08.2009 Version: 1.1
Product: Glysacorr* P 113
(30278797/SDS_GEN_EU/EN)
Date of print 27.08.2009
Causes serious eye irritation. Causes skin irritation.
Precautionary Statements (Prevention):
Wear protective gloves/clothing and eye/face protection. Wash with plenty of water and soap
thoroughly after handling.
Precautionary Statements (Response):
IF IN EYES: Rinse cautiously with water for several minuts. Remove contact lenses, if present and
easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs:
Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off
contaminated clothing and wash before reuse. Specific treatment (see on this label).
Classification of the substance and mixture:
Skin corrosion/irritation: Cat. 2
Serious eye damage/eye irritation: Cat. 2
Possible Hazards
Irritating to eyes and skin.
3. Composition/information on ingredients
Chemical nature
Preparation based on: carboxylic acid, dicarboxylic acid, amine, in water
Hazardous ingredients (GHS)
according to Regulation (EC) No. 1272/2008
3,5,5-trimethylhexanoic acid
Content (W/W): > 10 % - < 15 %
CAS Number: 3302-10-1
EC-Number: 221-975-0
Hazardous ingredients
according to Directive 1999/45/EC
3,5,5-trimethylhexanoic acid
Content (W/W): > 10 % - < 15 %
CAS Number: 3302-10-1
EC-Number: 221-975-0
Hazard symbol(s): Xn
R-phrase(s): 22, 36
Acute tox.: Cat. 4 (oral)
Eye dam./irr.: Cat. 2
The wording of the hazard symbols and R-phrases is specified in chapter 16 if dangerous ingredients
are mentioned.

Page: 3/8
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 26.08.2009 Version: 1.1
Product: Glysacorr* P 113
(30278797/SDS_GEN_EU/EN)
Date of print 27.08.2009
4. First-Aid Measures
General advice:
Immediately remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.
Note to physician:
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
5. Fire-Fighting Measures
Suitable extinguishing media:
water spray, dry extinguishing media, foam
Specific hazards:
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.
Further information:
Contaminated extinguishing water must be disposed of in accordance with official regulations.
6. Accidental Release Measures
Personal precautions:
Use personal protective clothing.
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.

Page: 4/8
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 26.08.2009 Version: 1.1
Product: Glysacorr* P 113
(30278797/SDS_GEN_EU/EN)
Date of print 27.08.2009
Methods for cleaning up or taking up:
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
with regulations.
Additional information: High risk of slipping due to leakage/spillage of product.
7. Handling and Storage
Handling
No special measures necessary provided product is used correctly.
Protection against fire and explosion:
No special precautions necessary.
Storage
Further information on storage conditions: Keep container tightly closed and in a cool place.
Protect from temperatures below: -10 °C
Protect from temperatures above: 50 °C
8. Exposure controls and personal protection
Components with workplace control parameters
102-71-6: 2,2',2"-nitrilotriethanol (Content (W/W): > 10 % - < 20 %)
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Particle filter with medium efficiency for solid
and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Page: 5/8
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 26.08.2009 Version: 1.1
Product: Glysacorr* P 113
(30278797/SDS_GEN_EU/EN)
Date of print 27.08.2009
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of
dust).
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is required additionally to the stated personal protection equipment.
9. Physical and Chemical Properties
Form: liquid
Colour: yellow
Odour: product specific
pH value: approx. 8.5
(100 g/l)
(ASTM D1287)
Melting point: < -13 °C (DIN ISO 3016)
Boiling point: > 100 °C
(1,013 hPa)
(ASTM D1120)
Flash point: > 100 °C
Flammability: does not ignite
Ignition temperature: > 200 °C (DIN 51794)
Explosion hazard: not explosive
Vapour pressure: 20 hPa
(20 °C)
107 hPa
(50 °C)
Density: 1.10 g/cm3
(20 °C)
Solubility in water: readily soluble
Hygroscopy: Non-hygroscopic
Viscosity, kinematic: approx. 12 mm2/s
(23 °C)
10. Stability and Reactivity
(DIN 51757)
Thermal decomposition: No decomposition if used as directed.
Hazardous reactions:
No hazardous reactions when stored and handled according to instructions.

Page: 6/8
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 26.08.2009 Version: 1.1
Product: Glysacorr* P 113
(30278797/SDS_GEN_EU/EN)
Date of print 27.08.2009
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
11. Toxicological Information
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): > 2,000 mg/kg
The product has not been tested. The statement has been derived from the properties of the individual
components.
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: Irritant. (OECD Guideline 404)
Serious eyes damages/irritation rabbit: Irritant. (OECD Guideline 405)
Other relevant toxicity information
Because of the pH-value, it can be provisionally labelled as 'Irritant'.
12. Ecological Information
Ecotoxicity
Toxicity to fish:
LC50 (96 h) > 100 mg/l, Fish
The product has not been tested. The statement has been derived from the properties of the individual
components.
Persistence and degradability
Assessment biodegradation and elimination (H2O):
The substance can be virtually eliminated from water in suitable effluent treatment plants by
biodegradation, stripping and mechanical separation.
13. Disposal Considerations
Must be dumped or incinerated in accordance with local regulations.
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.

Page: 7/8
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 26.08.2009 Version: 1.1
Product: Glysacorr* P 113
(30278797/SDS_GEN_EU/EN)
Date of print 27.08.2009
14. Transport Information
Land transport
ADR
RID
Inland waterway transport
ADNR
Sea transport
IMDG
Air transport
IATA/ICAO
15. Regulatory Information
Not classified as a dangerous good under transport regulations
Not classified as a dangerous good under transport regulations
Not classified as a dangerous good under transport regulations
Not classified as a dangerous good under transport regulations
Not classified as a dangerous good under transport regulations
Regulations of the European union (Labelling) / National legislation/Regulations
Directive 1999/45/EC ('Preparation Directive'):
Hazard symbol(s)
Xi Irritant.
R-phrase(s)
R36/38 Irritating to eyes and skin.
Other regulations
16. Other Information
Full text of hazard symbols and R-phrases if mentioned as hazardous components in chapter 3:

Page: 8/8
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 26.08.2009 Version: 1.1
Product: Glysacorr* P 113
(30278797/SDS_GEN_EU/EN)
Date of print 27.08.2009
Xn Harmful.
22 Harmful if swallowed.
36 Irritating to eyes.
Vertical lines in the left hand margin indicate an amendment from the previous version.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of
the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.