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the toxic truth - Greenpeace

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32 Amnesty internAtionAl And greenpeAce ne<strong>the</strong>rlAnds<br />

Chapter 2<br />

The first caustic wash at sea was completed<br />

by mid-April 2006. 79 The Probo Koala <strong>the</strong>n<br />

returned to La Skhirra, Tunisia to unload <strong>the</strong><br />

newly “washed” gasoline. Despite having<br />

previously told Univar that <strong>the</strong> hazardous<br />

waste from caustic washing would be<br />

disposed of at La Skhirra, 80 Trafigura had no<br />

intention of delivering <strong>the</strong> waste in Tunisia.<br />

tHe caustic wasHing on Board tHe Probo Koala<br />

Trafigura decided to carry out caustic washing<br />

on board <strong>the</strong> Probo Koala at sea after<br />

running out of options to do it on land. To<br />

carry out this operation, Trafigura arranged<br />

for shipments of <strong>the</strong> coker naphtha to be<br />

delivered to <strong>the</strong> Probo Koala. This took<br />

place in ship-to-ship (STS) operations in <strong>the</strong><br />

Mediterranean. Ships coming from <strong>the</strong> USA<br />

delivered coker naphtha to <strong>the</strong> Probo Koala.<br />

Trafigura <strong>the</strong>n organized for caustic soda to<br />

be delivered to <strong>the</strong> Probo Koala – again in<br />

STS operations. The first washing of coker<br />

naphtha on board <strong>the</strong> Probo Koala was carried<br />

out offshore near Malta in April 2006. 73<br />

A London-based executive of Trafigura later<br />

described <strong>the</strong> process as follows:<br />

“ ... We performed a full STS [shipto-ship]<br />

operation to <strong>the</strong> Mt Probo koala,<br />

... <strong>the</strong>reafter we added 50.000 litres<br />

(50cbms) of Caustic Soda (Material data<br />

Safety Sheet attached) proportionately<br />

across all cargo tanks of Mt Probo koala<br />

(using an injection pump/hoses to <strong>the</strong><br />

upper level of <strong>the</strong> coker naphta from <strong>the</strong><br />

top of <strong>the</strong> tank), <strong>the</strong>reafter circulated<br />

for 24hrs (by transferring individual tank<br />

quantities to an empty tank to achieve <strong>the</strong><br />

maximum inter-surface contact between<br />

Naphtha and Caustic Soda) and allowed <strong>the</strong><br />

Naphtha and Caustic to separate/settle<br />

and <strong>the</strong>reafter drained <strong>the</strong> “Used” caustic<br />

to <strong>the</strong> slop tanks.<br />

In order to ensure that all of <strong>the</strong> caustic<br />

was stripped from <strong>the</strong> treated coker<br />

Naphtha, we stripped more than <strong>the</strong><br />

quantity of caustic added originally to<br />

each cargo tank, to make best efforts that<br />

all caustic was stripped thus to ensure<br />

this may also strip some of <strong>the</strong> treated<br />

naphtha or any free water to <strong>the</strong> Slop Tanks.<br />

Thereafter (..) treated Naphtha on board<br />

was used as a blendstock to make finished<br />

Gasoline. ” 74<br />

The available evidence shows that some<br />

200 tonnes of caustic soda was transferred<br />

to <strong>the</strong> Probo Koala in STS operations over<br />

<strong>the</strong> period between April and late-June<br />

2006. As 50m 3 of caustic was added to<br />

each of <strong>the</strong> three batches of coker naphtha<br />

at least 150 tonnes of caustic soda was<br />

used for <strong>the</strong> washing operations. 75<br />

As well as <strong>the</strong> caustic soda, Trafigura added<br />

a catalyzing agent to some of <strong>the</strong> washes.<br />

Internal documents show that Trafigura<br />

experimented with <strong>the</strong> amount of oxidizing<br />

catalyst used, probably in an effort to optimize<br />

<strong>the</strong> reduction of <strong>the</strong> mercaptan sulphur<br />

of <strong>the</strong> naphtha. While no catalyst was used<br />

for <strong>the</strong> washing of <strong>the</strong> first coker naphtha<br />

load, 8kg of an oxidising catalyst was used<br />

for <strong>the</strong> second shipment, and 16 kilo for <strong>the</strong><br />

washing of <strong>the</strong> third shipment. 76<br />

A report commissioned by Trafigura from a<br />

consultancy company, Minton, Treharne &<br />

Davies Ltd shortly after <strong>the</strong> dumping, noted:<br />

“ In our view <strong>the</strong> exercise onboard <strong>the</strong><br />

Mt Probo Koala was an attempt to replicate<br />

this refinery process [Merox reaction] at<br />

77 sea. ”<br />

This view was later echoed by <strong>the</strong> Dutch<br />

courts, which stated:<br />

“ […] this essentially boils down to <strong>the</strong><br />

moving of an industrial process from land<br />

78<br />

to sea. ”<br />

In fact, Trafigura specifically instructed <strong>the</strong><br />

captain of <strong>the</strong> Probo Koala not to disclose <strong>the</strong><br />

presence of <strong>the</strong> waste at La Skhirra, stating in<br />

an email:<br />

“ PLS ENSUrE ThaT aNY rEMaININGS oF<br />

CaUSTIC SoDa IN ThE TaNkS’ INTErFaCE<br />

arE PUMPED INTo ThE SLoP TaNk To

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